Transport of gases in aromatic polyesters: Correlation with WAXD studies

Polymer packing density can be conveniently measured by either density-based measurements (direct or estimated free volume) or wide-angle X-ray diffraction (WAXD) spectra. Previously reported diffusivity and permeability values for various polyarylates and polyimides are examined on the basis of the packing density measured by these different techniques. It is shown that in these rigid glassy polymers, the mean intersegmental distance, the d-spacing, obtained from WAXD provides a better measure of the effect of polymer packing on diffusivity than either direct density measurements or estimated free volumes. It has been possible to correlate previously reported diffusivity and sorption data for various polyarylates and polycarbonate on the basis of the WAXD investigation, using the d-spacing and the amorphous peak width, respectively. The effect of polyarylate structure on d-spacing has been studied. A series of polyarylates have been synthesized with different substituents on the bridge carbon. In this series the d-spacing remains constant while the carbonyl group density and the glass transition temperatures are varied. However, small substituents on the aromatic ring cause significant changes in the d-spacing. These results can be used to tailor polyarylates with desired intersegmental distances and chain flexibility.     

The combined effects of evaporation and quench steps on asymmetric membrane formation by phase inversion

An analysis of the effects of combined evaporation and quench periods on the formation of asymmetric membranes by the phase inversion technique is presented. The model for the evaporation period assumes binary diffusion and includes composition dependence in the mutual diffusion coefficient and free convection mass transfer in the gas phase. The quench period model includes the use of 4 composition-dependent diffusion coefficients and incorporates a modified from of the interface jump mass balance which enables efficient numerical analysis of composition gradients in the film at the beginning of the quench period. Results for the effects of evaporation-period variable, including: evaporation time, initial cast film thickness, casting surface dimension, and vapor-phase composition, clearly indicate that significant effects of the evaporation period on membrane structure formation and its reproducibility occur within 20 seconds.     

Kinetics and mechanism of oxidation of indigo carmine by hypohalites

Kinetics of oxidation of indigo carmine (IC) by sodium hypohalites, NaOX (X ? Cl or Br), in alkaline buffer of pH 9–11 has been studied spectrophotometrically at λ = 610 nm. The experimental rate law obtained is ?d[IC]/dt = k[OX^?][IC][OH^?]^x where x <1. Variation of ionic strength or dielectric constant of the medium had no effect on the reaction rate while the addition of halide ions slightly retarded the rate. A most plausible mechanism proposed on the basis of experimental results involves the formation of isatin sulphonate which undergoes further oxidation to anthranilate. Activation parameters have been evaluated.     

Deformation of doped NaCl crystals during uniaxial compression at temperatures of 4.2–293 K

The impurity weakening of crystalline NaCl:Mg and NaCl:Mn associated with purification of the matrix in a melt is demonstrated. This effect is manifested in a consistent change in the yield strength and mobility of dislocations. Its unusual temperature dependence is determined: in a number of cases weakening becomes greater as the temperature is lowered within the interval 293–4.2 K. A deviation in the elastic region of the stress-strain curves is observed to increase as the temperature is lowered. Plasticizing of crystalline NaCl is established: when the deformation temperature is lowered from 293 to 77 and 4.2 K the rate of rise in the yield strength of Cd²⁺ and Sr²⁺ doped samples is lower than that of undoped samples. An explanation for this fact is proposed. Fiz. Tverd. Tela (St. Petersburg) 39, 313–317 (February 1997) Deceased.     

Step-strain deformations for viscoelastic fluids: Formulation of a strain-coupling constitutive equation

An integral constitutive equation which includes strain-coupling effects is proposed. The constitutive equation is more general than the K-BKZ equation, and it is shown that this equation can explain various important aspects of double-step stress-relaxation data.     

Stressed state of a rock mass around a working with a relief cavity

The stressed state of a rock mass in the vicinity of a preparatory working protected by a relief cavity is studied. A numerical study is made of the stress field and the relief zone, and the effect of length and slope of a slot on formation of the relief zone is clarified.Translated from Teoreticheskaya i Prikladnaya Mekhanika, No. 20, pp. 31–36, 1989.     

Traveling-wave solutions and their application to inverse problems of sorption dynamics

Translated from Matematicheskie Modeli i Optimizatsiya Vychislitel'nykh Algoritmov, pp. 67–74, 1994.     

Analysis of atmospheric particular matter and water using atomic emission spectrometry with inductively-coupled plasma and two-jet plasmatron

Summary A method for the atomic emission spectrometric analysis of air and water with inductively coupled and two-jet direct current plasmas has been developed. The method has been applied to the determination of impurity contents with good accuracy and sensitivity.     

Mössbauer studies on some new magnetic oxides

Three new magnetic oxides have been synthesised, viz., Li₂Fe₃VO₈, YFe₃TiO₈ and CaFe₃VO₈. XRD studies show that the first compound has a cubic symmetry of spinel type while the latter two show orthorhombic symmetry. All the three compounds are magnetic at room temperature, however, the first compound shows a large magnetic moment as compared to the other two. Their Mössbauer spectra at room temperature show distinct hyperfine split spectral lines. The present preliminary investigation indicates that the long range order is ferrimagnetic in Li₂Fe₃VO₈ and CaFe₃VO₈ while in YFe₃TiO₈ it is more likely to be canted antiferromagnetic.