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21.
R. Albrecht T. C. Awes C. Baktash P. Beckmann F. Berger R. Bock G. Claesson L. Dragon R. L. Ferguson A. Franz S. I. A. Garpman R. Glasow H. ?. Gustafsson H. H. Gutbrod J. W. Johnson K. -H. Kampert B. W. Kolb P. Kristiansson I. Y. Lee H. L?hner I. Lund F. E. Obenshain A. Oskarsson I. Otterlund T. Peitzmann S. Persson F. Plasil A. M. Poskanzer M. Purschke H. G. Ritter R. Santo H. R. Schmidt T. Siemiarczuk S. P. Sorensen E. Stenlund G. R. Young WA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1988,38(1):51-57
Charged particle multiplicity distributions and pseudo-rapidity density distributions from16O induced nuclear collisions at 200 and 60A GeV are presented. The data were taken, using a minimumbias trigger, with the WA80 set-up at the CERN SPS. In this presentation we focus on how the yield of charged particles depends on the projectile energy, the mass number of the target nucleus and the energy measured in a uranium-plastic sampling calorimeter covering angles close to zero degrees. The data are compared to simulations from the event generator FRITIOF. 相似文献
22.
The crystallization from the melt of three sharp polyethylene fractions has been studied at 5 kbar. It has been shown that the thickness of so-called extended-chain lamellae is a function of time, temperature, and molecular weight. There is by no means just the fully extended molecular configuration present. Crystallization is qualitatively similar to that of chain-folded crystals at 1 bar, giving an optimum lamellar thickness which increases with time and decreasing supercooling. Fractional crystallization is widespread and is a major cause of disparate lamellar thickness. Isothermal thickening of lamellae during crystallization has been established directly. Morphological detail suggests further that layers can increase their thickness tenfold over their initial size. 相似文献
23.
D. C. Bassett 《Journal of Macromolecular Science: Physics》2013,52(5-6):479-489
The new unified context for crystallization of linear macromolecules from the melt, established by recent work, is expounded. The morphology of spherulites shows that they form because of a short-range force operative at the branch points of dominant lamellae that causes them to diverge at noncrystallographic angles of about 20°. Work on monodisperse n-alkanes has confirmed the identification of this short-range force with the pressure from dynamic cilia during growth. Accordingly, spherulites, like chain folding, are a direct consequence of molecular length. It is suggested that the tendency to form coarse spherulites even for extended-chain growth at lower temperatures may result from the increasing difference between the lengths of nucleus and molecule. Crystallization on linear nuclei has been used to maximize the concentration of segregants at the growth front and to demonstrate cellulation in undoped polymers for the first time. The behavior of branched polyethylenes differs from the uniform growth of the linear polymer in coarsening and developing protuberances at the growth front, all the while slowing continuously toward an asymptotic steady state; differences of detail may be useful in distinguishing polymers of different catalytic origin and branch content. Spherulitie growth is also nonlinear for these polymers, but is always faster than for rows. When there is sufficient segregation, spherulites themselves cellulate, increasingly so for higher branch content. Cellulation is thus an uncommon and secondary process may be superposed on regular spherulitie growth beyond a certain distance. Cell dimensions do not scale with the diffusion length; in so doing, the phenomenon displays new physics. 相似文献
24.
Jeon JY Kim YH Cabrera D Bassett J 《The Journal of the Acoustical Society of America》2008,123(6):4272-4282
Opera performance conveys both visual and auditory information to an audience, and so opera theaters should be evaluated in both domains. This study investigates the effect of static visual and auditory cues on seat preference in an opera theater. Acoustical parameters were measured and visibility was analyzed for nine seats. Subjective assessments for visual-only, auditory-only, and auditory-visual preferences for these seat positions were made through paired-comparison tests. In the cases of visual-only and auditory-only subjective evaluations, preference judgment tests on a rating scale were also employed. Visual stimuli were based on still photographs, and auditory stimuli were based on binaural impulse responses convolved with a solo tenor recording. For the visual-only experiment, preference is predicted well by measurements taken related to the angle of seats from the theater midline at the center of the stage, the size of the photographed stage view, the visual obstruction, and the distance from the stage. Sound pressure level was the dominant predictor of auditory preference in the auditory-only experiment. In the cross-modal experiments, both auditory and visual preferences were shown to contribute to overall impression, but auditory cues were more influential than the static visual cues. The results show that both a positive visual-only or a positive auditory-only evaluations positively contribute to the assessments of seat quality. 相似文献
25.
26.
A newly developed interface coupling a CHN combustion device (elemental analyser 'EA') to an isotope ratio mass spectrometer is described and evaluated. The purpose of the device is to extend the dynamic range of delta(13)C and delta(15)N analysis from less than 2 orders of magnitude to more than 3 orders of magnitude. Carbon isotope ratio measurements of atropine as a model compound have been performed analysing between 1 μg to 5 mg C with acceptable to excellent precision (0.6 to 0.06 per thousand, delta-notation). The correction due to the blank signal is critical for sample amounts smaller than 4 μg C. The maximum sample weight is determined by the combustion capacity of the EA. Larger sample amounts are measured using dilution of a small part of the EA effluent with helium. The dilution mechanism works virtually free of isotope fractionation. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
27.
DC Bassett 《Macromolecular Symposia》1997,114(1):121-126
Molecular cilia, the uncrystallized portions of chains already partly attached to polymer crystals, exert a profound influence on the course of polymeric crystallization with ultimate responsibility for the divergence of adjacent lamellae which leads to spherulitic growth. Their effective size and pressure have been measured, in α-polypropylene, from electron microscopic measurements of the separation and maximum curvature of lamellae in row structures. That cilia exist and extend the effective region occupied by a lamella beyond the geometrical confines of its fold surfaces is important for crystallization theory and may well have implications for the connection of lamellae into networks and for gelation. 相似文献
28.
N-nitrosodimethylamine (NDMA) is a probable human carcinogen of concern that has been identified as a drinking water contaminant. U.S. Environmental Protection Agency Method 521 has been developed for the analysis of NDMA and 6 additional N-nitrosamines in drinking water at low ng/L concentrations. The method uses solid-phase extraction with coconut charcoal as the sorbent and dichloromethane as the eluent to concentrate 0.50 L water samples to 1 mL. The extracts are analyzed by gas chromatography-chemical ionization tandem mass spectrometry using large-volume injection. Method performance was evaluated in 2 laboratories. Typical analyte recoveries of 87-104% were demonstrated for fortified reagent water samples, and recoveries of 77-106% were demonstrated for fortified drinking water samples. All relative standard deviations on replicate analyses were < 11%. 相似文献
29.
U.S. Environmental Protection Agency (EPA) Method 535 has been developed in order to provide a method for the analysis of "Alachlor ESA and other acetanilide degradation products," which are listed on EPA's 1998 Drinking Water Contaminant Candidate List. Method 535 uses solid-phase extraction with a nonporous graphitized carbon sorbent to extract the ethane sulfonic acid (ESA) and oxanilic acid degradates of propachlor, flufenacet, dimethenamid, alachlor, acetochlor, and metolachlor from finished drinking water matrixes. Separation and quantitation of the target analytes are achieved with liquid chromatography/tandem mass spectrometry. Dimethachlor ESA and butachlor ESA were chosen during the method development as the surrogate and internal standard. Drinking water samples were dechlorinated with ammonium chloride without adversely affecting the analyte recoveries. Typical mean recoveries of 92-116% in deionized water and 89-116% in ground water were observed with relative standard deviations of <5%. 相似文献
30.
Hollow-core microstructured polymer optical fiber 总被引:3,自引:0,他引:3
We have fabricated microstructured polymer optical fibers that guide light in a hollow core using the photonic bandgap mechanism. The hollow core allows the use of polymer fibers to be extended to wavelength ranges where material absorption typically prohibits their use, with attenuation lower than the material loss observed in the infrared. The fabrication method is similar to other microstructured polymer optical fibers, which has favorable implications for the feasibility of manufacturing such bandgap fibers. 相似文献