Effects of template and precursor chemistry on structure and properties of mesoporous TiO2 thin films

Mesoporous TiO2 thin films were synthesized by sol-gel processing using an aqueous-based, inexpensive, and environmentally friendly precursor and cationic surfactants as templates under mild reaction conditions. The films were prepared by spin-coating on glass substrates followed by calcination to remove the surfactant. N2 sorption, X-ray diffraction, and transmission electron microscopy were used to characterize the porosity, pore size, and pore structure before and after calcination. Films were found to have wormlike pore structures after calcination and surface areas on the order of 200 m2/g. These results show that the mesostructure and porosity of the thin films can be controlled by the surfactant template chemistry such as surfactant/Ti ratio, pH, and rate of solvent evaporation.     

Exposed-key weakness of αη

The αη protocol given by Barbosa et al. [G.A. Barbosa, E. Corndorf, P. Kumar, H.P. Yuen, Phys. Rev. Lett. 90 (2003) 227901, quant-ph/0212018] claims to be a secure way of encrypting messages using mesoscopic coherent states. We show that transmission under αη exposes information about the secret key to an eavesdropper, and we estimate the rate at which an eavesdropper can learn about the key. We also consider the consequences of using further randomization to protect the key and how our analysis applies to this case. We conclude that αη is not informationally secure.     

Effects of trace metals and organic additives on porosity and dielectric constant of high purity mesoporous silica films

The beneficial effects that alkali metal and alkylammonium salt additions to molecularly templated silica sols have on the resulting mesoporous silica films formed from evaporative-coating methods with respect to porosity, elastic modulus, dielectric constant, and film surface uniformity were investigated and identified.     

Use of nanoparticles in capillary and microchip electrochromatography

Applications of nanoparticles are of rising interest in separation science, due to their favorable surface-to-volume ratio as well as their applicability in miniaturization. A stationary phase with large surface area in combination with an electroosmotic flow-driven system has great potential in a highly efficient separation system. This review covers the use of various nanoparticles as stationary or pseudostationary phase in capillary and microchip electrochromatography. The use of nanoparticles in pseudostationary phase capillary electrochromatography and open-tubular capillary electrochromatography are thoroughly discussed. The stationary and pseudostationary phases that are described include polymer nanoparticles, gold nanoparticles, silica nanoparticles, fullerenes and carbon nanotubes.     

Phosphor und Phosphate

Analytical and Bioanalytical Chemistry -     

Neue Anwendungen des Silberreduktors

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