全文获取类型
收费全文 | 4170篇 |
免费 | 87篇 |
国内免费 | 22篇 |
专业分类
化学 | 2699篇 |
晶体学 | 25篇 |
力学 | 161篇 |
数学 | 651篇 |
物理学 | 743篇 |
出版年
2021年 | 27篇 |
2020年 | 31篇 |
2019年 | 33篇 |
2018年 | 39篇 |
2017年 | 38篇 |
2016年 | 61篇 |
2015年 | 73篇 |
2014年 | 86篇 |
2013年 | 231篇 |
2012年 | 170篇 |
2011年 | 199篇 |
2010年 | 124篇 |
2009年 | 116篇 |
2008年 | 171篇 |
2007年 | 165篇 |
2006年 | 178篇 |
2005年 | 196篇 |
2004年 | 160篇 |
2003年 | 147篇 |
2002年 | 159篇 |
2001年 | 67篇 |
2000年 | 72篇 |
1999年 | 65篇 |
1998年 | 48篇 |
1997年 | 73篇 |
1996年 | 78篇 |
1995年 | 67篇 |
1994年 | 56篇 |
1993年 | 60篇 |
1992年 | 53篇 |
1991年 | 54篇 |
1990年 | 39篇 |
1989年 | 44篇 |
1988年 | 35篇 |
1987年 | 33篇 |
1985年 | 81篇 |
1984年 | 64篇 |
1983年 | 51篇 |
1982年 | 67篇 |
1981年 | 73篇 |
1980年 | 54篇 |
1979年 | 67篇 |
1978年 | 68篇 |
1977年 | 79篇 |
1976年 | 52篇 |
1975年 | 53篇 |
1974年 | 50篇 |
1973年 | 38篇 |
1971年 | 36篇 |
1968年 | 27篇 |
排序方式: 共有4279条查询结果,搜索用时 739 毫秒
91.
Bernard R. Brooks Duanka Janei
Martin Karplus 《Journal of computational chemistry》1995,16(12):1522-1542
Methods have been developed for the determination of vibrational frequencies and normal modes of large systems in the full conformational space (including all degrees of freedom) and in a reduced conformational space (reducing the number of degrees of freedom). The computational method, which includes Hessian generation and storage, full and iterative diagonalization techniques, and the refinement of the results, is presented. A method is given for the quasiharmonic analysis and the reduced basis quasiharmonic analysis. The underlying principle is that from the atomic fluctuations, an effective harmonic force field can be determined relative to the dynamic average structure. Normal mode analysis tools can be used to characterize quasiharmonic modes of vibration. These correspond to conventional normal modes except that anharmonic effects are included. Numerous techniques for the analyses of vibrational frequencies and normal modes are described. Criteria for the analysis of the similarity of low-frequency normal modes is presented. The approach to determining the natural frequencies and normal modes of vibration described here is general and applicable to any large system. © 1995 John Wiley & Sons, Inc. 1 This article is a U.S. Government work and, as such, is in the public domain in the United States of America. 相似文献
92.
The Dunford-Pettis property is shown to hold for the uniformalgebra A() and its dual for some standard domains , includingstrongly pseudoconvex bounded domains in Cn, pseudoconvex boundeddomains of finite type in C2, and bounded domains in C. Previouslythe result was known for the unit ball and unit polydisc inCn. Techniques used involve Bourgain algebras, Hankel operators,properties of the Bergman kernel, quasi-metrics on the boundary,and -theory. 相似文献
93.
94.
95.
96.
V. Bernard N. Kaiser Ulf -G. Meißner A. Schmidt 《Zeitschrift für Physik A Hadrons and Nuclei》1994,348(4):317-325
We consider the spin-averaged nucleon forward Compton scattering amplitude in heavy baryon chiral perturbation theory including all terms to order
. The chiral prediction for the spin-averaged forward Compton scattering amplitude is in good agreement with the data for photon energies110 MeV. We also evaluate the nucleon electric and magnetic Compton polarizabilities to this order and discuss the uncertainties of the various counter terms entering the chiral expansion of these quantities. 相似文献
97.
For the zero-temperature Glauber dynamics of theq-state Potts model, the fractionr(q, t) of spins which never flip up to timet decays like a power lawr(q, t)t
–(q)
when the initial condition is random. By mapping the problem onto an exactly soluble one-species coagulation model (A+AA) or alternatively by transforming the problem into a free-fermion model, we obtain the exact expression of (q) for all values ofq. The exponent (q) is in general irrational, (3)=0.53795082..., (4)=0.63151575..., ..., with the exception ofq=2 andq=, for which (2)=3/8 and ()=1. 相似文献
98.
Bernard Helffer 《Letters in Mathematical Physics》1996,38(3):297-312
This Letter gives detailed proofs concerning the analysis of the pair correlations for a nonconvex model. Using the transfer matrix approach, the problem is reduced to the analysis of the spectral properties of this transfer operator. Although the problem is similar to the semiclassical study of the Kac operator presented in a paper with M. Brunaud, which was devoted to the study of exp-(v/2) exp h
2 exp-(v/2) for h small, new features appear for the model exp-(v/2h) exp h exp-(v/2h). Our principal results concern the splitting of this operator between the two largest eigenvalues. We give an upper and a lower bound for this splitting in the semi-classical regime. As a corollary, we get good control of the decay of the pair correlation. Some of the results were announced in a previous paper. Related WKB constructions will be developed in a later paper.Inspired by papers by M. Kac [15, 16]. 相似文献
99.
Delangle P Dutasta JP Van Oostenryck L Tinant B Declercq JP 《The Journal of organic chemistry》1996,61(25):8904-8914
The semirigid phosphonamide ligands 1-5 have been synthesized from the macrocyclic precursors 6-9 by reaction with 1,3-propanediol ditosylate or 1,2-dichloroethane. For the thiophosphoryl compounds 1 and 2, and the phosphoryl derivative 5, the reactions were carried out in biphasic aqueous NaOH solutions. The phosphoryl derivatives 3 and 4 were better obtained from NaH in anhydrous tetrahydrofuran. The conformations of the hosts in solution were deduced from low-temperature NMR and NOE difference experiments. Conformational equilibria between exo and endo forms are observed for the 18-membered macrocycles 1 and 3. The exo conformer predominates in solution for the 21-membered macrocycle 2, whereas 4 exists as rapidly exchanging conformers. The X-ray crystal structures of macrocycles 1, 2, and 5 have been determined as well as the complexes 1.Hg(SCN)(2) and 5.LiNO(3). In the Hg(2+) complex the metal ion is located out of the macrocyclic cavity and is coordinated to the thiophosphoryl unit. In 5.LiNO(3)()()the Li(+) cation is located inside the macrocyclic cavity and is coordinated to a tetrahedral array of oxygen donors. Free energies of complexation (DeltaG degrees ) of the phosphorylated ligands 3-5 with alkali metal and ammonium cations were determined in CHCl(3) saturated with H(2)O by picrate extraction experiments. The -DeltaG degrees values are greatest for 4 complexing K(+) and NH(4)(+) (7.3 and 8.0 kcal/mol, respectively). The relationships between structure and binding are discussed. 相似文献
100.