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131.
Elvira Vidović Doris Klee Hartwig Höcker 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4536-4544
Poly(D ,L ‐lactide) and poly(D ,L ‐lactide‐co‐glycolide) with various composition and with one methacrylate and one carboxylate end group were synthesized and grafted onto poly(vinyl alcohol) (PVA) via the carboxylate group. The graft copolymers were crosslinked via the methacrylate groups using a free radical initiator. The polymer networks were characterized by means of NMR and studied qualitatively by means of IR spectroscopy. The influence of the glycolide content in the polyester grafts and of the number of ester units in the grafts on thermal properties and swellability were studied as well. The high swellability in water is characteristic of all hydrogels. Differential scanning calorimetry (DSC) showed a single glass transition temperature that occurs in the range between 51 and 69 °C. Thermogravimetric analysis (TGA) of the networks showed the main loss in weight in the temperature range between 290 and 370 °C. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4536–4544, 2007 相似文献
132.
The complex morphology of high-speed melt-spun nylon-6 fibres hydrated with D2O was investigated using 1H double-quantum-filtered spin-diffusion NMR experiments. The magnetisation exchange from selected crystalline domains along the fibrils and interfibrils was simulated with the help of a three-dimensional solution of a spin-diffusion equation approximated by a product of one-dimensional analytical NMR signals, which correspond to a lamellar morphology. This allows to measure the sizes of crystalline and less-mobile amorphous domains along the fibrils, as well as the diameter of the fibrils and interfibril distances. A series of nylon-6 fibres with extreme values of winding speed and draw ratio was investigated. The changes detected in the domain size along the fibrils and interfibrils show the same trend in the data obtained from wide-angle X-ray diffraction and small-angle X-ray scattering. 相似文献
133.
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135.
M. Lugo-Licona J. Miranda C. M. Romo-Kröger 《Journal of Radioanalytical and Nuclear Chemistry》2004,262(2):391-401
The production cross sections of L-shell X-ray of some rare earth elements have been measured by collision of 12C4+ and 16O4+ ions of 0.5 to 0.75 MeV/amu. The results were compared with experimental data of other authors and with theoretical predictions
gained by the ECPSSR and ECPSSR plus multiple ionization (ECPSSR+MI) models. For atomic parameters (fluorescence yields and
probabilities for Coster-Kronig transitions) the role of several databases were studied. The ECPSSR theory underestimates
cross sections when compared with experimental results obtained in the present work, but ECPSSR+MI has a better agreement
with the experimental data.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
136.
Solichová D Melichar B Klejna M Jurašková B Královská L Bláha V Zd'ánský P Zadák Z 《Talanta》2003,60(2-3):459-465
Twelve self-sustaining nonagenarians, 10 women and two men, aged 94+/-3 years, and eight institutionalised nonagenarians, eight women, aged 91+/-1 year as well as 11 control subjects, seven women and four men, aged 84+/-5 years entered the study. Urinary neopterin, an indicator of systemic immune activation, and serum thiobarbituric acid reactive substances (TBARS), a marker of lipoperoxidation, were determined initially, and collection of the blood and urine samples was repeated at 3-month interval. Neopterin was measured in the urine specimens by reversed-phase high performance liquid chromatography. A C(18) reversed-phase column 3.3x150 mm, 5 mum-diameter packing Separon SGX was used. Potassium phosphate buffer (15 mmol l(-1), pH 6.4) at flow rate of 0.8 ml min(-1) was used as mobile phase. After centrifugation (5 min, 1300xg) and diluting 100 mul of urine specimens with 1.0 ml of mobile phase containing 2 g of disodium-EDTA per litre, a 20 mul sample was injected on a column. Neopterin was identified by its native fluorescence (353 nm excitation, 438 nm emission). Creatinine was determined by Jaffé kinetic reaction after dilution of sample 1:50 (v/v). The concentration of neopterin in urine was expressed as neopterin/creatinine ratio (mumol mol(-1) creatinine). TBARS were determined spectrofluorometrically using LS-5 spectrofluorimeter (excitation wavelength 528 nm, emission wavelength 558 nm) after extraction with n-butanol treatment with thiobarbituric acid. The significance of differences between nonagenarians and control group was examined by ANOVA-Kruskal-Wallis tests, using statistical software NCSS 6.0.21 (Kaysville, UT, 1996). The decision on significance was based on P=0.05. Urinary neopterin was significantly higher in institutionalised compared to self-sustaining subjects and controls (625+/-565 vs. 203+/-63 mumol mol(-1) creatinine, and 198+/-128 mumol mol(-1) creatinine, respectively, P=0.006). The serum TBARS were higher in both groups of nonagenarians (3.23+/-1.16 mumol l(-1) and 2.69+/-0.39 vs. 2.12+/-0.83 mumol l(-1) for the self-sustaining, institutionalised and controls, respectively, P=0.023). We conclude that the fluorimetric determinations of urinary neopterin and serum TBARS can be useful for the monitoring health status in the elderly patients. 相似文献
137.
The final state of Au+Au collisions at √s=130 AGeV at RHIC has been reconstructed within the framework of the Buda-Lund hydrodynamical model, by performing a simultaneous fit to final data on twoparticle Bose-Einstein correlations of the STAR and PHENIX Collaboration, and final identified single-particle spectra as measured by the PHENIX Collaboration. The results indicate a strongly three dimensional expansion, with a four-velocity field that is almost a spherically symmetric Hubble flow. We find large transverse geometrical source sizes, R G=9.8±1.2 fm, relatively short mean freeze-out time, τ0=6.1±0.3 fm/c and a short duration of particle emission, Δτ=0.02±1.5 fm/c. Most strikingsly, we find an indication for a hot central part of the hydrodynamically evolving core, characterized by a central temperature T 0=202±13 MeV that is close to (or even above) the deconfinement temperature of the quark-hadron phase transition. The best fit indicates a cold surface temperature T s=110±16 MeV. When the possibility of the hot center is excluded, the confidence level of the fit decreases from 28.9% to 1.0%. Predictions are made for the rapidity dependence of the slope parameters and for the transverse mass depedence of the rapidity width of the single-particle spectra, and the transverse mass dependence of the non-identical particle correlations. 相似文献
138.
This study compared the fracture strength of Class II slot cavities restored with polymerizable restorative materials. Sixty, caries-free, posterior teeth were divided into five groups of 12 teeth. The Class II slot cavities were prepared. The teeth were restored with two packable composites (Filtek P60, Surefil), a microhybrid composite (Filtek Z250)and two ormocer (Definite, Admira). The restorations were then subjected to fracture resistance tests. The marginal ridges of the restorations were loaded at an angle of 13.5° to the long axis of the tooth in an Universal Testing Machine until failure. Analysis of mean forces indicated that, Filtek P60, Surefil and Filtek Z250 exhibited better performance than Definite and Admira. The tested resin composites differed in their mechanical properties. This study suggested that fracture behavior were highly influenced by the filler system. Overall, Filtek P60, Surefil, Filtek Z250, demonstrated good fracture resistance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
139.
Finding Robust Solutions Using Local Search 总被引:1,自引:0,他引:1
Kenneth Sörensen 《Journal of Mathematical Modelling and Algorithms》2004,3(1):89-103
This paper investigates how a local search metaheuristic for continuous optimisation can be adapted so that it finds broad
peaks, corresponding to robust solutions. This is relevant in problems in which uncertain or noisy data is present. When using
a genetic or evolutionary algorithm, it is standard practice to perturb solutions once before evaluating them, using noise
from a given distribution. This approach however, is not valid when using population-less techniques like local search and
other heuristics that use local search. For those algorithms to find robust solutions, each solution needs to be perturbed
and evaluated several times, and these evaluations need to be combined into a measure of robustness. In this paper, we examine
how many of these evaluations are needed to reliably find a robust solution. We also examine the effect of the parameters
of the noise distribution. Using a simple tabu search procedure, the proposed approach is tested on several functions found
in the literature.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
140.
Jessica Strömbro Peter Gudmundson 《International Journal of Solids and Structures》2008,45(22-23):5765-5787
In this paper a simplified network model for mechano-sorptive creep is presented, which is a further development of an earlier paper [Strömbro, J., Gudmundson, P., 2008. Mechano-sorptive creep under compressive loading – a micromechanical model. International Journal of Solids and Structures 45 (9), 2420–2450.]. It is assumed that the anisotropic hygroexpansion of the fibres leads to large stresses at the fibre bonds when the moisture content changes. The resulting stress state will accelerate creep if the fibre material obeys a constitutive law that is non-linear. Fibre kinks are included in order to capture experimental observations of larger mechano-sorptive effects in compression than in tension. Moisture dependent material parameters and anisotropy in the fibre distribution have been introduced. Theoretical predictions based on the model are compared to experimental results for an anisotropic paper both under tensile and compressive loading at varying moisture content and it is found that the important features in the experiments are captured by the model. Different kinds of drying conditions have also been examined. 相似文献