Pore-Scale Modelling of Rate Effects in Waterflooding

We develop a rate-dependent network model that accounts for viscous forces by solving for the wetting and non-wetting phase pressure and which allows wetting layer swelling near an advancing flood front. The model incorporates a new time-dependent algorithm by accounting for partial filling of elements. We use the model to study the effects of capillary number, mobility ratio and contact angle distribution on waterflood displacement patterns, saturation and velocity profiles. By using large networks, generated from a new stochastic network algorithm, we reproduce Buckley–Leverett profiles directly from pore-scale modelling thereby providing a bridge between pore-scale and macro-scale transport.     

Cyclopropane derivatives from the lithium aluminium hydride reduction of methoxyalkynols

Lithium aluminium hydride reduction of methoxyalkynol(1) yields cyclopropane derivatives (2) and (3), both formed by loss of a methoxy group; a reaction scheme for their formation is presented.     

Behavior of Nonaqueous Phase Liquids in Fractured Porous Media under Two‐Phase Flow Conditions

After dense nonaqueous phase liquids (DNAPLs) travel downward through the subsurface, they typically come to rest on fractured bedrock or tight clay layers, which become additional pathways for DNAPL migration. DNAPLs trapped in fractures are continuous sources of groundwater contamination. To decide whether they can be left in place to dissolve or volatilize, or must be removed with active treatment, the movement of DNAPLs in fractured media must be understood at a fundamental level. This work presents numerical simulations of the movements of DNAPLs in naturally fractured media under twophase flow conditions. The flow is modeled using a multiphase network flow model, used to develop predictive capabilities for DNAPL flow in fractures. Capillary pressure–saturation–relative permeability curves are developed for twophase flow in fractures. Comparisons are made between the behavior in crystalline, almost impermeable rocks (e.g. granite) and more permeable rocks like sandstone, to understand the effects of the rock matrix on the displacement of the DNAPLs in the fracture. For capillarydominated flow, displacements occur as a sequence of jumps, as the invading phase overcomes the capillary pressure at downgradient apertures. Preferential channels for the displacement of nonaqueous phase are formed due to high fracture aperture in some regions.     

Analytic Analysis for Oil Recovery During Counter-Current Imbibition in Strongly Water-Wet Systems

We study counter-current imbibition, where a strongly wetting phase (water) displaces non-wetting phase spontaneously under the influence of capillary forces such that the non-wetting phase moves in the opposite direction to the water. We use an approximate analytical approach to derive an expression for saturation profile when the viscosity of the non-wetting phase is non-negligible. This makes the approach applicable to water flooding in hydrocarbon reservoirs, or the displacement of non-aqueous phase liquid (NAPL) by water. We find the recovery of non-wetting phase as a function of time for one-dimensional flow. We compare our predictions with experimental results in the literature. Our formulation reproduces experimental data accurately and is superior to previously proposed empirical models.     

Three-phase flow and gravity drainage in porous media

We present a theoretical and experimental treatment of three-phase flow in water-wet porous media from the molecular level upwards. Many three-phase systems in polluted soil and oil reservoirs have a positive initial spreading coefficient, which means that oil spontaneously spreads as a layer between water and gas. We compute the thickness and stability of this oil layer and show that appreciable recovery of oil by drainage only occurs when the oil layer occupies crevices or roughness in the pore space. We then analyze the distribution of oil, water and gas in vertical equilibrium for a spreading system, which is governed byα=γ _ow (ρ _o ?ρ _g )/γ _go (ρ _w ?ρ _o ), whereγ _ow andγ _go are the oil/water and gas/oil interfacial tensions respectively, andρ _g ,ρ _o andρ _w are the gas, oil and water densities respectively. Ifα>1, there is a height above the oil/water contact, beyond which connected oil only exists as a molecular film, with a negligible saturation. This height is independent of the structure of the porous medium. Whenα<1, large quantities of oil remain in the pore space and gravity drainage is not efficient. If the initial spreading coefficient is negative, oil can be trapped and the recovery is also poor. We performed gravity drainage experiments in sand columns and capillary tubes which confirmed our predictions.     

Relative permeabilities from two- and three-dimensional pore-scale network modelling

We present a computer study of two-phase flow in a porous medium. The porous medium is represented by an isotropic network of up to 80 000 randomly placed nodes connected by thin tubes. We then simulate two-fluid displacements in this network and are able to demonstrate the effects of viscous and capillary forces. We use the local average flow rates and pressures to calculate effective saturation dependent relative pemeabilities, fractional flows and capillary pressures. Using a radial Buckley-Leverett theory, the mean saturation profile can be inferred from the solution of the fractional flow equation, which is consistent with the computed saturation. We show that the relative permeability may be a function of both viscosity ratio and capillary number.     

Marine natural products

This review covers the literature published in 2001 for marine natural products, with 497 citations (373 for the period January to December 2001) and includes 793 compounds isolated from marine microorganisms and phytoplankton, green algae, brown algae, red algae, sponges, coelenterates, bryozoans, molluscs, tunicates and echinoderms. The emphasis is on new compounds and new stereochemical assignments (683 for 2001), together with relevant biological activities, source organisms and country of origin. Syntheses that confirm or revise structures or stereochemistries have been included (95), including any first total synthesis of a marine natural product.     

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