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71.
The second order Grüneisen constant constitutes an additional measure of the anharmonicity in a solid (the Grüneisen constant itself being the first measure). This quantity and the corresponding second mode-Grüneisen parameters are calculated for CsBr using a modified rigid ion model of lattice dynamics. The model parameters are deduced from the three elastic constants and the long wavelength optical mode frequencies. Using the first and second order pressure dependences of these physical observables, the individual second mode-Grüneisen parameters are obtained as a function of wave vector. The temperature variation of the second Grüneisen constant is then deduced in a quasi-harmonic approximation. The second Grüneisen constant is also calculated from available thermodynamic data and is in reasonable agreement with the present theoretical prediction. 相似文献
72.
The expression for the memory function of Corngold et al. has been modified using an effective potential for liquid sodium to calculate the velocity autocorrelation function and the coefficient of self diffusion. The results are found in good agreement with computer experiment results of Schiff. 相似文献
73.
The local or gap mode frequencies of a host lattice-point defect system. XY:Z may be predicted from the properties of the end member pure crystals XY and XZ alone whenever pertinent data on pure crystals are available, without invoking any arbitrary force constant softening. In this instance the molecular model has been used, and relevant examples from alkali halides are presented. A modification of the Green's function technique is also discussed. 相似文献
74.
We consider a model for elastic scattering and inelastic diffractive production at high energy, which is inspired by Quantum Chromodynamics. The pomeron arises in our model from gluon exchange between quark constituents. The color-neutrality of each hadron implies strong cancellations among the gluon exchanges. Hence our model is “subtractive”, in contrast to the old “additive” quark model. The subtractive model provides a natural explanation for the large cross section which is observed for diffractive dissociation. We show that multiple gluon exchange contributes significantly, alongside two gluon exchange, in building the pomeron. 相似文献
75.
76.
Upon adsorption of various vapours, the electrical conductivity of lycopene semiconductor changes appreciably This phenomenon had been used as a probe to study the adsorption and desorption processes in these polyene crystals The adsorption and desorption kinetics have been found to follow a modified Roginsky-Zeldovich relation A three-stage adsorption process has been identified The first stage gives a Lennard-Jones potential energy curve, followed by a transition over a potential barrier to the second stage of adsorption in a potential well In the third stage a deep potential energy surface is reached by activation over a second potential barrier and strongly bound complexes between the vapour molecules and the surface molecules of the crystals are finally formed. 相似文献
77.
We study turbulence in the one-dimensional Burgers equation with a white-in-time, Gaussian random force that has a Fourier-space spectrum approximately 1/k, where k is the wave number. From very high-resolution numerical simulations, in the limit of vanishing viscosity, we find evidence for multiscaling of velocity structure functions which cannot be falsified by standard tests. We find a new artifact in which logarithmic corrections can appear disguised as anomalous scaling and conclude that bifractal scaling is likely. 相似文献
78.
We present the first study of the dynamic scaling or multiscaling of passive-scalar turbulence. For the Kraichnan version of passive-scalar turbulence we show analytically, in both Eulerian and quasi-Lagrangian frameworks, that simple dynamic scaling is obtained but with different dynamic exponents. By developing the multifractal model we show that dynamic multiscaling occurs in passive-scalar turbulence only if the advecting velocity field is itself multifractal. We substantiate our results by detailed numerical simulations in shell models of passive-scalar advection. 相似文献
79.
We show that different ways of extracting time scales from time-dependent velocity structure functions lead to different dynamic-multiscaling exponents in fluid turbulence. These exponents are related to equal-time multiscaling exponents by different classes of bridge relations, which we derive. We check this explicitly by detailed numerical simulations of the Gledzer-Ohkitani-Yamada shell model for fluid turbulence. Our results can be generalized to any system in which both equal-time and time-dependent structure functions show multiscaling. 相似文献
80.