Crystal structure and magnetization of a Co3B2O6 single crystal

The crystal structure and magnetic properties of Co₃B₂O₆ single crystals are studied. Orthorhombic symmetry with space group Pnnm is detected at room temperature. The measurements of static magnetization and dynamic magnetic susceptibility reveal two magnetic anomalies at T ₁ = 33 K and T ₂ = 10 K and an easy-axis magnetic anisotropy. The effective magnetic moment indicates a high-spin state of the Co²⁺ ion. A spin-flop transition is found at low temperatures and H _sf = 23 kOe. EXAFS spectra of the K-edge absorption of Co are recorded at various temperatures, the temperature-induced changes in the parameters of the local environment of cobalt are analyzed, and the effective Co-Co and Co-O distances are determined. The magnetic interactions in the crystal are analyzed in terms of an indirect coupling model.     

Magnetic and electrical properties of Fe<Subscript>1.91</Subscript>V<Subscript>0.09</Subscript>BO<Subscript>4</Subscript> warwickite

We have performed a complex investigation of the structure and the magnetic and electrical properties of a warwickite single crystal with the composition Fe_1.91V_0.09BO₄. The results of Mössbauer measurements at T=300 K indicate that there exist “localized” (Fe²⁺, Fe³⁺) and “delocalized” (Fe_2.5+) states distributed over two crystallographically nonequivalent positions. The results of magnetic measurements show that warwickite is a P-type ferrimagnet below T=130 K. The material exhibits hopping conductivity involving strongly interacting electrons. The experimental data are analyzed in comparison to the properties of the initial (unsubstituted) Fe₂BO₄ warwickite. The entire body of data on the electric conductivity and magnetization are interpreted on a qualitative basis.     

Experimental search for the effect of resonant environment on the Mössbauer absorption of gamma rays by <Superscript>57</Superscript>Fe

Due to the virtual photon exchange between atomic nuclei and the field of zero-point electromagnetic oscillations, some nuclei of a given sample are in a virtual excited state with the lifetime ～?/E, where E is the energy of nuclear level. For ⁵⁷Fe nuclei, whose first excited state has an energy of 14.4 keV, this time is equal to ～4.6×10^?20 s. If a thin ⁵⁷Fe Mössbauer gamma-ray absorber is surrounded by a thick screen of the same atoms, the number of virtual excited nuclei in the absorber decreases and, at first glance, it should more strongly absorb Mössbauer gamma rays emitted by an external source and passing through the absorber. In this work, the ratio of the intensities of 14.4-keV gamma rays emitted by the ⁵⁷Fe nuclide and passing through the thin resonant absorber is measured in the absence and presence of the resonant screen around the absorber. Comparison shows that these ratios measured for the gamma source at rest and in the oscillating state differ by 0.00123±0.00075. This value should be treated as the upper limit for the desired effect under these experimental conditions.     

Change in the magnetic properties of nanoferrihydrite with an increase in the volume of nanoparticles during low-temperature annealing

The results of the investigation into the effect of low-temperature annealing of a powder of nanoparticles of bacterial ferrihydrite on its magnetic properties have been presented. It has been found that an increase in the time (up to 240 h) and temperature (in the range from 150 to 200°C) of annealing leads to a monotonic increase in the superparamagnetic blocking temperature, the coercive force, and the threshold field of the opening of the magnetic hysteresis loop (at liquid-helium temperatures), as well as to an increase in the magnetic resonance line width at low temperatures and in the magnetic susceptibility at room temperature. At the same time, according to the results of the analysis of the Mössbauer spectra, the annealing of ferrihydrite does not lead to the formation of new iron oxide phases. Most of these features are well consistent with the fact that the low-temperature annealing of ferrihydrite causes an increase in the size of nanoparticles, which is confirmed by the results of transmission electron microscopy studies.     

Synthesis and properties of NaFeGe<Subscript>2</Subscript>O<Subscript>6</Subscript> polycrystals

NaFeGe₂O₆ polycrystals were synthesized and their x-ray diffraction, magnetic, electrical, and Mössbauer characteristics were measured. It is established that this monoclinic compound is a dielectric with a temperature of antiferromagnetic ordering of 15 K. The Mössbauer spectrum at 300 K is a quadrupole doublet. The isomer shift is 0.40 mm/s, which is characteristic of the high-spin Fe³⁺ ion in the octahedral coordination. The quadrupole splitting is 0.34 mm/s, which indicates that the oxygen octahedron around the iron cation is distorted. The exchange interactions are estimated, and the crystal magnetic structure is discussed.     

HoFeTi2O7: Synthesis,Peculiarities of the Crystal Structure,and Magnetic Properties

Physics of the Solid State - Polycrystalline samples of HoFeTi2O7 were obtained by solid-phase synthesis and investigated using X-ray diffraction, gamma resonance, and SQUID measurements....     

Hydroxylation of fullerenes modified with iron nanoparticles

The possibility was explored for synthesizing polyhydroxylated fullerenes directly from soot containing iron nanoparticles stabilized by carbon shell.     

Solid-state synthesis in Ni/Fe/MgO(001) epitaxial thin films

Solid-state synthesis in Ni/Fe/MgO(001) bilayer epitaxial thin films has been studied experimentally. The phase sequence Fe/Ni→(～350°C)Ni₃Fe→(～400°C)NiFe→(～ 550°C)γ_par is formed as the annealing temperature increases. The crystal structure in the invar region consists of epitaxially intergrown single-crystal blocks consisting of the paramagnetic γ_par and ferromagnetic NiFe phases, which satisfy the orientation relationship [100](001)NiFe ∥ [100](001) γ_par. It has been shown that the nucleation temperatures of the Ni₃Fe, NiFe, and γ_par phases coincide with the temperatures of solid-state transformations in the Ni-Fe system.     

Search for the resonance environmental effect on the decay periods of long-lived nuclear isomers

Experiments on a search for the resonance environmental effect on the decay periods T_1/2 of long-lived nuclear isomers are described. It is shown that a change in T_1/2 obtained upon sample cooling in previous experiments with the ^180mHf isomer is likely due to the insufficient correctness of the procedure used for separating γ peaks from the backgrounds in the measured γ spectra. The new approach to this problem reveals the absence of this effect for T_1/2 within an experimental accuracy of 1.2%. However, a difference of 2.25±0.77% between the ^103mRh decay periods T_1/2 was found for the solid and liquid γ sources. A control experiment with the ^80mBr isomer showed that, as expected, the decay periods T_1/2 for two temperatures coincide with each other within an accuracy of 1%.