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41.
Sort J Buchanan KS Novosad V Hoffmann A Salazar-Alvarez G Bollero A Baró MD Dieny B Nogués J 《Physical review letters》2006,97(6):067201
The effect of imprinting symmetric and displaced vortex structures into an antiferromagnetic material is investigated in micron-sized disks consisting of exchange coupled ferromagnetic-antiferromagnetic bilayers. The imprint of displaced vortices manifests itself by the occurrence of a new type of asymmetric hysteresis loops characterized by curved, reversible, central sections with nonzero remanent magnetization. Such an imprint is achieved by cooling the disks through the blocking temperature of the system in small fields. Micromagnetic simulations reveal that asymmetric vortexlike loops naturally result from the competition between the different energies involved in the system. 相似文献
42.
William Kun Liang Barış Balcıog̃lu Robert Svaluto 《Annals of Operations Research》2013,211(1):273-288
In this paper, we analyze a repair shop serving several fleets of machines that fail from time to time. To reduce downtime costs, a continuous-review spare machine inventory is kept for each fleet. A spare machine, if available on stock, is installed instantaneously in place of a broken machine. When a repaired machine is returned from the repair shop, it is placed in inventory for future use if the fleet has the required number of machines operating. Since the repair shop is shared by different fleets, choosing which type of broken machine to repair is crucial to minimize downtime and holding costs. The optimal policy of this problem is difficult to characterize, and, therefore, is only formulated as a Markov Decision Process to numerically compute the optimal cost and base-stock level for each spare machine inventory. As an alternative, we propose the dynamic Myopic(R) policy, which is easy to implement, yielding costs very close to the optimal. Most of the time it outperforms the static first-come-first-served, and preemptive-resume priority policies. Additionally, via our numerical study, we demonstrate that repair shop pooling is better than reserving a repair shop for each fleet. 相似文献
43.
Impact of the Oxygen Defects and the Hydrogen Concentration on the Surface of Tetragonal and Monoclinic ZrO2 on the Reduction Rates of Stearic Acid on Ni/ZrO2 下载免费PDF全文
Sebastian Foraita Dr. John L. Fulton Zizwe A. Chase Aleksei Vjunov Pinghong Xu Dr. Eszter Baráth Dr. Donald M. Camaioni Dr. Chen Zhao Prof. Dr. Johannes A. Lercher 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(6):2423-2434
The role of the specific physicochemical properties of ZrO2 phases on Ni/ZrO2 has been explored with respect to the reduction of stearic acid. Conversion on pure m‐ZrO2 is 1.3 times more active than on t‐ZrO2, whereas Ni/m‐ZrO2 is three times more active than Ni/t‐ZrO2. Although the hydrodeoxygenation of stearic acid can be catalyzed solely by Ni, the synergistic interaction between Ni and the ZrO2 support causes the variations in the reaction rates. Adsorption of the carboxylic acid group on an oxygen vacancy of ZrO2 and the abstraction of the α‐hydrogen atom with the elimination of the oxygen atom to produce a ketene is the key to enhance the overall rate. The hydrogenated intermediate 1‐octadecanol is in turn decarbonylated to heptadecane with identical rates on all catalysts. Decarbonylation of 1‐octadecanol is concluded to be limited by the competitive adsorption of reactants and intermediate. The substantially higher adsorption of propionic acid demonstrated by IR spectroscopy and the higher reactivity to O2 exchange reactions with the more active catalyst indicate that the higher concentration of active oxygen defects on m‐ZrO2 compared to t‐ZrO2 causes the higher activity of Ni/m‐ZrO2. 相似文献
44.
Javier Sotres Anabel Lostao Dr. Linda Wildling Andreas Ebner Carlos Gómez‐Moreno Prof. Hermann J. Gruber Prof. Dr. Peter Hinterdorfer Prof. Dr. Arturo M. Baró Prof. 《Chemphyschem》2008,9(4):590-599
Atomic force microscopy is a technique capable to study biological recognition processes at the single‐molecule level. In this work we operate the AFM in a force‐scan based mode, the jumping mode, where simultaneous topographic and tip–sample adhesion maps are acquired. This approach obtains the unbinding force between a well‐defined receptor molecule and a ligand attached to the AFM tip. The method is applied to the avidin–biotin system. In contrast with previous data, we obtain laterally resolved adhesion maps of avidin–biotin unbinding forces highly correlated with single avidin molecules in the corresponding topographic map. The scanning rate 250 pixel s?1 (2 min for a 128×128 image) is limited by the hydrodynamic drag force. We are able to build a rupture‐force distribution histogram that corresponds to a single defined molecule. Furthermore, we find that due to the motility of the polymer used as spacer to anchor the ligand to the tip, its direction at rupture does not generally coincide with the normal to the tip–sample, this introduces an appreciable error in the measured force. 相似文献
45.
The first overtone region of the C-H stretching vibration of 1,2-trans-d(2)-ethene (HDC=CDH) was monitored via jet-cooled action spectroscopy and room temperature photoacoustic spectroscopy. The spectra include a strong band, which we assigned as the nu(1)+nu(9) C-H stretch vibration, and five additional bands related to transitions to coupled states. The spectral features were modeled in terms of a six-state deperturbation analysis, revealing the energies of the zero-order states and the relatively strong couplings between the initially excited nu(1)+nu(9) state and the doorway states. Considering these energies and the fundamental frequencies of 1,2-trans-d(2)-ethene and presuming that only low-order resonances are involved in the couplings enabled the assignment of the states. The analysis also allowed obtaining insight on energy flow and to find out that the energy oscillations between the C-H stretch state and the doorway states occur on a subpicosecond time scale. 相似文献
46.
Matthias Hlderle Georg Bar Rolf Mülhaupt 《Journal of polymer science. Part A, Polymer chemistry》1997,35(13):2539-2548
A novel oxazoline-functional methacrylate was prepared and employed as comonomer to produce nonaqueous dispersions of oxazoline-functional polymer particles. In nonaqueous free radical dispersion copolymerization of methylmethacrylate in the presence of oxazoline-functional methacrylate, ethyleneglycoldimethacrylate crosslinking agent, AIBN initiator, and polystyrene-block-poly(ethene-alt-propene) dispersing agent, the average polymer particle size, varying between 100 and 500 nm, was controlled by the dispersing agent contents. According to titration with HClO4 all oxazoline groups regardless of their location at particle surface or bulk, were accessible. Glass transition temperature decreased from 120 to 0°C when oxazoline functional methacrylate was increased from 0 to 95 mol %. As imaged by atomic force microscopy incorporation of the new oxazoline-functional methacrylate improved film formation. Oxazoline-functional polymer particles were easy to redisperse in a variety of other diluents. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 2539–2548, 1997 相似文献
47.
Bespechansky E Portnov A Zwielly A Rosenwaks S Bar I 《The Journal of chemical physics》2006,125(13):133301
H and D photofragments produced via vibrationally mediated photodissociation of jet-cooled normal ethene (C2H4), 1,2-trans-d2-ethene (HDCCDH), and 1,1-d2-ethene (CH2CD2), initially excited to the fourth C-H stretch overtone region, were studied for the first time. H and D vibrational action spectra and Doppler profiles were measured. The action spectra include partially resolved features due to rotational cooling, while the monitored room temperature photoacoustic spectra exhibit only a very broad feature in each species. Simulation of the spectral contours allowed determination of the band types and origins, limited precision rotational constants, and linewidths, providing time scales for energy redistribution. The H and D Doppler profiles correspond to low average translational energies and show slight preferential C-H over C-D bond cleavage in the deuterated variants. The propensities toward H photofragments emerge even though the energy flow out of the initially prepared C-H stretch is on a picosecond time scale and the photodissociation occurs following internal conversion, indicating a more effective release of the light H atoms. 相似文献
48.
Didier Villemin Nawel Cheikh Nathalie Bar Mohamed A. Didi 《Tetrahedron letters》2006,47(31):5519-5521
The reaction of four α-hydroxyketones 1a-d with a double equivalent of t-butyl acetylacetonate in the presence of KF-alumina under microwave irradiation afforded 6-acetyl-5-hydroxy-3,3-dialkyl-7-methyl isobenzofuran-1(3H)-ones 3a-d. 相似文献
49.
The statistical properties of the estimated eye aberrations differ in general from the actual ones owing to the cross coupling and aliasing generated in the estimation process. In particular, the estimated Zernike aberration coefficients may show fictitious correlations that are not present in the incoming wavefronts. This fact should be taken into account when analyzing estimated aberration datasets, searching for correlations related to physiological eye features. We give an analytical model for this effect and evaluate its magnitude for a particular example, assuming that the true aberration statistics follows a Kolmogorov power law. 相似文献
50.
A Novel Method for the Synthesis of Newfangled Asymmetric Schiff Bases from α‐amino Acids under Ultrasonic Conditions and in Aqueous Medium 下载免费PDF全文
Kıvılcım Şendil Turgay Tekin Haydar Göksu Mehmet Oğuz Barış Anıl Mehmet Serdar Gültekin 《中国化学会会志》2016,63(9):808-817
Chiral Schiff bases were obtained at high yields via a novel technique. Aryl aldehydes and chiral α‐amino acids were treated (1) in the presence of H3PO4 in ethanol at 80°C for 24 h, and (2) in the presence of K2CO3 under ultrasonic conditions in an aqueous ethanol medium within 5 min with yields reaching up to 96%. The results showed that the presented methodology under ultrasonic conditions was effective, practical, and eco‐friendly compared to that using an acidic medium. The corresponding asymmetric Schiff bases were synthesized for the first time, and were characterized by 1H and 13C nuclear magnetic resonance and infrared spectroscopy and high‐resolution mass spectrometry. 相似文献