全文获取类型
收费全文 | 128篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 42篇 |
力学 | 3篇 |
数学 | 8篇 |
物理学 | 80篇 |
出版年
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2015年 | 1篇 |
2013年 | 1篇 |
2012年 | 1篇 |
2011年 | 8篇 |
2010年 | 6篇 |
2009年 | 1篇 |
2008年 | 30篇 |
2007年 | 15篇 |
2006年 | 11篇 |
2005年 | 4篇 |
2004年 | 4篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 4篇 |
1999年 | 7篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 6篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1981年 | 1篇 |
1977年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有133条查询结果,搜索用时 0 毫秒
81.
J. Benitez M. del Mar Graciani C. D. Hubbard F. Sanchez-Burgos 《Journal of solution chemistry》1990,19(1):19-29
The oxidation of iodide ion by permanganate ion has been studied in several electrolyte solutions over the concentration range (0–6M). The observed kinetic salt effect may be interpreted as arising as a result of ionsolvent interactions. This salt effect is additive for different salts. Support for these conclusions comes from an examination of the activity coefficients of species estimated from the treatment given by Pitzer. It has also been shown that the species relevant in terms of kinetic control are unassociated. 相似文献
82.
83.
84.
Chlorobenzene hydrodechlorination in liquid phase has been studied. Chlorine released during the reaction inhibits conversion in large metallic particles. It was found comparing the behavior of Pd/SiO2, Pd/Al2O3 and Pd/C catalysts that the support plays the role of a chlorine trap. The activity for Pt, Rh and Pd at similar dispersions corresponds to the chlorine adsorption affinity of the metals. 相似文献
85.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Aguilo E Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Ancu LS Andeen T Anderson S Andrieu B Anzelc MS Arnoud Y Arov M Arthaud M Askew A Asman B Assis Jesus AC Atramentov O Autermann C Avila C Ay C Badaud F Baden A Bagby L Baldin B Bandurin DV Banerjee S Banerjee P Barberis E Barfuss AF Bargassa P Baringer P Barreto J Bartlett JF Bassler U Bauer D Beale S Bean A Begalli M Begel M Belanger-Champagne C 《Physical review letters》2007,99(5):052001
We report the first direct observation of the strange b baryon Xi(b)- (Xi(b)+). We reconstruct the decay Xi(b)- -->J/psiXi-, with J/psi-->mu+mu-, and Xi--->Lambdapi--->ppi-pi- in pp collisions at square root of s =1.96 TeV. Using 1.3 fb(-1) of data collected by the D0 detector, we observe 15.2 +/- 4.4(stat)(-0.4)(+1.9)(syst) Xi(b)- candidates at a mass of 5.774 +/- 0.011(stat) +/- 0.015(syst) GeV. The significance of the observed signal is 5.5 sigma, equivalent to a probability of 3.3 x 10(-8) of it arising from a background fluctuation. Normalizing to the decay Lambda(b)-->J/psiLambda, we measure the relative rate sigma(Xi(b-) x B(Xi)b})- -->J/psiXi-)/sigma(Lambda(b)) x B(Lambda(b)-->J/psiLambda) = 0.28+/-0.09(stat)(-0.08)(+0.09)(syst). 相似文献
86.
Benitez JJ de la Fuente OR Díez-Pérez I Sanz F Salmeron M 《The Journal of chemical physics》2005,123(10):104706
Atomic force microscopy operating in noncontact electrostatic force mode was used to study the interaction of water with films of alkylamines and alkylsilanes on mica. The films efficiently block water adsorption except in exposed mica areas, where it strongly modifies the mobility of surface ions. We also studied the molecular orientation of octadecylamine molecules forming monolayers and multilayer islands. In monolayer films the molecules bind to mica through the amino group, producing a positive contact potential relative to mica (dipole pointing up). In multilayer films the methyl and amino group terminations are exposed in alternating layers that give rise to alternating values of the contact potential. These findings correlate with low and high friction forces measured in the methyl termination and amino terminations. 相似文献
87.
F.K. Röpke I.R. SeitenzahlS. Benitez M. FinkR. Pakmor M. KromerS.A. Sim F. Ciaraldi-SchoolmannW. Hillebrandt 《Progress in Particle and Nuclear Physics》2011,66(2):309-318
Despite their astrophysical significance-as a major contributor to cosmic nucleosynthesis and as distance indicators in observational cosmology-Type Ia supernovae lack theoretical explanation. Not only is the explosion mechanism complex due to the interaction of (potentially turbulent) hydrodynamics and nuclear reactions, but even the initial conditions for the explosion are unknown. Various progenitor scenarios have been proposed. After summarizing some general aspects of Type Ia supernova modeling, recent simulations of our group are discussed. With a sequence of modeling starting (in some cases) from the progenitor evolution and following the explosion hydrodynamics and nucleosynthesis we connect to the formation of the observables through radiation transport in the ejecta cloud. This allows us to analyze several models and to compare their outcomes with observations. While pure deflagrations of Chandrasekhar-mass white dwarfs and violent mergers of two white dwarfs lead to peculiar events (that may, however, find their correspondence in the observed sample of SNe Ia), only delayed detonations in Chandrasekhar-mass white dwarfs or sub-Chandrasekhar-mass explosions remain promising candidates for explaining normal Type Ia supernovae. 相似文献
88.
MJ Lazaro AA Herod M Domin Y Zhuo CA Islas R Kandiyoti 《Rapid communications in mass spectrometry : RCM》1999,13(14):1401-1412
Three methods for determining a 'safe' estimate for high-mass limits of MALDI spectra of coal derived liquids were explored, using a sample of coal-tar pitch and its pyridine-insoluble fraction. Co-addition of increasing numbers of single-shot spectra (10, 30, 50 and 100 pulses) showed visually observable reductions in noise levels, consistent with robust and statistically meaningful signals. Three separate types of post-acquisition calculation were used to identify high-mass limits of the spectra. (i) A literature method indicated high-mass limits similar to those observed visually-as a shift from baseline at the highest masses, nearly 350 000 u for the coal tar pitch and about 390 000 u for its pyridine insoluble fraction. (ii) Comparing instrument signal with pre-selected multiples of the standard deviation, upper mass estimates of between 40-60 000 u for the coal-tar pitch and about 95 000 u for its pyridine-insoluble fraction were found. (iii) Calculation of the slope was used to identify 'lift-off' of the spectrum from baseline. The angle between the smoothed spectrum and the baseline was matched to a pre-selected value (e.g. 0.5 degrees and 1 degrees ). However, the arbitrary specification of the key parameter did not establish this last method on a firm basis. The choice of a criterion for estimating high-mass limits of MALDI spectra remains a semi-quantitative procedure; a reasonably conservative high-mass limit may be estimated by comparison of signal with five times the standard deviation. However, evaluation of size exclusion chromatograms of the present samples using polystyrene standards suggests that molecular mass distributions of pitch samples arrived at by MALDI mass spectrometry are, at least partly, determined by the limitations of available instruments. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
89.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Alexeev GD Alkhazov G Alton A Alverson G Alves GA Ancu LS Aoki M Arnoud Y Arov M Askew A Asman B Atramentov O Avila C Backusmayes J Badaud F Bagby L Baldin B Bandurin DV Banerjee S Barberis E Baringer P Barreto J Bartlett JF Bassler U Beale S Bean A Begalli M Begel M Belanger-Champagne C Bellantoni L Benitez JA Beri SB Bernardi G Bernhard R Bertram I Besançon M Beuselinck R Bezzubov VA Bhat PC Bhatnagar V Blazey G Blessing S Bloom K 《Physical review letters》2010,105(21):211802
We present the first search for pair production of isolated jets of charged leptons in association with a large imbalance in transverse energy in pp collisions using 5.8 fb?1 of integrated luminosity collected by the D0 detector at the Fermilab Tevatron Collider. No excess is observed above the standard model background, and the result is used to set upper limits on the production cross section of pairs of supersymmetric chargino and neutralino particles as a function of "dark-photon" mass, where the dark photon is produced in the decay of the lightest supersymmetric particle. 相似文献
90.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Aguilo E Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Ancu LS Andeen T Anderson S Andrieu B Anzelc MS Arnoud Y Arov M Arthaud M Askew A Asman B Jesus AC Atramentov O Autermann C Avila C Ay C Badaud F Baden A Bagby L Baldin B Bandurin DV Banerjee P Banerjee S Barberis E Barfuss AF Bargassa P Baringer P Barreto J Bartlett JF Bassler U Bauer D Beale S Bean A Begalli M Begel M Belanger-Champagne C Bellantoni L 《Physical review letters》2007,99(13):131801
Long-lived, heavy particles are predicted in a number of models beyond the standard model of particle physics. We present the first direct search for such particles' decays, occurring up to 100 h after their production and not synchronized with an accelerator bunch crossing. We apply the analysis to the gluino (g), predicted in split supersymmetry, which after hadronization can become charged and lose enough momentum through ionization to come to rest in dense particle detectors. Approximately 410 pb(-1) of pp collisions at square root(s) = 1.96 TeV collected with the D0 detector during Run II of the Fermilab Tevatron collider are analyzed in search of such "stopped gluinos" decaying into a gluon and a neutralino (chi(1)(0)). Limits are placed on the (gluino cross section) x (probability to stop) x [BR(g --> g chi(1)(0))] as a function of the gluino and chi(1)(0) masses, for gluino lifetimes from 30 micros-100 h. 相似文献