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221.
Hybrid polymer networks (HPNs) based on unsaturated polyester resin (UPR) and epoxy resins were synthesized by reactive blending. The epoxy resins used were epoxidised phenolic novolac (EPN), epoxidised cresol novolac (ECN) and diglycidyl ether of bisphenol A (DGEBA). Epoxy novolacs were prepared by glycidylation of the novolacs using epichlorohydrin. The physical, mechanical, and thermal properties of the cured blends were compared with those of the control resin. Epoxy resins show good miscibility and compatibility with the UPR resin on blending and the co-cured resin showed substantial improvement in the toughness and impact resistance. Considerable enhancement of tensile strength and toughness are noticed at very low loading of EPN. Thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC) were employed to study the thermal properties of the toughened resin. The EPN/UPR blends showed substantial improvement in thermal stability as evident from TGA and damping data. The fracture behaviour was corroborated by scanning electron microscopy (SEM). The performance of EPN is found to be superior to other epoxy resins. 相似文献
222.
Let Fk denote the family of 2-edge-colored complete graphs on 2k vertices in which one color forms either a clique of order k or two disjoint cliques of order k. Bollobás conjectured that for every ?>0 and positive integer k there is n(k,?) such that every 2-edge-coloring of the complete graph of order n?n(k,?) which has at least edges in each color contains a member of Fk. This conjecture was proved by Cutler and Montágh, who showed that n(k,?)<4k/?. We give a much simpler proof of this conjecture which in addition shows that n(k,?)<?−ck for some constant c. This bound is tight up to the constant factor in the exponent for all k and ?. We also discuss similar results for tournaments and hypergraphs. 相似文献
223.
Accoe F Berglund M Geypens B Taylor P 《Rapid communications in mass spectrometry : RCM》2008,22(14):2280-2286
On-line determination of the oxygen isotopic composition (delta(18)O value) in organic and inorganic samples is commonly performed using a thermal conversion elemental analyzer (TC-EA) linked to a continuous flow isotope ratio mass spectrometry (IRMS) system. Accurate delta(18)O analysis of N-containing compounds (like nitrates) by TC-EA-IRMS may be complicated because of interference of the N(2) peak on the m/z 30 signal of the CO peak. In this study we evaluated the effectiveness of two methods to overcome this interference which do not require any hardware modifications of standard TC-EA-IRMS systems. These methods were (1) reducing the amount of N(2) introduced into the ion source through He dilution of the N(2) peak and (2) an improved background correction on the CO m/z 30 sample peak integration.Our results show that He dilution is as effective as diverting the N(2) peak in order to eliminate this interference. We conclude that the He-dilution technique is a viable method for the delta(18)O analysis of nitrates and other N-containing samples (which are not routinely measured using He dilution) using TC-EA-IRMS, since it can easily be programmed in the standard software of IRMS systems. With the He-dilution technique delta(18)O values of the nitrate isotope standards USGS34, IAEA-N3 and USGS35 were measured using the shortest possible traceability chain to the VSMOW-SLAP scale, and the results were -28.1 +/- 0.1 per thousand, +25.5 +/- 0.1 per thousand and +57.5 +/- 0.2 per thousand, respectively. An improved background correction was also an effective method, but required manual correction of the raw data. 相似文献
224.
A graph H is Ks ‐saturated if it is a maximal Ks ‐free graph, i.e., H contains no clique on s vertices, but the addition of any missing edge creates one. The minimum number of edges in a Ks ‐saturated graph was determined over 50 years ago by Zykov and independently by Erd?s, Hajnal and Moon. In this paper, we study the random analog of this problem: minimizing the number of edges in a maximal Ks ‐free subgraph of the Erd?s‐Rényi random graph G (n, p ). We give asymptotically tight estimates on this minimum, and also provide exact bounds for the related notion of weak saturation in random graphs. Our results reveal some surprising behavior of these parameters. © 2016 Wiley Periodicals, Inc. Random Struct. Alg., 51, 169–181, 2017 相似文献
225.
T. Narasimhamurthy R. V. Krishnakumar J. C. N. Benny K. Pandiarajan M. A. Viswamitra 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):870-871
In the title compound, 2,6‐diphenylthiacyclohexan‐4‐one, C17H16OS, mirror site symmetry is retained by the molecule in the solid state in the absence of C—H?X hydrogen bonds. The crystal structure is stabilized by van der Waals interactions, the shortest S?O and C?O contacts being 3.567 (2) and 3.512 (3) Å, respectively. 相似文献
226.
T. Narasimhamurthy J. C. N. Benny K. Pandiarajan Ravindranath S. Rathore 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(11):o620-o621
The structure of the title compound, C17H16OS, is primarily stabilized by T‐shaped and parallel‐displaced aromatic clusters. The distances between the centroids of the aromatic pairs are in the range 4.34–5.30 Å. In the crystal packing, the molecules dimerize by means of π–π interactions of both face‐to‐face and edge‐to‐face types, and the aromatic rings associate in a cyclic edge‐to‐face tetrameric arrangement of the herring‐bone type. These herring‐bone interactions appear to insulate hydrogen‐bond interactions in the crystal structure. 相似文献
227.
Marshall J. Allen Rahul Sujanani Alyssa Chamseddine Benny D. Freeman Zachariah A. Page 《Journal of polymer science. Part A, Polymer chemistry》2021,59(21):2581-2589
Water swollen polymer networks are attractive for applications ranging from tissue regeneration to water purification. For water purification, charged polymers provide excellent ion separation properties. However, many ion exchange membranes (IEMs) are brittle, necessitating the use of thick support materials that ultimately decrease throughput. To this end, novel double network hydrogels (DNHs) with variable water content are prepared and characterized in terms of mechanical and ion transport properties to evaluate their potential utility as tough membrane materials. The first network contains fixed anionic charges, while the other is comprised of a copolymer with varied ratios of hydrophobic ethyl acrylate (EA) and hydrophilic dimethyl acrylamide (DMA) repeat units. Characterization of freestanding DNH films reveals a reduction in water content from 88 to 53 wt% and a simultaneous increase in ultimate stress and strain by ~3.5× and ~4.5×, respectively, for 95%/5% EA/DMA, relative to 100% DMA. Fundamental salt transport properties relevant to water purification, including permeability, solubility, and diffusivity, are measured and systematically compared with conventional membrane materials to inform the development of DNHs for membrane applications. The ability to simultaneously reduce water content and increase mechanical integrity highlights the potential of DNHs as a synthetic platform for future membrane applications. 相似文献
228.
We prove that, with high probability, any 2‐edge‐coloring of a random tournament on n vertices contains a monochromatic path of length . This resolves a conjecture of Ben‐Eliezer, Krivelevich, and Sudakov and implies a nearly tight upper bound on the oriented size Ramsey number of a directed path. 相似文献
229.
The -color bipartite Ramsey number of a bipartite graph is the least integer for which every -edge-colored complete bipartite graph contains a monochromatic copy of . The study of bipartite Ramsey numbers was initiated, over 40 years ago, by Faudree and Schelp and, independently, by Gyárfás and Lehel, who determined the 2-color Ramsey number of paths. In this paper we determine asymptotically the 3-color bipartite Ramsey number of paths and (even) cycles. 相似文献
230.