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Ottosson N Børve KJ Spångberg D Bergersen H Sæthre LJ Faubel M Pokapanich W Öhrwall G Björneholm O Winter B 《Journal of the American Chemical Society》2011,133(9):3120-3130
The local electronic structure of glycine in neutral, basic, and acidic aqueous solution is studied experimentally by X-ray photoelectron spectroscopy and theoretically by molecular dynamics simulations accompanied by first-principle electronic structure and spectrum calculations. Measured and computed nitrogen and carbon 1s binding energies are assigned to different local atomic environments, which are shown to be sensitive to the protonation/deprotonation of the amino and carboxyl functional groups at different pH values. We report the first accurate computation of core-level chemical shifts of an aqueous solute in various protonation states and explicitly show how the distributions of photoelectron binding energies (core-level peak widths) are related to the details of the hydrogen bond configurations, i.e. the geometries of the water solvation shell and the associated electronic screening. The comparison between the experiments and calculations further enables the separation of protonation-induced (covalent) and solvent-induced (electrostatic) screening contributions to the chemical shifts in the aqueous phase. The present core-level line shape analysis facilitates an accurate interpretation of photoelectron spectra from larger biomolecular solutes than glycine. 相似文献
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T. Lund D. Molzahn R. Brandt B. Bergersen D. Eriksen E. Hagebø I.R. Haldorsen T. Bjørnstad C. Richard-Serre 《Physics letters. [Part B]》1981,102(4):239-241
The nuclear interaction between natural copper and 1 GeV 12C has been investigated with radiochemical methods. Charge and mass distributions have been derived. The form of the mass yield curve is determined by the total kinetic energy in the system. 相似文献
15.
B. I. Birger 《Mechanics of Composite Materials》1972,8(1):146-148
The conditions under which the radial and peripheral stresses in a free and in a constrained cylinder coincide at the ends of the cylinder when the temperature distribution is axially symmetrical are considered.P. I. Baranov Central Institute for Aircraft Engine Construction, Moscow. Translated from Mekhanika Polimerov, No. 1, pp. 163–165, January–February, 1972. 相似文献
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Background
The determination of the osmolality of aqueous samples using a freezing point osmometer is a well-established, routine laboratory method. In addition to their use in clinical and pharmaceutical laboratories, freezing point osmometers are also employed in food testing laboratories. One application is the determination of the osmolality of milk. Although cow's milk is a natural product whose water content is approximately 87%, the osmolality of milk is a significant value when the milk is collected from a larger population of animals. This value is used in milk processing to control the water content, based on the German Food Control Regulations for Milk. 相似文献17.
The trapping rate of positrons at dislocations in metals, and its temperature dependence, are calculated. Two different trapping processes, with the excess energy absorbed in either electron-hole pair formation or by phonon creation, are considered and the former is found to be the most important. An extension of the theory to include depletion of the positron density around the dislocations in a diffusion approximation is included. The trapping is found to be transition limited if the temperature is low or the trap potential shallow. At room temperature diffusion is important for deep traps. 相似文献
18.
The present article describes the determination of thermal stresses in an orthotropic cylinder with an axially symmetric temperature field taking into account the change in the elasticity constants over the cylinder radius. A closed solution is given for constant elasticity coefficients.P. I. Baranov Central Institute of Aircraft-Engine Building, Moscow. Translated from Mekhanika Polimerov, No. 2, pp. 310–314, March–April, 1972. 相似文献
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In many companies there is an on-going discussion about capacity, capacity utilization and capital tied up in inventories. However, traditional models such as the EOQ model only include capacity considerations in the set-up cost, or in the cost of a replenishment order. This implies e.g. that they do not consider the set-up time as a capacity constraint. Furthermore, in these models the set-up cost is usually treated as a constant, even though the opportunity cost for capacity in general is dependent upon the capacity utilization.The purpose of this paper is to derive an analytical model for the balancing of capacity and lot sizes. The model includes costs for capacity, work-in-process (queueing, set-up, and processing time), and finished goods inventory. The total costs are minimized with respect to capacity. Then, the corresponding, recommended lot sizes are determined. The model was tested with data from a Swedish manufacturing company. The results turned out to coincide with experiences of the company in many important respects. The model offers production management an opportunity to discuss the relationship between capacity, work-in-process, and lot sizes. 相似文献