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981.
The chemical adsorption of H atoms on an (8,0) zigzag boron nitride nanotube is studied using the density functional theory with the supercell method. One to four H atoms per 32 B and 32 N are considered. The results show that H atoms prefer to adsorb on the top sites of adjacent B and N atoms to form an armchair chain along the tube axis. An even-odd oscillation behavior of the adsorption energy of H atoms on the tube is found, and the average adsorption energy of even H atoms is obviously bigger than that of odd H atoms. The results can be understood with the frontier orbital theory. Based on this adsorption behavior, several high-symmetric structures of H adsorbed boron nitride nanotubes with 50% and 100% coverages are studied. The pairs of lines' pattern with 50% coverage has the biggest average adsorption energy per H(2) among the chosen configurations, corresponding to approximately 4 wt % hydrogen storage.  相似文献   
982.
The composition of the surface waxes of three apple ( Malus domestica L.) cultivars ("Florina", "Golden B" and "Ozark Gold") has been studied by means of spectroscopic and GC–MS analysis of the class-fractionated mixture of components. Odd n -alkanes, mainly C27 and C29 molecules, are prevalent in the saturated fraction. Small concentrations of alkenes were also found; the C28:1 component is strongly (72%) in excess over the other 1-alkenes. Straight-chain esters (mainly of palmitic acid) of saturated primary alcohols (C18–C30) were also detected; whereas the acyl moiety is made up essentially of an even number of carbons, the alcohol counterpart does not exhibit this characteristic. Aldehydes are present (C20–C30) with the homologue patterns C26–C30 most strongly represented. Straight-chain free secondary alcohols characterize the waxes of "Florina" and "Ozark Gold"; the hydroxy function is located far from the extremity of the carbon framework. Outstanding is the presence of three alcohols with 29 carbon centres. These alcohols are accompanied by free straight-chain primary alcohols, mainly with even-numbered carbon chains in the range C26–C30. Free fatty acids are present; all of have a framework of even-numbered carbon chains mainly in the range C16–C20. C18:1 (oleic acid) is well represented.  相似文献   
983.
The hydration of micellised sodium dehydrocholate molecules was determined by viscosity measurements. It was found that there are 39 water molecules for each micellised surfactant molecule. About ten water molecules may be attributed to the hydration of the sodium carboxylate group. By assignation of two water molecules to each of the three carbonyl groups, the total hydration of a micellised sodium dehydrocholate molecule was estimated as about 16 water molecules. The remaining 23 water molecules per micellised sodium dehydrocholate molecule may be attributed to water trapped in the structure of micelles.  相似文献   
984.
Determination of ambroxol in an automated multi-pumping pulsed flow system.   总被引:3,自引:0,他引:3  
A new flow methodology exploiting the multi-pumping approach was developed for the spectrophotometric determination of ambroxol hydrochloride in pharmaceutical preparations. The flow manifold was implemented by using, exclusively, multiple solenoid-actuated micro-pumps, which acted simultaneously as sample insertion, solutions propelling and reagents commutation units. Linear calibration plots were obtained over an ambroxol concentration ranging from 10 to 200 mg l(-1) (r.s.d. < 0.5%, n = 15) and a sampling rate of about 60 samples per hour (flow rate = 1.92 ml min(-1), sample volume = 80 microl).  相似文献   
985.
The ion chemistry of the title compounds, a nonafluorobutyl methyl ether and a hydrofluoropropane, is elucidated by a combination of studies using atmospheric pressure ionization mass spectrometry and triple quadrupole mass spectrometry. In the positive ion mode, the hydrofluoroether readily forms an [M - F]+ ion, attributable to hydronium ion induced dehydrofluorination, the product of which can be further hydrated to give a protonated hydrofluoroester. By contrast, the hydrofluoropropane does not react with the hydronium ion but rather gives hydrofluoroalkenylium cations via H atom and F atom abstraction by the dioxygen radical cation. In the negative ion mode, the fluorobutyl methyl ether undergoes dissociative electron capture with O2-*, O2-*(H2O), O3-*, and NO2- to generate the fluorobutoxy anion, which can dissociate by CF2[doublebond]O loss to give the perfluorocarbanion when the precursor ions are internally excited. The hydrofluoropropane reacts readily with common atmospheric anions to form molecular complexes with F-, O2-*, and O3-* and the strongly H-bonded species, O2-*(HF) and F-(HF). Interestingly, isomeric pentafluoropropanes form in the reaction with O2-*, either O2-*(HF) or F-(HF), depending on the specific pattern of the fluoro substitution.  相似文献   
986.
Low-energy CAD product-ion spectra of various molecular species of phosphatidylserine (PS) in the forms of [M−H] and [M−2H+Alk] in the negative-ion mode, as well as in the forms of [M+H]+, [M+Alk]+, [M−H+2Alk]+, and [M−2H+3Alk]+ (where Alk=Li, Na) in the positive-ion mode contain rich fragment ions that are applicable for structural determination. Following CAD, the [M−H] ion of PS undergoes dissociation to eliminate the serine moiety (loss of C3H5NO2) to give a [M−H−87] ion, which equals to the [M−H] ion of a phoshatidic acid (PA) and give rise to a MS3-spectrum that is identical to the MS2-spectrum of PA. The major fragmentation process for the [M−2H+Alk] ion of PS arises from primary loss of 87 to give rise to a [M−2H+Alk−87] ion, followed by loss of fatty acid substituents as acids (RxCO2H, x=1,2) or as alkali salts (e. g., RxCO2Li, x=1,2). These fragmentations result in a greater abundance of [M−2H+Alk−87−R2CO2H] than [M−2H+Alk−87−R1CO2H] and a greater abundance of [M−2H+Alk−87−R2CO2Li] than [M−2H+Alk−87−R1CO2Li]; while further dissociation of the [M−2H+Alk−87−R2(or 1)CO2Li] ions gives a preferential formation of the carboxylate anion at sn-1 (R1CO2) over that at sn-2 (R2CO2). Other major fragmentation process arises from differential loss of the fatty acid substituents as ketenes (loss of Rx′CH=CO, x=1,2). This results in a more prominent [M−2H+Alk−R2′CH=CO] ion than [M−2H+Alk−R1′CH=CO] ion. Ions informative for structural characterization of PS are of low abundance in the MS2-spectra of both the [M+H]+ and the [M+Alk]+ ions, but are abundant in the MS3-spectra. The MS2-spectrum of the [M+Alk]+ ion contains a unique ion corresponding to internal loss of a phosphate group probably via the fragmentation processes involving rearrangement steps. The [M−H+2Alk]+ ion of PS yields a major [M−H+2Alk−87]+ ion, which is equivalent to an alkali adduct ion of a monoalkali salt of PA and gives rise to a greater abundance of [M−H+2Alk−87−R1CO2H]+ than [M−H+2Alk−87−R2CO2H]+. Similarly, the [M−2H+3Alk]+ ion of PS also yields a prominent [M−2H+3Alk−87]+ ion, which undergoes consecutive dissociation processes that involve differential losses of the two fatty acyl substituents. Because all of the above tandem mass spectra contain several sets of ion pairs involving differential losses of the fatty acid substituents as ketenes or as free fatty acids, the identities of the fatty acyl substituents and their positions on the glycerol backbone can be easily assigned by the drastic differences in the abundances of the ions in each pair.  相似文献   
987.
Summary Various possibilities for the determination of trace impurities in high-purity iron by atomic spectrometry were investigated in detail. For Ba, Bi, Cd, Co, Cr, Cu, Mn, Ni, Pb, Ti and V, flame AAS, furnace AAS and ICP-OES were firstly evaluated in terms of their power of detection. Detection limits in the g/g-range could be achieved by direct determination. For determination in the ng/g-range a removal of iron by a solvent extraction technique prior to the instrumental measurement was required. The power of detection of direct determination, and of combined procedures were compared with regard to routine applicability and a minimization of systematic errors.  相似文献   
988.
异咯嗪蒙脱石修饰电极的电化学行为   总被引:1,自引:0,他引:1  
吴志斌  董绍俊 《电化学》1997,3(1):40-44
应用十六烷基三甲基溴化铵对蒙脱石进行改性,成功地制备稳定性良好的异咯嗪蒙脱石修饰电采,用循环伏安法对此修饰电极的电化学行为进行了研究。测定了异咯嗪在蒙脱石膜内的化学扩散系数,对异咯嗪在改性蒙脱石中电极反应机制进行了探讨。  相似文献   
989.
化学计量学定量分析模型的评价及应用   总被引:3,自引:0,他引:3  
张录达  吴振良 《分析化学》1996,24(1):97-100
本文介绍了评价化学计量学校正技术所建立的定量分析模型定量分析效果的一种实用方法,根据定量分析模型对样品待测组分的计算值x与样品待测组分的标准值y建立简单回归模型:y=a+bx通过检验回归参数a=0,b=1的假设能否在一定概率水平上被接受,评价定量分析模型对样品待测组分的预测效果。  相似文献   
990.
N-取代吩噻嗪和DDQ的电荷转移络合作用   总被引:1,自引:0,他引:1  
具有盼嘤酸化学结构的化合物有广泛的用途I‘-\其中吩嘤埃衍生物在医学上用作抗精神病药物特别受到药理学家们的注意,发现其药理作用与其分子提供电子的能力有关卜‘」但是我们应该注意到,作为抗精神病药物的吩嚷嚷衍生物,其吩座爆分子的氮原子都连有一个叔胺基链问,例如氯丙障(I)和奋乃静(11).而我们知道,胺类特别是叔胺类有强的提供电子的能力*;在上述的药物分子中是主要的提供电子因素,因此以这类化合物作为给体研究其供电子能力,是不能实际反映吩嘤嗓分子本身的给电子能力的.吩嘤噪类属于二苯并杂环化合物,分子中既…  相似文献   
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