Investigation of techniques for minimizing resistivity of thin metallic films at submillimeter wavelengths

Experimental investigations of the substrate deposition temperature and annealing temperature influence on aluminum films deposited on diamond substrates were conducted. Tests were performed at direct current and at 101.55 GHz. Minimum resistivity levels, near theoretical predictions, occurred for deposition temperatures in the range of 50–160°C and for peak annealing temperatures of 100–120°C. Both colder and hotter substrate temperatures resulted in larger resistivity levels.     

The measurement of222Rn in drinking water by low-level liquid scintillation counting

Radon-222 (Rn) has universally been found in well water. Non-stagnant ground water is collected at the well head while the well is pumping. The water is adjusted to a slow, non-aerated, steady flow through a clear tube, and a 500 ml glass bottle is filled. The sample is tightly capped after a high meniscus has developed. In the laboratory, standard 22 ml glass vials are filled with 10 ml of a toluene based mineral oil LS cocktail. Then, two 5 ml sample aliquots are pipetted into the vial. Vials are capped tightly, shaken vigorously, and placed in the liquid scintillation (LS) counter. Secular equilibrium is established in approximately 4 hours, after which samples are counted for 100 minutes each. The counting efficiency for Rn and progeny ranges between 315 to 345 percent depending on the chosen spectral window. The average background is about 6 cpm. A total of 28 wells were tested for Rn in the Carefree-Cave Creek, Arizona, USA area. The area's geometric average Rn concentration was found to be 46.5 Bq·l^–1. The associated estimated lung dose is 0.51 mSv·y^–1.Deceased 1 June 1991.     

Study of spontaneous fission with EUROGAM

Prompt γ radiation following spontaneous fission has been measured using the EUROGAM 2 array. Using these data and newly developed analysis techniques a number of subjects were studied, which are briefly discussed. One of these subjects, shape transition in A≈100 Sr and Zr nuclei is discussed in more detail. Quadrupole moments were determined for rotational bands in the N=58,59,60,62 and 64 Sr and Zr isotopes. Deformation parameters, which increase from β₂ ≈ 0.1 at N=56 to β₂ ≈ 0.4 at N=64, suggest that in strontium and zirconium isotopes shape change happens gradually between N=56 and N=62 and is probably due to an occupancy of three or more deformation-driving orbitals of h_11/2 parentage.     

Bestimmung der Alkalien

Ohne Zusammenfassung     

Search for chargino-neutralino production in pp collisions at sq rt[s] = 1.96 TeV

We present a search for associated production of the chargino and neutralino supersymmetric particles using up to 1.1 fb{-1} of integrated luminosity collected by the CDF II experiment at the Tevatron pp collider at sq rt[s]=1.96 TeV. We analyze events with a large transverse momentum imbalance and either three charged leptons or two charged leptons of the same electric charge. The numbers of observed events are consistent with standard model expectations. Upper limits on the production cross section are derived in different theoretical models.     

Measurement of the Lambda b0 lifetime in Lambda b0-->J/psi Lambda 0 in pp collisions at square root s=1.96 TeV

We report a measurement of the Lambda b0 lifetime in the exclusive decay Lambda b0-->J/psi Lambda 0 in pp collisions at square root s=1.96 TeV using an integrated luminosity of 1.0 fb-1 of data collected by the CDF II detector at the Fermilab Tevatron. Using fully reconstructed decays, we measure tau(Lambda b0)=1.593(-0.078)(+0.083)(stat)+/-0.033(syst) ps. This is the single most precise measurement of tau(Lambda b0) and is 3.2sigma higher than the current world average.     

Observation of exclusive electron-positron production in hadron-hadron collisions

We present the first observation of exclusive e(+)e(-) production in hadron-hadron collisions, using pp[over] collision data at (square root) s = 1.96 TeV taken by the run II Collider Detector at Fermilab, and corresponding to an integrated luminosity of 532 pb(-1). We require the absence of any particle signatures in the detector except for an electron and a positron candidate, each with transverse energy E(T) > 5 GeV and pseudorapidity |eta| < 2. With these criteria, 16 events are observed compared to a background expectation of 1.9+/-0.3 events. These events are consistent in cross section and properties with the QED process pp[over] --> p + e(+)e(-) + p[over] through two-photon exchange. The measured cross section is 1.6(-0.3)(+0.5)(stat) +/- 0.3(syst) pb. This agrees with the theoretical prediction of 1.71+/-0.01 pb.     

The non-uniform transformation strain problem for an anisotropic ellipsoidal inclusion

The problem of an anisotropic ellipsoidal inclusion which undergoes a stress-free transformation strain (in the sense of J.D. Eshelby) is considered, and the following theorem is proved: If an ellipsoidal region in an infinite anisotropic linear elastic medium undergoes, in the absence of its surroundings, a stress-free transformation strain which is a polynomial of degree M in the position coordinates x_t, then the final stress and strain state in the transformed inclusion, when constrained by its surroundings, is also a polynomial of degree M in x_t.     

The importance of chain length for the polyphosphate enhancement of acidic potassium permanganate chemiluminescence

Sodium polyphosphate is commonly used to enhance chemiluminescence reactions with acidic potassium permanganate through a dual enhancement mechanism, but commercially available polyphosphates vary greatly in composition. We have examined the influence of polyphosphate composition and concentration on both the dual enhancement mechanism of chemiluminescence intensity and the stability of the reagent under analytically useful conditions. The average chain length (n) provides a convenient characterisation, but materials with similar values can exhibit markedly different distributions of phosphate oligomers. There is a minimum polyphosphate chain length (∼6) required for a large enhancement of the emission intensity, but no further advantage was obtained using polyphosphate materials with much longer average chain lengths. Providing there is a sufficient average chain length, the optimum concentration of polyphosphate is dependent on the analyte and in some cases, may be lower than the quantities previously used in routine detection. However, the concentration of polyphosphate should not be lowered in permanganate reagents that have been partially reduced to form high concentrations of the key manganese(III) co-reactant, as this intermediate needs to be stabilised to prevent formation of insoluble manganese(IV).     

Simultaneous control of spectroscopic and electrochemical properties in functionalised electrochemiluminescent tris(2,2'-bipyridine)ruthenium(II) complexes

Using a combination of electrochemical, spectroscopic and computational techniques, we have explored the fundamental properties of a series of ruthenium diimine complexes designed for coupling with other molecules or surfaces for electrochemiluminescence (ECL) sensing applications. With appropriate choice of ligand functionality, it is possible to manipulate emission wavelengths while keeping the redox ability of the complex relatively constant. DFT calculations show that in the case of electron withdrawing substituents such as ester or amide, the excited state is located on the substituted bipyridine ligand whereas in the case of alkyl functionality it is localised on a bipyridine. The factors that dictate annihilation ECL efficiency are interrelated. For example, the same factors that determine ΔG for the annihilation reaction (i.e. the relative energies of the HOMO and LUMO) have a corresponding effect on the energy of the excited state product. As a result, most of the complexes populate the excited state with an efficiency (Φ(ex)) of close to 80% despite the relatively wide range of emission maxima. The quantum yield of emission (Φ(p)) and the possibility of competing side reactions are found to be the main determinants of ECL intensity.