Stereochemical aspects of the formation of toxisterols A

Mechanisms for the formation of toxisterol A are suggested. The connection between the conformation of the initial previtamin and the stereochemistry of the reaction products is discussed.Lensoviet Leningrad Technological Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 225–229, March–April, 1989.     

Partially ordered baer involutive algebras

A survey is given of the basic results of the theory of AW^*-algebras, the properties of the rings of measurable and locally measurable operators associated with von Neumann algebras and AW^*-algebras are described, Baer^*-algebras admitting partial orderings compatible with their algebraic structures are investigated.Translated from Itogi Nauki i Tekhniki, Seriya Sovremennye Problemy Matematiki (Noveishie Dostizheniya), Vol. 27, pp. 99–128, 1985.     

Three-dimensional trajectory study of the I + HI → IH + I, H + I2 reactions

The quasiclassical trajectory calculation of the I + HI collision is performed in order to study the exchange and endothermic reaction channels. The rate constant of the exchange reaction I′ + HI → HI′ + I is found to be equal to 7.7 × 10¹¹ cm³/mol s at room temperature of 300 K. The study of the endothermic reaction I + HI → H + I₂ shows that it takes place only in configurations with large bend angles. Due to the non-collinear character of this reaction its threshold (2 eV) exceeds significantly the threshold of the minimal energy (collinear) reaction path (1.55 eV).     

Ferroelectric polarization switching in nylon-11

Cold-drawn Nylon-11 films, which were prepared by stretching the melt-quenched films to a draw ratio of 2.8: 1 at room temperature, were found to exhibit an electric displacement versus electric field hysteresis loop. The results confirmed that the Nylon-11 film exhibited ferroelectric behavior at or below room temperature. The coercive fields were 65, 98, 125, 160, and 215 MV/m at 20, 0, ?20, ?40, and ?60°C and the remanent polarization at ?20°C (where there was considerably less dc conduction) was 56 mC/m². Switching of the polarization was almost completed within 20 ms.     

Canonical fields in the quantum sh-Gordon model

In the quantum sh model fundamental canonical fields are constructed with the help of the Gel'fand-Levitan-Marchenko equations.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Maternaticheskogo Instituta im. V. A. Steklova, Akad. Nauk SSSR, Vol. 172, pp. 145–159, 1989.     

Violation of KNO scaling and the NBD phenomenon in the framework of the statistical bootstrap model

The connection is considered of multiplicity distributions in three stages: partonic, hadronization, and hadronic. An interpretation of the LoPHD parameter is found. It is shown that under specific hypotheses on the form of the mass spectrum, the statistical bootstrap model leads to the negative binomial distribution (NBD) at the hadronic stage of development of the multiple production process with specific analytic dependences of the parameters of the NBD.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 28–32, May, 1991.One of the authors (V. I. Kuvshinov) is thankful to R. Hagedorn and G. Burgers for numerous discussions.     

Inhomogeneities in silicon p-n-junctions

Latent macroscopic defects in silicon are detected by electrical and electron microscope measurements. They lead to anomalous temperature dependence of the Fermi level position and growth in the hole capture coefficient. A level with energy of 0.55 eV measured from the conduction zone controls the recombination process. It is proposed that macroscopic defects develop upon association of oxygen-silicon vacancy complexes. Action of an electron beam leads to reversible changes which increase upon multiple scanning, affecting the value of the diffusion length.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 71–75, April, 1991.     

Optical quenching of the magnetoplastic effect in NaCl crystals

Observations indicate that illuminating NaCl crystals by ultraviolet light (λ=350 nm) suppresses the magnetoplastic effect. The processes induced by illumination take place in a subsystem of point defects and are related to a change in the state of magnetically sensitive dislocation pinning sites. Fiz. Tverd. Tela (St. Petersburg) 39, 1389–1391 (1996)