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41.
Virgil Percec Cristian Grigoras Tushar K. Bera Bogdan Barboiu Philippe Bissel 《Journal of polymer science. Part A, Polymer chemistry》2005,43(20):4894-4906
Our laboratory has reported the elaboration of an iterative strategy for the synthesis of dendritic macromolecules from conventional monomers. This synthetic method involves a combination of self‐regulated metal‐catalyzed living radical polymerization initiated from arenesulfonyl chlorides and an irreversible terminator multifunctional initiator (TERMINI). The previous TERMINI, (1,1‐dimethylethyl)[[1‐[3,5‐bis(S‐phenyl‐4‐N,N′ diethylthiocarbamate)phenyl]ethenyl]oxy]dimethylsilane, was prepared in nine reaction steps. The replacement of the previous TERMINI with one that requires only three steps for its synthesis, diethylthiocarbamic acid S‐{3‐[1‐(tert‐butyl‐dimethyl‐silanyloxy)‐vinyl]‐5‐diethylcarbamoylsulfanyl‐phenyl} ester, and the use of the more reactive Cu2S/2,2′‐bipyridine rather than the Cu2O/2,2′‐bipyridine self‐regulated catalyst have generated an accelerated method for the synthesis of dendritic macromolecules. This method provides rational design strategies for the synthesis of dendritic macromolecules with different compaction by the use of a single monomer. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4894–4906, 2005 相似文献
42.
A. K. Sen R. Bera P. K. Karmakar 《International Journal of Infrared and Millimeter Waves》1997,18(11):2233-2257
The use of Ka Band (20/30 GHz) for future satellite communications has been addressed. The exploitation of Ka band with a
bandwidth of 2500 MHz seems to represent the largest significant achievement in satellite communications potential, so far.
The problems associated with the use of this frequency band such as attenuation and receiver noise temperature (floor) variation
with rain has been addressed. The receiver noise floor variation with rain has so far been ignored. Therefore, in view of
propagation and noise study over this Ka Band, both signal attenuation and receiver noise floor variations with rain rate
are estimated using dual frequency radiometers operating at 22.235 and 31.4 GHz over a tropical station, Calcutta, India. 相似文献
43.
A rigorous derivation of the optical theorem (OT) from the conservation of probability flux (CPF) is presented for scattering
on an arbitrary spherically symmetric potential inN-spatial dimensions (ND). The constructed expression for the OT is found to yield the corresponding well-known results for
two- and three-dimensional cases in a rather natural way. The Aharonov-Bohm (AB) effect is considered as a scattering event
of an electron by a magnetic field confined in an infinitely long shielded solenoid and a similar derivation is attempted
for an appropriate optical theorem. Our current understanding of the scattering theory is found to be inadequate for the purpose.
The reason for this is discussed in some detail. 相似文献
44.
45.
Rajendra K. Bera 《国际流体数值方法杂志》1989,9(3):251-262
Theodorsen's method for calculating the incompressible potential flow past an aerofoil is viewed afresh. It is found that some simple modifications to the computational process make the computations relatively faster, easier and more accurate. The new modifications are applicable to the analysis of conventional aerofoils with up to moderate thickness and camber ratios. Several examples are presented to show the effectiveness of the modifications. 相似文献
46.
In this work, an alternative treatment known as Nikiforov–Uvarov (NU) method is proposed to find the exact solutions of the Feinberg–Horodecki equation for the time-dependent potentials. The present procedure is illustrated with two examples: (1) time-dependent Wei Hua oscillator, (2) time-dependent Manning–Rosen potential. 相似文献
47.
Saibal Bera Kaushik Dey Tapan K. Pal Arjun Halder Srinu Tothadi Suvendu Karak Matthew Addicoat Rahul Banerjee 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(13):4287-4291
Porous solids that can be switched between different forms with distinct physical properties are appealing candidates for separation, catalysis, and host–guest chemistry. In this regard, porous organic cages (POCs) are of profound interest because of their solution‐state accessibility. However, the application of POCs is limited by poor chemical stability. Synthesis of an exceptionally stable imine‐linked (4+6) porous organic cage ( TpOMe‐CDA ) is reported using 2,4,6‐trimethoxy‐1,3,5‐triformyl benzene (TpOMe) as a precursor aldehyde. Introduction of the ‐OMe functional group to the aldehyde creates significant steric and hydrophobic characteristics in the environment around the imine bonds that protects the cage molecules from hydrolysis in the presence of acids or bases. The electronic effect of the ‐OMe group also plays an important role in enhancing the stability of the reported POCs. As a consequence, TpOMe‐CDA reveals exceptional chemical stability in neutral, acidic and basic conditions, even in 12 m NaOH. Interestingly, TpOMe‐CDA exists in three different porous and non‐porous polymorphic forms (α, β, and γ) with respect to differences in crystallographic packing and the orientation of the flexible methoxy groups. All of the polymorphs retain their crystallinity even after treatment with acids and bases. All the polymorphs of TpOMe‐CDA differ significantly in their properties as well as morphology and could be reversibly switched in the presence of an external stimulus. 相似文献
48.
Mukesh Kumar Alaria A. K. Sinha A. Bera V. Srivastava 《International Journal of Infrared and Millimeter Waves》2008,29(12):1083-1090
The main objective of the paper is to make an efficient design of the input and output coaxial coupler for a helix TWTs. An
approach has been developed for the efficient design and analysis of the coaxial couplers in the practical situation. Normally
multi-section impedance transformer approach is used for any wide band coupler. For a space helix TWT, coupler should be wide
bandwidth and small size. In this case coupler is matched with helix slow wave structure and the standard 50-ohm connectors.
The simulated return loss (dB) profile for different type of couplers is obtained by using Ansoft HFSS, CST microwave studio
and compares those with experimental results. The tip loss design at sever ends for the input and the output section has been
also optimized. 相似文献
49.
Shyam Sundar Mondal Namita Jaiswal Partha Sarathi Bera Ranjay K. Tiwari Jogendra Nath Behera Nripen Chanda Subhas Ghosal Tanmoy Kumar Saha 《应用有机金属化学》2021,35(1)
A series of copper (II) ( 1 and 3 ) and cobalt (II/III) ( 2 , 4 and 5 ) complexes comprising different imino‐phenolate ligands DCH , DTH and DBH 2 (where DCH = 2,4‐dichloro‐6‐((mesitylimino)methyl)phenol, DTH = 2,4‐di‐tert‐butyl‐6‐((mesitylimino)methyl) phenol and DBH 2 = 2,4‐dibromo‐6‐((mesitylimino)methyl)phenol) have been prepared with excellent yield and high purity. By utilizing different spectroscopic tools such as UV–visible, electrospray ionization (ESI)‐mass, Fourier‐transform infrared (FTIR) spectrometry and elemental analysis, the prepared complexes ( 1 – 5 ) were thoroughly characterized. The molecular structure of the synthesized complexes was ascertained by using single‐crystal X‐ray diffraction studies (SCXRDs). The experiment reveals that Complexes 1 – 5 bind to calf thymus DNA (CT‐DNA) through non‐intercalative way with good interacting abilities. However, 1 – 5 are excellent quenchers of the fluorescence intensity of bovine serum albumin (BSA) following the static pathway. Additionally, they had shown remarkable cytotoxic potential against MCF‐7 (mammary gland adenocarcinoma) and A549 (lung adenocarcinoma) cell lines. The IC50 values associated with these complexes were much lower than the conventional drug cisplatin. Apoptosis‐induced cell death was confirmed from the DNA fragmentation studies and Hoechst 33342 staining. The 2′,7′‐dichlorofluorescein diacetate (DCFDA) assay indicates that the complex mediated reactive oxygen species (ROS) generation is accountable for governing the apoptosis mechanism via oxidative cell distress. Apart from these studies, by carrying out density functional theory (DFT) method, highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) energy gap calculations and optimized structures of the synthesized complexes were accomplished. 相似文献
50.
Tania Chowdhury Kaushik Bera Debabrata Samanta Sandip Dolui Suvendu Maity Nakul C. Maiti Prasanta Kumar Ghosh Debasis Das 《应用有机金属化学》2020,34(4):e5556
Four new zinc (II) complexes [Zn (HL1H)Br2] (1), [Zn (HL1H)Cl2] (2), [Zn2(HL2)Br3] (3), and [Zn (HL2)Cl] (4) have been synthesized by adopting template synthetic strategy and utilizing two homologous Schiff base ligands (H2L1 = 4-bromo-2-{[2-(2-hydroxyethylamino)-ethylimino]-methyl}-6-methoxyphenol, H2L2 = 4-bromo-2-{[3-(2-hydroxyethylamino)propylimino]methyl}-6-methoxyphenol), differing in one -CH2- unit in the ligating backbone, by adopting template synthetic strategy. All the complexes have been characterized by single crystal X-ray diffraction analysis as well as by other routine physicochemical techniques. Ligand mediated structural variations have been observed and rationalized by density functional theoretical (DFT) calculations. Interaction of the complexes 1–4 with Bovine Serum Albumin protein (BSA) has been studied by different spectroscopic techniques. A complete thermodynamic profile (ΔHo, ΔSo and ΔGo) was evaluated initially from the change in absorption and fluorescence spectra upon addition of BSA to the complexes. Appreciable binding constant values in the range ~ 0.94–4.51 × 104 M−1 indicate efficient binding tendency of the complexes to BSA with the sequence 1 ≅ 2 > 3 ≅ 4. Circular dichroism (CD), isothermal calorimetric titration experiments, molecular docking and molecular dynamics have been performed to gain deep insight into the binding regions of complex 1 to BSA. Experimental evidences suggest an interaction of zinc complexes at the surface of BSA protein and this particular binding has been exploited to determine unknown concentration of BSA protein. For this purpose complex 1 was explored as a BSA protein quantification tool. 相似文献