Bose-Einstein condensates and Efimov states in trapped many-boson systems

We investigate trapped cold Bose gases using the stochastic variational approach with realistic attractive finite-range two-body interactions. We study the properties of the Bose-Einstein condensates, particularly in the large scattering-length regime, and establish the existence of meta-stable many-body Efimov states.     

Mössbauer spectroscopy of perovskite-related oxide fluorides of composition Ba0.5Sr0.5FeO2F at elevated temperatures

The discovery of superconductivity in perovskite-related oxide fluorides of composition Sr₂CuO₂F_2?+?x has stimulated interest in the synthesis and characterisation of other inorganic oxide fluorides with related structures. Recently a new low temperature preparation of inorganic oxide fluorides has been reported, which entails heating the precursor oxide with the polymer poly (vinylidene fluoride) to fluorinate oxygen deficient strontium ferrite, SrFeO_{3??? δ} . The oxygen-deficient compounds Sr_0.5Ba_0.5FeO_{3??? δ} has been fluorinated to give a compound of composition Sr_0.5Ba_0.5FeO₂F. The magnetic transition temperature for this compound is determined by Mössbauer spectroscopy to be 670(±10) K.     

Nucleation time-lag from nucleation and growth experiments in deeply undercooled glass-forming liquids

A new approach is proposed to explain the strong difference between the induction periods (nucleation time-lags) obtained from nucleation rate measurements and from crystal growth experiments for lithium silicate glasses; and their similar magnitude for a Na₂O · 2CaO · 3SiO₂ glass. For these two glass families, the time-lags for nucleation estimated from crystal growth kinetics were compared with those directly obtained from nucleation experiments. A theoretical analysis was performed employing analytical solutions of the Frenkel-Zeldovich equation. In such analysis, the frequently assumed condition of size-independence of the thermodynamic properties of the crystallites was used. Provided this assumption is correct, time-lag data obtained in the two above mentioned ways should coincide. Consequently the significant difference between the values of nucleation time-lag for lithium silicate glasses from nucleation and growth data gives a strong indirect evidence for the deviation of the properties of critical nuclei from the respective parameters characterizing the state of the newly evolving macrophase. For Na₂O · 2CaO · 3SiO₂ glass at intermediate stages of crystallization we show that the average composition of the growing crystals is close to that of the near-critical nuclei. The fact that the nucleation and growth rates of this soda-lime-silica glass refer to the same phase provides an explanation for the similarity of the induction periods estimated from nucleation and growth experiments.     

A sharp weightedL 2-estimate for the solution to the time-dependent Schrödinger equation

For Ξ∈R ⁿ ,t∈R andf∈S(R ⁿ ) define $\left( {S^2 f} \right)\left( t \right)\left( \xi \right) = \exp \left( {it\left| \xi \right|^2 } \right)\hat f\left( \xi \right)$ . We determine the optimal regularitys ₀ such that $\int_{R^n } {\left\| {(S^2 f)[x]} \right\|_{L^2 (R)}^2 \frac{{dx}}{{(1 + |x|)^b }} \leqslant C\left\| f \right\|_{H^s (R^n )}^2 ,s > s_0 } ,$ holds whereC is independent off∈S(R ⁿ ) or we show that such optimal regularity does not exist. This problem has been treated earlier, e.g. by Ben-Artzi and Klainerman [2], Kato and Yajima [4], Simon [6], Vega [9] and Wang [11]. Our theorems can be generalized to the case where the exp(it|ξ|²) is replaced by exp(it|ξ|^a),a≠2. The proof uses Parseval's formula onR, orthogonality arguments arising from decomposingL ²(R ⁿ ) using spherical harmonics and a uniform estimate for Bessel functions. Homogeneity arguments are used to show that results are sharp with respect to regularity.     

An optimal semiclassical bound on commutators of spectral projections with position and momentum operators

Letters in Mathematical Physics - We prove an optimal semiclassical bound on the trace norm of the following commutators $$[{\varvec{1}}_{(-\infty ,0]}(H_\hbar ),x]$$ , $$[{\varvec{1}}_{(-\infty...     

Finite-sample properties of estimators for first and second order autoregressive processes

Statistical Inference for Stochastic Processes - The class of autoregressive (AR) processes is extensively used to model temporal dependence in observed time series. Such models are easily...     

Rate coefficients for reactions of OH radicals with CH3D,CH2D2, CHD3, and CD4

Fourier transform infrared (FTIR) smog chamber techniques were used to investigate the atmospheric chemistry of the isotopologues of methane. Relative rate measurements were performed to determine the kinetics of the reaction of the isotopologues of methane with OH radicals in cm³ molecule⁻¹ s⁻¹ units: k(CH₃D + OH) = (5.19 ± 0.90) × 10⁻¹⁵, k(CH₂D₂ + OH) = (4.11 ± 0.74) × 10⁻¹⁵, k(CHD₃ + OH) = (2.14 ± 0.43) × 10⁻¹⁵, and k(CD₄ + OH) = (1.17 ± 0.19) × 10⁻¹⁵ in 700 Torr of air diluent at 296 ± 2 K. Using the determined OH rate coefficients, the atmospheric lifetimes for CH_4–xD_x (x = 1–4) were estimated to be 6.1, 7.7, 14.8, and 27.0 years, respectively. The results are discussed in relation to previous measurements of these rate coefficients.     

Solvent‐Dependent Structure of the I3− Ion Derived from Photoelectron Spectroscopy and Ab Initio Molecular Dynamics Simulations

Ab initio molecular dynamics (MD) simulations of the solvation of LiI₃ in four different solvents (water, methanol, ethanol, and acetonitrile) are employed to investigate the molecular and electronic structure of the I₃^? ion in relation to X‐ray photoelectron spectroscopy (XPS). Simulations show that hydrogen‐bond rearrangement in the solvation shell is coupled to intramolecular bond‐length asymmetry in the I₃^? ion. By a combination of charge analysis and I 4 d core‐level XPS measurements, the mechanism of the solvent‐induced distortions has been studied, and it has been concluded that charge localization mediates intermolecular interactions and intramolecular distortion. The approach involving a synergistic combination of theory and experiment probes the solvent‐dependent structure of the I₃^? ion, and the geometric structure has been correlated with the electronic structure.