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51.
Jena Sudipta Ray Asit Sahoo Ambika Kamila Pradeep Kumar Nayak Sanghamitra Panda Pratap Chandra 《Chemistry of Natural Compounds》2021,57(6):1147-1149
Chemistry of Natural Compounds - 相似文献
52.
Sarata Kumar Sahoo Yuji Nakamura Kunio Shiraishi Akimasa Masuda 《International journal of environmental analytical chemistry》2013,93(12):919-926
A chemical and mass-spectrometric procedure for uranium isotopic analysis using a thermal ionisation mass spectrometer equipped with a Wide Aperture Retardation Potential energy filter has been developed and applied to uranium isotopic measurements for various soil samples. Soil samples were digested using a microwave digestor. Uranium was isolated from soil samples by the chemical separation procedure based on the use of anion-exchange resin and UTEVA extraction chromatography column. The isotope ratios were measured for two certified reference materials by using a VG Sector 54-30 thermal ionisation mass spectrometer in dynamic mode with Faraday cup and Daly ion counting system. Replicates of standard reference materials showed excellent analytical agreement with established values supporting the reliability and accuracy of the method. Precision of the 235U/238U ratio was achieved by a correction factor of 0.22% amu as a function of ion-beam intensity with sample loads of around 250?ng of U. The resulting reproducibility for standards and soil samples was better than 0.2% at two standard deviations (SD). Uranium isotopic compositions have been determined in several reference soil samples such as Buffalo river sediment, NIST 2704, river sediment SRM 4350b and ocean sediment NIST-4357 and a Chernobyl soil sample. There was a significant deviation from the natural uranium in comparison with Chernobyl soil samples. 相似文献
53.
54.
One of the long standing problems in quantum chemistry had been the inability to exploit full spatial and spin symmetry of an electronic Hamiltonian belonging to a non‐Abelian point group. Here, we present a general technique which can utilize all the symmetries of an electronic (magnetic) Hamiltonian to obtain its full eigenvalue spectrum. This is a hybrid method based on Valence Bond basis and the basis of constant z‐component of the total spin. This technique is applicable to systems with any point group symmetry and is easy to implement on a computer. We illustrate the power of the method by applying it to a model icosahedral half‐filled electronic system. This model spans a huge Hilbert space (dimension 1,778,966) and in the largest non‐Abelian point group. The C60 molecule has this symmetry and hence our calculation throw light on the higher energy excited states of the bucky ball. This method can also be utilized to study finite temperature properties of strongly correlated systems within an exact diagonalization approach. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2012 相似文献
55.
56.
An innovative conductometric measurement technique using a nonconventional but high‐performance (high‐precision, high‐resolution, rapid response features for online graphic display) in house–built pulsating conductivity monitoring instrument has been deployed to study the kinetic behavior during the reaction of ethyl acetate and NaOH. A laboratory‐made constant temperature reaction bath with the facility of continuous stirring of solution for homogeneous mixing was used to carry out experiments at desired solution temperatures. Rate constants of the saponification reaction in the temperature range at various temperatures (30–55°C) were determined, and the results were compared with the reported values. Although the reported data exhibit wide scatter, our data are in agreement with some of the literature data. From these data, thermodynamic parameters such as activation energy, activation enthalpy, activation entropy, and activation free energy have been evaluated. With the introduction of this novel conductometric measurement technique, the determination of rate constants at various solution temperatures becomes much simpler and faster. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 648–656, 2011 相似文献
57.
Ch.?Binek P.?Borisov Xi?Chen A.?Hochstrat S.?Sahoo W.?KleemannEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2005,45(2):197-201
Perpendicular exchange bias (PEB) involving perpendicular
magnetic anisotropy (PMA) in both the antiferromagnetic (AF) pinning and the
ferromagnetic (FM) sensor layer is expected to become important in future
perpendicular recording and sensing devices. Further, because of the reduced
spin dimensionality, PEB promises to be easier understandable than the
conventional planar exchange bias (EB). In addition to its first realization
using the Ising-type AF compounds FeF2 and FeCl2 we have tested
control strategies of EB being alternative to the conventional magnetic and
thermal ones. Indeed, specific symmetry properties of the pinning layer have
been shown to enable mechanical (viz. piezomagnetic via FeF2) and electric
control (viz. magneto-electric via Cr2O3) of EB, respectively.
Electric control promises to become relevant for TMR devices in MRAM
technology. 相似文献
58.
C.?SurEmail author B. K.?Sahoo R. K.?Chaudhuri B. P.?Das D.?Mukherjee 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2005,32(1):25-31
We have employed the relativistic coupled cluster theory to calculate
the magnetic dipole and electric quadrupole hyperfine constants for
the ground and low lying excited states of singly ionized magnesium.
Comparison with experimental and the other theoretical results are
done and predictions are also made for a few low lying excited states
which could be of interest. We have made comparative studies of the
important many body effects contributing to the hyperfine constants
for the different states of the ion. 相似文献
59.
Braunisch H Habashy TM Sinha BK Pabon J Kong JA 《The Journal of the Acoustical Society of America》2004,115(1):269-279
The problem of inferring unknown geometry and material parameters of a waveguide model from noisy samples of the associated modal dispersion curves is considered. In a significant reduction of the complexity of a common inversion methodology, the inner of two nested iterations is eliminated: The approach described does not employ explicit fitting of the data to computed dispersion curves. Instead, the unknown parameters are adjusted to minimize a cost function derived directly from the determinant of the boundary condition system matrix. This results in an efficient inversion scheme that, in the case of noise-free data, yields exact results. Multimode data can be simultaneously processed without extra complications. Furthermore, the inversion scheme can accommodate an arbitrary number of unknown parameters, provided that the data have sufficient sensitivity to these parameters. As an important application, we consider the sonic guidance condition for a fluid-filled borehole in an elastic, homogeneous, and isotropic rock formation for numerical forward and inverse dispersion analysis. We investigate numerically the parametric inversion with errors in the model parameters and the influence of bandwidth and noise, and examine the cases of multifrequency and multimode data, using simulated flexural and Stoneley dispersion data. 相似文献
60.
The reaction of [Cp*MoCl(4)] with an excess of LiBH(4), followed by thermolysis with tellurium powder in toluene, afforded a tricapped cubane cluster, [(Cp*Mo)(4)B(4)H(4)(μ(4)-BH)(3)] (1), which represents an unprecedented metal-rich metallaborane cluster with a cubane core containing 58 cluster valence electrons (cve) and three metal-metal bonds. 相似文献