Highly stereoselective synthesis of peracylated α-aldopyranosyl chlorides from aldopyranose peracetates and thionyl chloride catalyzed by BiCl3 generated in situ from the procatalyst BiOCl

Aldopyranose peracetates react with thionyl chloride and BiCl₃, generated in situ from a substoichiometric amount of the procatalyst BiOCl, producing the corresponding peracylated aldopyranosyl chlorides in very good to excellent yields (82–97%) with exclusive α-anomeric selectivity.     

Fluctuation study of pionisation in ultrarelativistic nucleus-nucleus interaction

The scaled factorial moments and the multifractal moments have been investigated in differentη-intervals to study the dynamical fluctuation of pions produced in 200 AGeV³²S-Ag/Br interaction. In order to investigate the detail characteristics of intermittency behaviour, theF-moments are extracted up to the eighth order of moments in differentM-intervals. The analysis indicates a non-thermal phase transition and different regime of particle production during the hadronisation process.     

Gamma ray photon-induced modifications in Triafol-TN and Triafol-BN polymeric track detectors

Photon induced modifications in Triafol-TN and Triafol-BN polymers have been studied in the dose range of 10¹–10⁶ Gy at room temperature using a ⁶⁰Co source. To monitor the chemical and structural changes induced by gamma rays, UV, IR, and ESR studies were carried out. Thermal studies were also conducted for understanding the effects of gamma irradiations on these polymers. Variation of track etching characteristics and activation energy for bulk etching have been studied at different gamma rays doses. The experimental results are presented and discussed.     

Flicker noise in degenerately doped Si single crystals near the metal-insulator transition

In this paper we report some of the important results of experimental investigations of the flicker noise near the metal-insulator (MI) transition in doped silicon single crystals. This is the first comprehensive work to study low-frequency noise in heavily doped Si over an extensive temperature range (2 K<T<500 K). The measurements of conductance fluctuations (flicker noise) were carried out in the frequency range 10⁻²<f<4 × 10¹ Hz in single crystalline Si across the MI transition by doping with phosphorous and boron. The magnitude of noise in heavily doped Si is much larger than that seen in lightly doped Si over the whole temperature range. The extensive temperature range covered allowed us to detect two distinct noise mechanisms. At low temperatures (T<100 K) universal conductance fluctuations (UCF) dominate and the spectral dependence of the noise is determined by dephasing the electron from defects with two-levels (TLS). At higher temperatures (T>200 K) the noise arises from activated defect dynamics. As the MI transition is approached, the 1/f spectral power, typical of the metallic regime, gets modified by the presence of discrete Lorentzians which arise from generation-recombination process which is the characteristic of a semiconductor.     

超模的同构定理

本文利用模论导出超模的三个同构定理,同时,给出超模的Jordan-Holder定理,最后,探讨了超模的基本关系∈~*,并研究其性质．     

Environment-induced decoherence II. Effect of decoherence on Bell''s inequality for an EPR pair

According to Bell's theorem, the degree of correlation between spatially separated measurements on a quantum system is limited by certain inequalities if one assumes the condition of locality. Quantum mechanics predicts that this limit can be exceeded, making it nonlocal. We analyse the effect of an environment modelled by a fluctuating magnetic field on the quantum correlations in an EPR singlet as seen in the Bell inequality. We show that in an EPR setup, the system goes from the usual ‘violation’ of Bell's inequality to a ‘non-violation’ for times larger than a characteristic time scale which is related to the parameters of the fluctuating field. We also look at these inequalities as a function of the spatial separation between the EPR pair.     

Effect of benzophenone on the H2O2-induced photopolymerization of methyl methacrylate

Benzophenone (BP) in low concentrations (<0.001 mol 1^?1) produces a rate enhancing effect in the H₂O₂-induced bulk photopolymerization of MMA. R_p is proportional to [H₂O₂]^0.4 and [BP]^0.4, and $\text{k}{}_{\mathrm{p}}{}^2\text{k}{}_1$ at 30° is 1.00 × 10^?2 1.mol^?1 sec^?1. In diluted systems, different solvents produce different kinetic effects, reaction order with respect to monomer being negative for IPA and THF as solvent, positive but <1.0 for benzene and chloroform, 1.2 for acetonitrile, CCl₄ and t-butanol and 1.8 for DMA. The variable solvent effect is attributed to modification of the initiation process by the various solvents to different extents. Kinetic analysis of data for bulk photopolymerization gives evidence for primary radical termination and degradative initiator transfer.     

Mixed micellization of an anionic gemini surfactant (GA) with conventional polyethoxylated nonionic surfactants in brine solution at pH 5 and 298 K

The micellization behavior of an anionic gemini surfactant, GA with nonionic surfactants C₁₂E₈ and C₁₂E₅ in presence of 0.1 M NaCl at 298 K temperature, has been studied tensiometrically in pure and mixed states, and the related physicochemical parameters (cmc, γ _cmc, pC ₂₀, Γ _max, and A _min) have been evaluated. Tensiometric profile (γ vs log [surfactant]), for conventional surfactants, generally consists of a single point of intersection; a gradually decreasing line (normally linear, or with slight curvature) ultimately saturates in γ at a particular [surfactant], corresponding to complete monolayer saturation. The gemini, in this report, led to two unequivocal breaks in the tensiometric isotherm. An attempt to the interpretation of the two breaks from molecular point of view is provided, depending solely on the chemical structure of the surfactant. The gemini, even in mixed state with the conventional nonionic surfactants C₁₂E₅ and C₁₂E₈, manifested the dual breaks; of course, the dominance of the feature decreases with increasing mole fraction of the nonionics in the mixture. Theories of Clint, Rosen, Rubingh, Motomura, Georgiev, Maeda, and Nagarajan have been used to determine the interaction between surfactants at the interface and micellar state of aggregation, the composition of the aggregates, the theoretical cmc in pure and mixed states, and the structural parameters according to Tanford and Israelachvili. Several thermodynamic parameters have also been predicted from those theories.