Akustische Rastermikroskopie als Methode zur Oberfl?chenuntersuchung

Summary Techniques of scanning acoustic microscopy generally rely on local variations of such solid state parameters influencing generation or propagation of acoustic waves. Depending on the manner of impressing acoustic waves into the sample various methods are distinguished. In conventional scanning acoustic microscopy ultrasound is generated by a lens-transducer arrangement outside the sample and focussed onto or below its surface. Changes in the propagation of this ultrasound wave, like absorption and reflexion or temporal propagation delays, enable analysis of the mechanical or elastic response. At very high frequencies and with additional time-resolving detection techniques applications of this technique to surface analysis become possible. Other scanning acoustic microscopes imply the generation of sound or ultrasound directly within the sample itself due to the impact of temporarily modulated particle or photon beams. These are presently laser, electron, or ion beams. With these methods the acoustic signal as detected by a transducer attached to the sample is on principle affected by propagation properties, too, but it is dominated by local changes of the generation process for the acoustic wave, mainly because the frequency ranges used presently are associated with very long acoustic wavelengths. Depending on the physical nature of the primary probe used many sound generation mechanisms are given resulting in a large amount of different applications. By adjusting the probe parameters in a suitable manner the sound generation process can be confined to the direct vicinity of the specimen surface, which makes this technique feasible for surface characterization. The principles of the various techniques are described, and their usability for surface analysis is discussed.     

Covariant trace formalism for heavy mesons-wave top-wave transitions

Heavy meson,s- top-wave, weakb→c transitions are studied in the context of the heavy quark effective theory using covariant meson wave functions. We use the trace formalism to evaluate the weak transitions. As expected from heavy quark symmetry, the eight transitions betweens- andp-wave states are described in terms of only two universal form factors which are given in terms of explicit wave function overlap integrals. We present our results in terms of both invariant and helicity amplitudes. Using our helicity amplitude expressions we discuss rate formulae, helicity structure functions and joint angular decay distributions in the decays \(\bar B \to D^{**} ( \to (D,D^* ) + \pi ) + W^ - ( \to l^ - \bar v_l )\) . The heavy quark symmetry predictions for the one pion transitionsD ^**→(D,D ^*)+π are similarly worked out by using trace techniques.     

Growth of density inhomogeneities in a flow of wave turbulence

We consider the flow being a superposition of random waves and describe the evolution of the spectrum of the passive scalar in the leading (fourth) order with respect to the wave amplitudes. We find that wave turbulence can produce an exponential growth of the passive scalar fluctuations when either both solenoidal and potential components are present in the flow or there are potential waves with the same frequencies but different wave numbers.     

Ion implantation induced stoichiometric imbalance in SiO2

Carrier trapping was studied to understand the displacement damage caused by ion implantation in SiO₂. Implantation causes local departures from stoichiometry due to different recoil behavior of Si and O atoms. To avoid chemical interaction with the oxide network noble gas implants were used. It is shown that a fraction of the defects is not removed even after extended high temperature treatment. Data on isochronal annealing steps and on the spatial distribution of the non-stoichiometry are given.     

Separation of cold medicine ingredients using a precise MEKC method at elevated pH

An MEKC method was developed in order to separate a cold medicine formulation containing acetaminophen, ephedrine sulfate, doxylamine succinate, and dextromethorphan hydrobromide as active pharmaceutical ingredients. Because of their similar physical and chemical properties, it was a challenge to separate the basic compounds without sample pretreatment. In addition, the high content of alcohol and sucrose together with the variety of further excipients had to be considered. Thus, the complex matrix required several optimization steps. These included the search for the optimum pH and for a suitable sodium dodecyl sulfate concentration to avoid matrix-capillary wall interaction and to ensure precision. As a second developing step, an internal standard (benzocaine) was chosen to guarantee a high level of quantitative performance. An RSD% value of the peak areas between 1.0 and 2.0 was reached. The employed method development strategy can be generalized to similar separation approaches in the future.