全文获取类型
收费全文 | 3819篇 |
免费 | 139篇 |
国内免费 | 19篇 |
专业分类
化学 | 2818篇 |
晶体学 | 10篇 |
力学 | 71篇 |
数学 | 523篇 |
物理学 | 555篇 |
出版年
2021年 | 37篇 |
2020年 | 41篇 |
2019年 | 51篇 |
2018年 | 33篇 |
2017年 | 21篇 |
2016年 | 82篇 |
2015年 | 106篇 |
2014年 | 76篇 |
2013年 | 145篇 |
2012年 | 186篇 |
2011年 | 228篇 |
2010年 | 159篇 |
2009年 | 109篇 |
2008年 | 223篇 |
2007年 | 208篇 |
2006年 | 206篇 |
2005年 | 201篇 |
2004年 | 137篇 |
2003年 | 114篇 |
2002年 | 119篇 |
2001年 | 65篇 |
2000年 | 74篇 |
1999年 | 69篇 |
1998年 | 64篇 |
1997年 | 67篇 |
1996年 | 63篇 |
1995年 | 60篇 |
1994年 | 60篇 |
1993年 | 70篇 |
1992年 | 59篇 |
1991年 | 29篇 |
1990年 | 37篇 |
1989年 | 28篇 |
1988年 | 32篇 |
1987年 | 44篇 |
1986年 | 38篇 |
1985年 | 59篇 |
1984年 | 29篇 |
1983年 | 33篇 |
1982年 | 48篇 |
1981年 | 18篇 |
1980年 | 42篇 |
1978年 | 32篇 |
1977年 | 38篇 |
1976年 | 23篇 |
1974年 | 21篇 |
1973年 | 21篇 |
1972年 | 21篇 |
1971年 | 20篇 |
1969年 | 21篇 |
排序方式: 共有3977条查询结果,搜索用时 15 毫秒
991.
[reaction: see text] The application of vinyloxiranes, substituted with an electron-withdrawing group, as masked dienolates in vinylogous imino-aldol reactions was achieved. Under the reaction conditions highly substituted 1,2-dihydropyridines were obtained in moderate to good yields. Mechanistic studies indicate that the reaction proceeds via the formation of an (E)-amino-alpha,beta-unsaturated aldehyde, followed by isomerization to the (Z)-isomer, cyclization, and elimination of a water molecule, leading to the formation of the 1,2-dihydropyridine. 相似文献
992.
A sequential kinetic resolution catalyzed by halohydrin dehalogenase was employed for the synthesis of two valuable enantiopure building blocks. Resolution of methyl 4-chloro-3-hydroxybutanoate methylester ((R,S)-2) with use of a Trp249Phe mutant of halohydrin dehalogenase yielded methyl 4-cyano-3-hydroxybutanoate methylester ((S)-4) with 96.8% ee (40% yield) and (S)-2 with 95.2% ee (41% yield). This reaction is carried out in aqueous solution under mild conditions and provides access to a useful statin side-chain building block. 相似文献
993.
The characterization and control of the phase of broadband femtosecond pulses in nonlinear microscopy are successfully demonstrated with a collinear configuration of spectral shear interferometry for direct electric field reconstruction (SPIDER). A femtosecond-pulse shaper is used as a dispersionless interferometer for the measurement of the spectral phase and to actively compress a broadband supercontinuum from a photonic crystal fiber. This allows in situ online phase management and enables the application of quantum control spectroscopy in microenvironments. 相似文献
994.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Agelou M Agram JL Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Andeen T Anderson S Andrieu B Anzelc MS Arnoud Y Arov M Askew A Asman B Assis Jesus AC Atramentov O Autermann C Avila C Ay C Badaud F Baden A Bagby L Baldin B Bandurin DV Banerjee P Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Begalli M Begel M Belanger-Champagne C Bellantoni L Bellavance A 《Physical review letters》2006,97(15):151804
We present a search for associated Higgs boson production in the process pp-->WH-->WWW*-->l;+/-nul'+/-nu'+X in final states containing two like-sign isolated electrons or muons (e+/-e;+/-, e+/-micro+/-, or micro+/-micro+/-). The search is based on D0 run II data samples corresponding to integrated luminosities of 360-380 pb-1. No excess is observed over the predicted standard model background. We set 95% C.L. upper limits on sigma(pp-->WH)xBr(H-->WW*) between 3.2 and 2.8 pb for Higgs boson masses from 115 to 175 GeV. 相似文献
995.
Let be a prime, and k=(p+1)/2. In this paper we prove that two things happen if and only if the class number . One is the non-integrality at p of a certain trace of normalised critical values of symmetric square L-functions, of cuspidal Hecke eigenforms of level one and weight k. The other is the existence of such a form g whose Hecke eigenvalues satisfy “dihedral” congruences modulo a divisor of p (e.g. p=23, k=12, g=Δ). We use the Bloch-Kato conjecture to link these two phenomena, using the Galois interpretation of the congruences to produce global torsion elements which contribute to the denominator of the conjectural formula for an L-value. When , the trace turns out always to be a p-adic unit. 相似文献
996.
The Ramanujan Journal - Kostant proved that the mth coefficient of the $$(r^2-1)$$ th power of the Dedekind eta function is non-vanishing for $$r \ge \mathsf {max} \{4,m \}$$ and r an... 相似文献
997.
Panagiotou and Stufler recently proved an important fact on their way to establish the scaling limits of random Pólya trees: a uniform random Pólya tree of size consists of a conditioned critical Galton–Watson tree and many small forests, where with probability tending to one, as tends to infinity, any forest , that is attached to a node in , is maximally of size . Their proof used the framework of a Boltzmann sampler and deviation inequalities.In this paper, first, we employ a unified framework in analytic combinatorics to prove this fact with additional improvements for , namely . Second, we give a combinatorial interpretation of the rational weights of these forests and the defining substitution process in terms of automorphisms associated to a given Pólya tree. Third, we derive the limit probability that for a random node the attached forest is of a given size. Moreover, structural properties of those forests like the number of their components are studied. Finally, we extend all results to other Pólya structures. 相似文献
998.
The piston rod of a reciprocating compressor is sealed with elastic cylindrical sealing elements. Across the sealings the pressure drops from the operating pressure to the ambient pressure. The lubrication gap between the elastic sealing and reciprocating piston rod is studied with the aim to find conditions of a leakage free sealing. The flow in the lubrication gap and the elastic deformation of the sealing are determined simultaneously. The netflow during one cycle of the reciprocating piston rod is calculated. It turns out that maintaining zero leakage is very sensible. Indeed the outbound flow during out-stroke has to be equal the inbound flow during the instroke. By prescribing a special shape of the undeformed sealing zero leakage can be attained — at least theoretically for certain operating conditions. It turns out that temperature dependent material data and a model for cavitation is necessary. The model, its numerical implementation and results will be discussed. (© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
999.
Bernhard H. Haak 《Complex Analysis and Operator Theory》2010,4(2):281-299
In Ho and Russell (SIAM J Control Optim 21(4):614–640, 1983), and Weiss (Syst Control Lett 10(1): 79–82, 1988), a Carleson
measure criterion for admissibility of one-dimensional input elements with respect to diagonal semigroups is given. We extend
their results from the Hilbert space situation (L
2-admissibility on the state space ℓ
2) to the more general situation of L
p
-admissibility on the state space ℓ
q
. For analytic diagonal semigroups we present a new result that does not rely on Laplace transform methods. A comparison of
both criteria leads to a result on L
p
-admissibility for reciprocal systems in the sense of Curtain (Syst Control Lett 49(2):81–89, 2003). 相似文献
1000.
Daniele Cassani Bernhard Ruf Cristina Tarsi 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2010
We study optimal embeddings for the space of functions whose Laplacian Δu belongs to L1(Ω), where Ω⊂RN is a bounded domain. This function space turns out to be strictly larger than the Sobolev space W2,1(Ω) in which the whole set of second-order derivatives is considered. In particular, in the limiting Sobolev case, when N=2, we establish a sharp embedding inequality into the Zygmund space Lexp(Ω). On one hand, this result enables us to improve the Brezis–Merle (Brezis and Merle (1991) [13]) regularity estimate for the Dirichlet problem Δu=f(x)∈L1(Ω), u=0 on ∂Ω; on the other hand, it represents a borderline case of D.R. Adams' (1988) [1] generalization of Trudinger–Moser type inequalities to the case of higher-order derivatives. Extensions to dimension N?3 are also given. Besides, we show how the best constants in the embedding inequalities change under different boundary conditions. 相似文献