全文获取类型
收费全文 | 747篇 |
免费 | 18篇 |
国内免费 | 2篇 |
专业分类
化学 | 387篇 |
晶体学 | 9篇 |
力学 | 45篇 |
数学 | 150篇 |
物理学 | 176篇 |
出版年
2024年 | 2篇 |
2023年 | 6篇 |
2022年 | 11篇 |
2021年 | 26篇 |
2020年 | 9篇 |
2019年 | 14篇 |
2018年 | 27篇 |
2017年 | 26篇 |
2016年 | 32篇 |
2015年 | 16篇 |
2014年 | 48篇 |
2013年 | 74篇 |
2012年 | 44篇 |
2011年 | 39篇 |
2010年 | 36篇 |
2009年 | 46篇 |
2008年 | 38篇 |
2007年 | 27篇 |
2006年 | 26篇 |
2005年 | 29篇 |
2004年 | 26篇 |
2003年 | 21篇 |
2002年 | 23篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 2篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 8篇 |
1979年 | 2篇 |
1975年 | 2篇 |
1973年 | 5篇 |
1970年 | 2篇 |
1968年 | 2篇 |
1957年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有767条查询结果,搜索用时 78 毫秒
51.
A simple, rapid tandem mass spectrometric method for recognition of chiral molecules by proton transfer reactions with chiral sec-butylamines and sec-butanols is reported. 相似文献
52.
Ding Y Habib Q Shaw SZ Li DY Abt JW Hong Z An H 《Journal of combinatorial chemistry》2003,5(6):851-859
A versatile solid phase combinatorial approach was developed and utilized for the rapid synthesis of new 2'-O-methylcytidine nucleoside libraries 1-7 containing 672 compounds with 3'-deoxy-3'-C-methyl, 3'-deoxy-3'-C-hydroxymethyl, and 5-alkyl/alkynyl modifications. The modified uridine scaffolds 8-10, 23-25, and 31 were loaded onto the 4-methoxytrityl chloride (MMT-Cl) polystyrene resin through the hydroxyl groups at the 5'-position as well as on the substituents at the 3'- and 5-positions. The scaffolds loaded on the resin were orthogonally protected by MMT group on the resin itself and TBDMS or acetyl protecting groups. The 4-position of the uridine derivatives was activated by 2,4,6-triisopropyl benzene sulfonyl chloride for further derivatization. The resins 14-16, 28-30, and 32 loaded with the corresponding activated scaffolds were reacted with the selected and validated amino building blocks in the 96 well format on the semiautomated synthesizer. The high-quality 2'-O-methylcytidine libraries 1-7 were thus generated and characterized by liquid chromatography-mass spectrometry (LC-MS) analysis with 63-99% successful rates. 相似文献
53.
Isolation and structure determination of a novel furanic ester from the aerial part of Prasium majus
The aerial part of Prasium majus provided a new furanic ester, 2-2-[(5-formyl-6[(5-formylfuran-2-yl)methoxy] succinic acid dimethyl ester, (+/-)-hiziprafuran. Its structure was principally established by one- and two-dimensional NMR spectroscopy. 相似文献
54.
We formulate the conditions under which the dynamics of a continuously measured quantum system becomes indistinguishable from that of the corresponding classical system. In particular, we demonstrate that even in a classically chaotic system the quantum state vector conditioned by the measurement remains localized and, under these conditions, follows a trajectory characterized by the classical Lyapunov exponent. 相似文献
55.
A dynamic model is developed which enables the prediction of risers’ tubes temperature of water tube boilers under various operating conditions. The model is composed of fluid dynamics model representing the fluid flow in the drum-downcomer-riser loop and a dynamic thermal model of the riser’s temperature. The model gives a detailed account of the two-phase heat transfer process which takes place between the risers’ inner walls and the water–steam mixture flow inside the tubes. The model is used to simulate various operational scenarios of water tube boilers. Results of the simulation provide insight into the dynamic interactions of the boiler’s main variables including the drum pressure, water volume, steam quality and risers’ temperature. Such a model is useful in checking operational scenarios before their actual plant implementation, can be a basis for developing boiler start up procedures and online temperature predictions to prevent eminent tube overheating. 相似文献
56.
Habib Ammari Hyeonbae Kang Eunjoo Kim Hyundae Lee Kaouthar Louati 《Studies in Applied Mathematics》2009,122(1):85-104
The vibration behavior of structures can be characterized in terms of resonance frequencies and mode shapes, which describe properties of the tested object in a global way but do not, in general, provide information about structural details. Following an asymptotic formalism, in much the same spirit as the work in [ 3 ] and recent text [ 1 ], we develop an efficient method to address the inverse problem of identifying an internal corrosive part of small Hausdorff measure in a two-dimensional structure by vibration analysis. The viability of our reconstruction method is documented by a variety of numerical results from synthetic, noiseless and noisy data. 相似文献
57.
Nicolas Ginoux Georges Habib 《Abhandlungen aus dem Mathematischen Seminar der Universit?t Hamburg》2008,78(1):69-90
We study a Killing spinor type equation on spin Riemannian flows. We prove integrability conditions and partially classify
those flows carrying non-trivial solutions.
相似文献
58.
We establish an asymptotic expansion of the steady-state voltage potentials in the presence of a diametrically small conductivity inhomogeneity that is nearly touching the boundary. Our asymptotic formula extends those already derived for a small inhomogeneity far away from the boundary and is expected to lead to very effective algorithms, aimed at determining location and certain properties of the shape of a small inhomogeneity that is nearly touching the boundary based on boundary measurements. Viability of the asymptotic formula is documented by numerical examples. 相似文献
59.
Habib Md. Ahasan Anower Md. Shamim AlGhamdi Ahmed Faragallah Osama S. Eid Mahmoud M. A. Rashed Ahmed Nabih Zaki 《Optical Review》2021,28(4):383-392
Optical Review - In this study, a simple hollow core hexagonal structured photonic crystal fiber is offered and analyzed to discern commonly used different type of alcohols in our daily life. The... 相似文献
60.
Mariem Nafti Radhouane Chakroun Chiraz Hannachi Bechir Hamrouni Habib Nouaïgui 《Analytical letters》2017,50(12):2012-2022
Hexavalent chromium Cr(VI) is a well-established carcinogen associated with lung, nasal, and sinus cancer. Cr(VI) threshold limit values in workroom air have been recently lowered. Consequently, the currently available analytical methods are insufficiently sensitive or high cost. In this paper, a simple, cost-effective, sensitive, and reproducible method using solid-phase extraction with electrothermal atomic absorption spectrometry for determination of hexavalent chromium in airborne samples is reported. The method validation included selectivity, linearity, accuracy, and precision. Interferences from other ions likely to be present in airborne samples, including trivalent chromium, were tested and selectivity was demonstrated. The detection and quantification limits were, respectively, as low as 0.1 and 0.4?µg?L?1. The linearity ranged from 0.5 to 50.0?µg?L?1, with a regression coefficients exceeding 0.998. The extraction recovery exceeded 98%. The developed method was successfully compared with a reference spectrophotometric method. The performances achieved were similar to ion chromatography and high-performance liquid chromatography approaches. The novel method was tested on airborne samples collected from the workplace. The method’s performance suggests that it may be an alternative to high-cost techniques for monitoring occupational exposure to hexavalent chromium. 相似文献