全文获取类型
收费全文 | 241篇 |
免费 | 8篇 |
专业分类
化学 | 132篇 |
晶体学 | 1篇 |
力学 | 23篇 |
数学 | 15篇 |
物理学 | 78篇 |
出版年
2022年 | 4篇 |
2020年 | 6篇 |
2018年 | 5篇 |
2017年 | 2篇 |
2016年 | 6篇 |
2015年 | 4篇 |
2014年 | 7篇 |
2013年 | 15篇 |
2012年 | 14篇 |
2011年 | 13篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 5篇 |
2007年 | 10篇 |
2006年 | 4篇 |
2005年 | 6篇 |
2004年 | 4篇 |
2003年 | 7篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 12篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 8篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 1篇 |
1977年 | 6篇 |
1976年 | 6篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 2篇 |
1970年 | 1篇 |
1966年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有249条查询结果,搜索用时 15 毫秒
71.
Summary Synthesis of MHNAMT [3-methyl-4-(2-hydroxy-1 naphthalideneamino)-5-mercapto-1,2,4-triazole] and its IR and NMR spectral data are reported. The high stability of the characteristically coloured chelates with Cu(II), Co(II), Ni(II), Pd(II), Pt(IV) and Rh(III) has been made the basis for their efficient ascending TLC separations on silica gel G layers, when present together. Results of three different solvent systems are included to assess efficient resolution of the chelates. 相似文献
72.
A host-guest optical sensor for the determination of aliphatic amines as exemplified by octylamine is proposed. It is based on the reversible fluorescence enhancement of heptakis(2,6-di-O-isobutyl)-β-cyclodextrin(DOB-β-CD) hosting tetraphenylporphyrin (TPP) immobilized in poly(vinyl chloride) (PVC) membrane by aliphatic amine extracted from aqueous phase into membrane phase. The optimum membrane contained 1.15 wt % TPP, 6.15 wt % DOB-β-CD as sensing reagent and other membrane materials. The fluorescence enhancement of the membrane resulted from the formation of a stable three-component complex among DOB-β-CD, TPP, and aliphatic amines. With the optimum conditions described, the fluorescence response of the sensor to octylamine shows a good correlation with the theoretically derived equation in the range 1.0 × 10–6 to 8.0 × 10–4 mol/L. The response characteristics including reversibility, response time, reproducibility and lifetime and selectivity of this optical device are also discussed in detail. This sensor has also been applied for the determination of octylamine in water samples containing interferents with satisfactory recovery. 相似文献
73.
KM Clauwaert Van Bocxlaer JF HJ Major JA Claereboudt WE Lambert Van den Eeckhout EM Van Peteghem CH De Leenheer AP 《Rapid communications in mass spectrometry : RCM》1999,13(14):1540-1545
This paper describes the investigation of the potential of a quadrupole orthogonal acceleration time-of-flight mass spectrometer (Q-TOF) equipped with an atmospheric pressure ionisation interface for quantitative measurements of small molecules separated by reversed phase liquid chromatography. To this end, the detection limits and linear dynamic range in particular were studied in an LC/MS/MS experiment using 3,4-methylenedioxymethamphetamine standards and 3,4-methylenedioxyethylamphetamine for internal standardisation. In a second phase, the experiment was repeated with real biological extracts (whole blood, serum, and vitreous humour). A calibration for 3,4-methylenedioxymethamphetamine and its metabolite 3,4-methylenedioxyamphetamine was prepared in each of these matrices again using 3,4-methylenedioxyethylamphetamine as internal standard. The resulting quantitative data were compared with those obtained by liquid chromatography with fluorescence detection for the same extracts. The Q-TOF results revealed excellent sensitivity and a linear dynamic range of nearly four decades (2-10 000 pg on-column, r(2) = 0.9998, 1/x weighting). Furthermore, all the calibration curves prepared in biological material were superimposable, LC/MS/MS and LC-fluorescence, and the quantitative results for actual samples compared very favourably. It was concluded that the Q-TOF achieves a linear dynamic range for quantitative LC/MS/MS work exceeding that of fluorescence detection and at much better absolute sensitivity. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
74.
Bajaj VS Farrar CT Hornstein MK Mastovsky I Vieregg J Bryant J Eléna B Kreischer KE Temkin RJ Griffin RG 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,160(2):85-90
In this communication, we report enhancements of nuclear spin polarization by dynamic nuclear polarization (DNP) in static and spinning solids at a magnetic field strength of 9T (250 GHz for g=2 electrons, 380 MHz for 1H). In these experiments, 1H enhancements of up to 170+/-50 have been observed in 1-13C-glycine dispersed in a 60:40 glycerol/water matrix at temperatures of 20K; in addition, we have observed significant enhancements in 15N spectra of unoriented pf1-bacteriophage. Finally, enhancements of approximately 17 have been obtained in two-dimensional 13C-13C chemical shift correlation spectra of the amino acid U-13C, 15N-proline during magic angle spinning (MAS), demonstrating the stability of the DNP experiment for sustained acquisition and for quantitative experiments incorporating dipolar recoupling. In all cases, we have exploited the thermal mixing DNP mechanism with the nitroxide radical 4-amino-TEMPO as the paramagnetic dopant. These are the highest frequency DNP experiments performed to date and indicate that significant signal enhancements can be realized using the thermal mixing mechanism even at elevated magnetic fields. In large measure, this is due to the high microwave power output of the 250 GHz gyrotron oscillator used in these experiments. 相似文献
75.
We present measurements of the Nusselt number N as a function of the Rayleigh number R in cylindrical cells with aspect ratios 0. 5=gamma identical withD/d=12.8 ( D is the diameter and d is the height). We used acetone with a Prandtl number sigma = 4.0 for 10(5) less, similarR less, similar4x10(10). A fit of a power law N = N(0)R(gamma(eff)) over limited ranges of R yielded values of gamma(eff) from 0.275 near R = 10(7) to 0.300 near R = 10(10). The data are inconsistent with a single power law for N(R). For R>10(7) they are consistent with N = asigma-1/12R1/4+bsigma-1/7R3/7 as proposed by Grossmann and Lohse for sigma greater, similar2. 相似文献
76.
77.
78.
D.C. Reynolds D.W. Langer C.W. Litton G.L. McCoy K.K. Bajaj 《Solid State Communications》1983,46(6):473-476
A self-reversal model is presented to explain the luminescence dependence of the donor bound exciton intensity. The line broadening mechanism is attributed to rotational interaction with non-rigid rotator states. Line reversal results from absorption by non-broadened states near the crystal surface. The absence of a similar excitation intensity dependence for acceptor bound excitons is explained. 相似文献
79.
D.C. Reynolds C.W. Litton E.B. Smith P.W. Yu K.K. Bajaj 《Solid State Communications》1982,42(11):827-830
Recombination radiation due to an exciton bound to neutral donors and neutral acceptors in high purity vapor phase epitaxial GaAs is investigated using high resolution photoluminescence spectroscopy at liquid helium temperatures. It is found that those samples which show the presence of germanium acceptors also exhibit a strong residual donor referred to in the literature as X3. Samples containing carbon acceptors however, do not show the presence of X3. In the past X3 has been identified by some groups as due to carbon on the gallium site. The work presented here sugests that the X3 donor is associated with germanium. This identification of the X3 donor is in agreement with a recent assignment based on the far infrared study of neutron transmuted GaAs. 相似文献
80.
We study in detail the factors that influence the unification relations among the coupling parameters of strong and electroweak interactions. We find that the factor that decides the unification relations in a theory is the fermion content of the theory. The specific ‘observed’ group of strong and electroweak interactions used and the specific unification group in which these interactions are embedded are largely irrelevant. In particular, we find that the unification value of the electroweak mixing angle is the same for almost all models of interest. We also explicitly illustrate that the canonical value 3/8 of the mixing angle is a characteristic result of the currently popular sequential doublets scheme of fermions. Addition of extra fermion singlets reduces the mixing angle to 1/4. We propose this sequential triplets scheme of fermions as an interesting alternative to the current scheme. 相似文献