Detection of local-moment formation using the resonant interaction between coupled quantum wires

We study the influence of many-body interactions on the transport characteristics of a pair of quantum wires that are coupled to each other by means of a quantum dot. Under conditions where a local magnetic moment is formed in one of the wires, tunnel coupling to the other gives rise to an associated peak in its density of states, which can be detected directly in a conductance measurement. Our theory is therefore able to account for the key observations in the recent study of T. Morimoto et al. [Appl. Phys. Lett., ()]], and demonstrates that coupled quantum wires may be used as a system for the detection of local magnetic-moment formation.     

Probing the microscopic structure of bound states in quantum point contacts

Using an approach that allows us to probe the electronic structure of strongly pinched-off quantum point contacts (QPCs), we provide evidence for the formation of self-consistently realized bound states (BSs) in these structures. Our approach exploits the resonant interaction between closely coupled QPCs, and demonstrates that the BSs may give rise to a robust confinement of single spins, which show clear Zeeman splitting in a magnetic field.     

Draining of the sea of chaos: role of resonant transmission and reflection in an array of billiards

We investigate the dynamics of a system of coupled electron billiards by using a magnetic field to dramatically modify the underlying mixed phase space. At specific values of the magnetic field the sea of chaos is drained. At these fields there exist reflected or transmitted orbits associated with maxima and minima in the experimentally observed magnetoresistance. These effects are studied by comparing the classical and quantum-mechanical phase-space dynamics leading to a basic understanding of the role of chaos in the transport in an array of billiards.     

Spectrum of electronic excitations due to the adsorption of atoms on metal surfaces

The time-dependent, mean-field Newns-Anderson model for a spin-polarized adsorbate approaching a metallic surface is solved in the wide-band limit. Equations for the time evolution of the electronic structure of the adsorbate-metal system are derived and the spectrum of electronic excitations is found. The behavior of the model is demonstrated for a set of physically reasonable parameters.     

Nonuniform energy level broadening in open quantum dots: the influence of the closed dot eigenstates on transport

We present simulations of a realistically modeled quantum dot with soft boundaries and open leads supporting several modes. The wavefunctions of this open dot can be decomposed in terms of the eigenstates of a corresponding closed dot my means of projection. At particular resonances, this decomposition reveals that transport in the open dot can be mediated through a single eigenstate. Thus, the quantization of closed-dot energy levels can be preserved even as the dot is opened, but we find that there is a selection of particular eigenstates that depends strongly on the positions and nature of the contacts.     

Field-based cavity ring-down spectrometry of δ13C in soil-respired CO2

Measurement of soil-respired CO₂ at high temporal resolution and sample density is necessary to accurately identify sources and quantify effluxes of soil-respired CO₂. A portable sampling device for the analysis of δ¹³C values in the field is described herein.

CO₂ accumulated in a soil chamber was batch sampled sequentially in four gas bags and analysed by Wavelength-Scanned Cavity Ring-down Spectrometry (WS-CRDS). A Keeling plot (1/[CO₂] versus δ¹³C) was used to derive δ¹³C values of soil-respired CO₂. Calibration to the δ¹³C Vienna Peedee Belemnite scale was by analysis of cylinder CO₂ and CO₂ derived from dissolved carbonate standards. The performance of gas-bag analysis was compared to continuous analysis where the WS-CRDS analyser was connected directly to the soil chamber.

Although there are inherent difficulties in obtaining absolute accuracy data for δ¹³C values in soil-respired CO₂, the similarity of δ¹³C values obtained for the same test soil with different analytical configurations indicated that an acceptable accuracy of the δ¹³C data were obtained by the WS-CRDS techniques presented here. Field testing of a variety of tropical soil/vegetation types, using the batch sampling technique yielded δ¹³C values for soil-respired CO₂ related to the dominance of either C₃ (tree, δ¹³C=?27.8 to?31.9 ‰) or C₄ (tropical grass, δ¹³C=?9.8 to?13.6 ‰) photosynthetic pathways in vegetation at the sampling sites. Standard errors of the Keeling plot intercept δ¹³C values of soil-respired CO₂ were typically<0.4 ‰ for analysis of soils with high CO₂ efflux (>7–9 μmol m^?2 s^?1).     

Hollow polymer particles that are pH-responsive and redox sensitive: two simple steps to triggered particle swelling, gelation and disassembly

A new, simple, two-step method is introduced for preparing hollow particles that are both pH-responsive and redox sensitive. Hollow poly(methyl methacrylate-co-methacrylic acid) particles swell at moderate pH values, form gels in concentrated dispersions and can be disassembled by adding reducing agents.     

Turbulent shear layers in confining channels

We present a simple model for the development of shear layers between parallel flows in confining channels. Such flows are important across a wide range of topics from diffusers, nozzles and ducts to urban air flow and geophysical fluid dynamics. The model approximates the flow in the shear layer as a linear profile separating uniform-velocity streams. Both the channel geometry and wall drag affect the development of the flow. The model shows good agreement with both particle image velocimetry experiments and computational turbulence modelling. The simplicity and low computational cost of the model allows it to be used for benchmark predictions and design purposes, which we demonstrate by investigating optimal pressure recovery in diffusers with non-uniform inflow.     

An Improved Bekzomorphan Synthesis

A novel Beckmann rearrangement of the 6-mono-oxime of l-methyl-2,3-benzobicyclo[3.2.1]octan-4,6-dione provides the basis for a much improved synthesis of benzomorphans.     

Multimodal Interaction with BCL-2 Family Proteins Underlies the Proapoptotic Activity of PUMA BH3

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