Rule-based procedures in short-term electricity load forecasting

A short-term load-forecasting system has been developed to predictload demand for the Irish Electricity Supply Board from 1 to10 days in advance. Model output is acceptably accurate at mosttimes, but special days such as public holidays and the Easterweekend etc. require individual treatment. The basic model usedin everyday load forecasting is presented first, and specialdays when this model fails in accuracy are then examined andtreated separately using rule-based procedures. These proceduresare based on identified relationships between weather conditionsand prevailing daily load shapes. Comparisons are made betweenthe forecasts for these special days as given by the standardmodel and the ruled-based procedures.     

Frontiers in 2D NMR of paramagnetic metalloproteins

The possibilities and the limitations of 2D NMR for the structural characterization of paramagnetic metalloproteins are reviewed. We survey the general strategies for 2D¹H NMR investigations of hyperfine shifted signals. Careful adaptation of classical 2D NMR experiments to fast relaxing systems results in the detection of previously not observed scalar and dipolar connectivities, thus leading to the specific assignment of selected resonances. The approach is of general applicability for paramagnetic metalloproteins. We report here on the application of the application of the method to an iron sulfur protein and a heme protein. In both cases specific assignment of several hyperfine shifted signals, corresponding to active site protons, were obtained; this allowed significant insight into the structure-function relationships of these metalloproteins.     

Assembly of bifunctional receptors via the melamine-barbiturate structural motif

An assembly of cation receptor 1 and anion receptor 2 via the hydrogen bonding melamine-barbiturate structural motif complexes sodium thiocyanate, sodium iodide, and sodium azide in apolar solvents.     

The effect of complexing processes on energy transfer Tl+→Gd3+ and Tl+→Tb3+ in glass

T. Shevchenko Kiev University, 252022 Kiev, Pr. Akad. Glushakova, 6, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 3, pp. 192–196, May–June, 1995.     

Some inverse problems of internal-diffusion kinetics of adsorption

Methods are proposed for determining the diffusion coefficients of adsorbed molecules and the adsorption isotherms from given concentrations of the solutes in the external solution. The methods are based on a comparison of experimental data with the numerical results produced by a mathematical model of internal-diffusion kinetics of adsorption from a constant bounded volume.Translated from Vychislitel'naya i Prikladnaya Matematika, No. 66, pp. 41–46, 1988.     

Fringe field quantification in an LDV probe volume by use of a magnified image

The magnified cross-section of the LDV probe volume fringe field created on a far screen (image plane) with an imaging lens is examined both analytically and experimentally. It is shown that measurements of the image plane fringe field can be used to quantitatively determine the fringe field existing within the probe volume. Because the fringe spacing in the magnified image is more accessible experimentally, both longitudinal- and lateral-coordinate variations in fringe spacing can be determined, permitting a complete mapping of the fringe field. The detailed knowledge of the fringe field thus obtained allows beam quality, alignment, and fringe uniformity to be evaluated with greater precision than is possible with other techniques.The authors would like to acknowledge C. F. Edwards and R. L. Schmitt for the loan of the beam profiler and for many helpful discussions. This work was performed at the Combustion Research Facility, Sandia National Laboratories, and was supported by the U.S. Department of Energy, Office of Industrial Technologies, Advanced Industrial Concepts Division.