全文获取类型
收费全文 | 1385篇 |
免费 | 61篇 |
国内免费 | 4篇 |
专业分类
化学 | 972篇 |
晶体学 | 10篇 |
力学 | 45篇 |
数学 | 147篇 |
物理学 | 276篇 |
出版年
2023年 | 6篇 |
2022年 | 11篇 |
2021年 | 15篇 |
2020年 | 22篇 |
2019年 | 23篇 |
2018年 | 13篇 |
2017年 | 10篇 |
2016年 | 33篇 |
2015年 | 34篇 |
2014年 | 62篇 |
2013年 | 75篇 |
2012年 | 77篇 |
2011年 | 104篇 |
2010年 | 45篇 |
2009年 | 48篇 |
2008年 | 97篇 |
2007年 | 86篇 |
2006年 | 80篇 |
2005年 | 65篇 |
2004年 | 56篇 |
2003年 | 35篇 |
2002年 | 40篇 |
2001年 | 15篇 |
2000年 | 26篇 |
1999年 | 18篇 |
1998年 | 13篇 |
1997年 | 9篇 |
1996年 | 16篇 |
1995年 | 11篇 |
1994年 | 11篇 |
1993年 | 15篇 |
1992年 | 6篇 |
1991年 | 9篇 |
1990年 | 13篇 |
1989年 | 13篇 |
1988年 | 12篇 |
1987年 | 10篇 |
1985年 | 13篇 |
1984年 | 12篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 14篇 |
1980年 | 17篇 |
1979年 | 16篇 |
1978年 | 11篇 |
1977年 | 15篇 |
1976年 | 7篇 |
1975年 | 7篇 |
1974年 | 19篇 |
1973年 | 12篇 |
排序方式: 共有1450条查询结果,搜索用时 640 毫秒
41.
42.
Robert Tchitnga Hilaire Bertrand Fotsin Bonaventure Nana Patrick Hervé Louodop Fotso Paul Woafo 《Chaos, solitons, and fractals》2012,45(3):306-313
This paper shows an experimental evidence of chaos in one of the simplest imaginable autonomous implicit Hartley’s oscillator made simply of a junction field effect transistor (JFET) and a tapped coil. The experimental setup is implemented. The variations of amplitude of the oscillations through the control element are obtained showing the domain of existence of chaos. Phase portraits of the PSpice simulation, of the numerical integration and of the experiment are displayed, confirming a good agreement between theory and praxis. 相似文献
43.
44.
45.
Rik H. Verschueren Julie Schmauck Dr. Michael S. Perryman Dr. Hui-Lan Yue Julian Riegger Dr. Bertrand Schweitzer-Chaput Dr. Martin Breugst Dr. Martin Klussmann 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(38):9088-9097
In this work, the reactivities of acetonyl and benzoyl radicals in aromatic substitution and addition reactions have been compared in an experimental and computational study. The results show that acetonyl is more electrophilic than benzoyl, which is rather nucleophilic. A Hammett plot analysis of the addition reactions of the two radicals to substituted styrenes clearly support the nucleophilicity of benzoyl, but in the case of acetonyl, no satisfactory linear correlation with a single substituent-related parameter was found. Computational calculations helped to rationalize this effect, and a good linear correlation was found with a combination of polar parameters (σ+) and the radical stabilization energies of the formed intermediates. Based on the calculated philicity indices for benzoyl and acetonyl, a quantitative comparison of these two radicals with many other reported radicals is possible, which may help to predict the reactivities of other aromatic radical substitution reactions. 相似文献
46.
We consider a pricing and advertising dynamic-optimization problem where the goodwill dynamics evolve à la Nerlove–Arrow. The firm maximizes its profit over a finite-planning horizon corresponding to the product’s lifespan, and it turns out that the Hamiltonian is non-concave. We show the existence and uniqueness of an optimal solution under some mild conditions. 相似文献
47.
Camille Piovesan Anne-Laurence Dupont Isabelle Fabre-Francke Odile Fichet Bertrand Lavédrine Hervé Chéradame 《Cellulose (London, England)》2014,21(1):705-715
Two di-alkoxysilanes, with (AMDES, aminopropylmethyldiethoxysilane) or without (DMDES, dimethyldiethoxysilane) an amine function, and a tri-alkoxy aminosilane (APTES, aminopropyltriethoxysilane) as well as their mixtures were introduced in paper as fiber strengthening agents. The polymerization and copolymerization of these polysiloxanes in the paper were investigated. In all the cases where APTES was present, the formation of networks was established by measuring the soluble fraction amount extracted from the treated papers. A slight decrease of the opacity of the paper sheets when AMDES was part of the treatment was noted. The presence of APTES reduced this opacity loss. The study of the physicochemical properties of the treated paper (mechanical strength and alkalinity) demonstrated that, besides the required deacidification feature, the different treatments allowed an efficient strengthening of the cellulose fibers to various extents. Contact angle measurements indicated a decrease of the hydrophilic character of papers treated with the mixture APTES/AMDES and the occurrence of a hydrophobic character of the papers treated with APTES alone. These results were consistently obtained for both spray and immersion treatment processes. 相似文献
48.
49.
50.
Dr. Benoît Bertrand Dr. Candice Botuha Jérémy Forté Dr. Héloïse Dossmann Dr. Michèle Salmain 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(56):12846-12861
The two independent and coordination sites of a newly synthesized bis[2-(hydroxyphenyl)-1,2,4-triazole] platform have been exploited to prepare four monometallic neutral ()PtII complexes carrying DMSO, pyridine, triphenylphosphine, or N-heterocyclic carbene as the fourth ligand. Then, the second coordination site was used to introduce an IR-active rhenium tricarbonyl entity, affording the four corresponding heterobimetallic neutral PtII/ReI complexes, as well as a cationic PtII/ReI derivative. X-ray crystallographic studies showed that distortion of the organic platform occurred to accommodate the coordination geometry of both metal centers. No ligand exchange or transchelation occurred upon incubation of the PtII complexes in aqueous environment or in the presence of FeIII, respectively. The antiproliferative activity of the ligand and complexes was first screened on the triple-negative breast cancer cell line MDA-MB-231. Then, the IC50 values of the most active candidates were determined on a wider panel of human cancer cells (MDA-MB-231, MCF-7, and A2780), as well as on a nontumorigenic cell line (MCF-10A). Low micromolar activities were reached for the complexes carrying a DMSO ligand, making them the first examples of highly active, but hydrolytically stable, PtII complexes. Finally, the characteristic mid-IR signature of the {Re(CO)3} fragment in the Pt/Re heterobimetallic complexes was used to quantify their uptake in breast cancer cells. 相似文献