Optimization of turbulent jet mixing

We introduce an approach for controlling jet mixing that combines direct numerical simulation of an incompressible jet flow with stochastic optimization procedures. The jet is excited with helical and combined helical and axial actuations at the orifice. An objective function that measures the spreading of the jet evaluates the performance of the actuation parameters. The optimization procedure searches for the best actuation by automatically varying the parameters and calculating their objective function value. Solutions that lead to a pronounced spreading of the jet are found within reasonable time, although the evaluation of the objective function, the DNS of the jet, is expensive. For a jet flow at low Reynolds number the performance of different search algorithms (simulated annealing and evolution strategies) is evaluated. We compare various objective functions based on radial velocity and the concentration of a passive scalar, including functions that penalize actuation with high amplitudes. We find that a combined axial and helical actuation is much more efficient with respect to jet mixing than a helical actuation alone.     

On the Electric Potential Induced by a Homogeneous Magnetic Field in a Turbulent Pipe Flow

In this paper we study a turbulent pipe flow of a weakly electrical conducting fluid subjected to a homogeneous magnetic field which is applied perpendicular to the flow. This configuration forms the basis of a so-called electromagnetic induction flow meter. When the Hartmann number is small so that modification of flow by the Lorenz force can be neglected, the influence of the magnetic field results only in a spatially and temporally varying electric potential. The magnitude of the potential difference across the pipe is then proportional to the flow rate and this constitutes the principle of the flow meter. In this study the flow and electric potential are computed with help of a numerical flow simulation called Large-Eddy Simulation (LES) to which we have added an equation for the electrical potential. The results of the LES have been compared with experiments in which the electric potential is measured as a function of time at several positions on the circumference of the pipe. Both the experimental and numerical results for the mean potential at the pipe wall agree very well with an exact solution that can be obtained in this particular case of a homogeneous magnetic field. Furthermore, it is found that fluctuations in the electric potential due to the turbulence, are small compared to the velocity fluctuations. Based on the results we conclude that electrical-magnetic effects in pipe flow can be accurately computed with LES.     

The development of information storage materials — How microscopy can help?

The response of giant magnetoresistance (GMR) devices depends critically on the film microstructure, with parameters such as layer thickness and interfacial abruptness being crucial. This paper presents results obtained using high resolution electron microscopy (HREM), chemical mapping and atom probe microanalysis. Local variations in the magnetic properties are induced by the microstructure and also when the films are patterned to form small elements. These lead to changes in the magnetization reversal mechanism. Some results of the studies of the magnetization reversal carried out using in situ in Lorentz transmission electron microscopy (LTEM) magnetizing experiments are also included.     

The first homologous series of self-assembled aryl bromo- and aryl cyanocuprates, -argentates,and -aurates; MLi(2)XAr(2) (M = Cu(I), Ag(I), Au(I); X = Br,C(triple bond)N; Ar = [C(6)H(4)CH(2)N(Et)CH(2)CH(2)NEt(2)-2]-)

Reaction of 2 molar equiv of the diamine chelated aryllithium dimers Li(2)(C(6)H(4)[CH(2)N(Et)CH(2)CH(2)NEt(2)]-2)(2) (Li(2)Ar(2)) with the appropriate metal bromide allows the synthesis of the first homologous series of monomeric group 11 bromoate complexes of type MLi(2)BrAr(2) (M = Cu (7), Ag (8), Au (9)). Both in the solid state and in solution, the bromocuprate 7 is isostructural with the bromoargentate 8. The crystal structures of 7 and 8 consist of a MLi(2) core, and each of the two aryl ligands bridges via electron-deficient bonding between the group 11 metal and one Li atom (d(C(ipso)-M) = 1.941(4) (mean) and 2.122(4) (mean) A, for 7 and 8, respectively). The bromine atom exclusively bridges between the two lithium atoms. Each of the ortho-CH(2)N(Et)CH(2)CH(2)NEt(2) moieties is N,N'-chelate bonded to one lithium (d(N-Li) = 2.195(5) and 2.182(0) (mean) A for 7 and 2.154(8) and 2.220(1) (mean) A for 8). Although the MLi(2)BrAr(2) compounds are neutral higher-order -ate species, the structure can also be regarded as consisting of a contact ion pair consisting of two ionic fragments, [Li-Br-Li](+) and [Ar(2)M](-), which are interconnected by both Li-N,N'-chelate bonding and a highly polar C(ipso)-Li interaction. On the basis of NMR and cryoscopic studies, the structural features of the bromoaurate 9 are similar to those of 7 and 8. A multinuclear NMR investigation shows that the bonding between the [Li-Br-Li] and [Ar(2)M] moieties is intermediate between ionic and neutral with an almost equally polarized C(ipso)-Li bond in 7, 8, and 9. Similar reactions between M(C(triple bond)N) and 2 molar equiv of LiAr yield the analogous 2:1 cyanoate complexes of type MLi(2)(C(triple bond)N)Ar(2) (M = Ag (10), Au (11)). Multinuclear NMR studies show that the cyanoate complexes 10 and 11 are isostructural with the bromoate complexes 7, 8, and 9. This paper illustrates that these cyanoaurates may serve as excellent model complexes to gain more insight into the structure of 2:1 cyanocuprates in solution.     

Spectral characteristics of three styles of Croatian folk singing

This paper examines the differences between three Croatian folk singing styles, namely klapa, ojkanje, and tarankanje. In order to factor out singer-specific properties, each of the styles was performed by the same 12 professional male singers. The 36 performances were analyzed with a long-term average spectrum (LTAS) method from which direct effects of the pitch distribution were removed. After factoring out each singer's average, the 36 pitch-corrected LTAS contours were reduced to a two-dimensional representation in two ways: (1) a principal-component analysis and (2) a graphical plot of spectral slope versus speaker's formant strength. Both ways clearly separate the three styles. The spectrum of the klapa style turns out to be similar to that of speech. The ojkanje style is extremely loud and shows two spectral peaks: a sharp one tuned at twice the fundamental frequency and appropriate for long-distance communication on mountain slopes, and a broad one around 3.5 kHz, reminiscent of a speaker's formant. The tarankanje style has a very flat spectrum implemented by vocal pressedness and nasality, which is appropriate for blending into or imitating the timbral characteristics of the sopile folk instrument.     

基于Hilbert-Huang变换的金融收益政策风险因子识别方法

针对政策可能对金融收益产生风险问题,提出了基于Hilbert-Huang变换方法的政策风险因子识别检测方法。通过经验模态分解,Hilbert-Huang频谱分析得到金融时间序列的时域和频域特征,通过与量化处理后的政策进行匹配得到政策产生的异常波动情况,从而实现对政策因子风险的识别与处理。研究结果对于探究宏观政策对金融收益的影响具有重要参考意义。最后以国家房地产调控政策与地产指数为算例,发现本研究提出的方法识别精度高,具有非常好的应用前景。     

Correlation Analysis of the Alternating Step Generator

The alternating step generator is a well-known keystream generator consisting of two stop/go clocked LFSRs, LFSR₁ and LFSR₂, whose clocks are controlled by another LFSR, LFSR₃, which is clocked regularly. A probabilistic analysis of this generator is conducted which shows that the posterior probabilites of individual bits of the first derivatives of the regularly clocked LFSR₁ and LFSR₂ sequences, when conditioned on a given segment of the first derivative of the keystream sequence, can be computed efficiently in a number of probabilistic models of interest. The expected values of these probabilities, for a random keystream sequence, are derived by an approximate theoretical analysis and are also verified by systematic computer experiments. It is pointed out that these posterior probabilities can be enhanced in a resynchronization scenario and thus used for a low-complexity fast correlation attack on the two LFSRs. More generally, it is argued that even without resynchronization these probabilities may be significantly different from one half for fast correlation attacks based on iterative decoding algorithms to be successful, although with incresead complexity. A related method for computing the posterior probabilities of individual bits of the LFSR₃ sequence, when conditioned on both the keystream sequence and the LFSR₁ and LFSR₂ sequences, is also developed. As these posterior probabilities are much more different from one half, they can be used for a low-complexity fast correlation attack on LFSR₃, provided that the initial states of LFSR₁ and LFSR₂ are previously reconstructed.     

Preparation and crystal structure of [μ-Ni(C5H5)P(C6H5)3] [μ-C5H5] [ZnC5H5]2, a nickel-bridged cyclopentadienylzinc dimer

[μ-Ni(C₅H₅)P(C₆H₅)₃] [μ-C₅H₅]₂ [ZnC₅H₅]₂ has been obtained from the reaction of Cp₂Zn with Ni(COD)₂ in the presence of Ph₃P and its structure determined by X-ray crystallography. It consists of two cyclopentadienylzinc moieties bridged by the Ni atom of a CpNiPPh₃ group and by a Cp group. A possible mechanism for the formation of the compound is discussed.