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61.
C.J. Foot P.E.G. Baird M.G. Boshier D.N. Stacey G.K. Woodgate 《Optics Communications》1984,50(3):199-204
Intra-cavity second harmonic generation in a ring dye laser using lithium formate monohydrate has been observed to produce tunable cw UV radiation around 243 nm with single frequency powers of up to 1.4 mW. This wavelength region is of particular interest in the context of Doppler-free spectroscopy of atomic hydrogen. The radiation was used to excite an atomic beam of strontium to study the transition 5s2 1S0-4d5p 1P1 of Sr I. The isotope shifts were determined as follows: 88Sr-87Sr 123.7(8) MHz; 88Sr 285.0(8) MHz; 88Sr-84Sr 600.1(9) MHz. The values are compared with results for other lines and muonic isotope shifts to obtain the specific mass shift and field shift in this transition and to study the configuration mixing effects. The hyperfine structure of 87Sr was not resolved, the intervals being very much less than the measured linewidth of 25 MHz. 相似文献
62.
Nils O. Nilsen Lars Skattebøl Mark S. Baird Sheila R. Buxton Paul D. Slowey 《Tetrahedron letters》1984,25(27):2887-2890
Reaction of the dibromides (5) and (10) with methyl lithium in ether leads to products derived by 1,3-dehalogenation, (6) and (11), whereas (15) and (16) undergo 1,1-dehalogenation and rearrangement to allenes, (17) and (18). 相似文献
63.
Abe K Abt I Ahn CJ Akagi T Allen NJ Ash WW Aston D Baird KG Baltay C Band HR Barakat MB Baranko G Bardon O Barklow T Bazarko AO Ben-David R Benvenuti AC Bienz T Bilei GM Bisello D Blaylock G Bogart JR Bolton T Bower GR Brau JE Breidenbach M Bugg WM Burke D Burnett TH Burrows PN Busza W Calcaterra A Caldwell DO Calloway D Camanzi B Carpinelli M Cassell R Castaldi R Castro A Cavalli-Sforza M Church E Cohn HO Coller JA Cook V Cotton R Cowan RF Coyne DG D'Oliveira A Damerell CJ Daoudi M 《Physical review D: Particles and fields》1996,53(3):1023-1038
64.
Abe K Abt I Ahn CJ Akagi T Allen NJ Ash WW Aston D Baird KG Baltay C Band HR Barakat MB Baranko G Bardon O Barklow T Bazarko AO Ben-David R Benvenuti AC Bienz T Bilei GM Bisello D Blaylock G Bogart JR Bolton T Bower GR Brau JE Breidenbach M Bugg WM Burke D Burnett TH Burrows PN Busza W Calcaterra A Caldwell DO Calloway D Camanzi B Carpinelli M Cassell R Castaldi R Castro A Cavalli-Sforza M Church E Cohn HO Coller JA Cook V Cotton R Cowan RF Coyne DG D'Oliveira A Damerell CJ Daoudi M 《Physical review letters》1995,75(23):4173-4177
65.
66.
Abe K Abt I Ahn CJ Akagi T Ash WW Aston D Bacchetta N Baird KG Baltay C Band HR Barakat MB Baranko G Bardon O Barklow T Bazarko AO Ben-David R Benvenuti AC Bienz T Bilei GM Bisello D Blaylock G Bogart JR Bolton T Bower GR Brau JE Breidenbach M Bugg WM Burke D Burnett TH Burrows PN Busza W Calcaterra A Caldwell DO Calloway D Camanzi B Carpinelli M Cassell R Castaldi R Castro A Cavalli-Sforza M Church E Cohn HO Coller JA Cook V Cotton R Cowan RF Coyne DG D'Oliveira A Damerell CJ Dasu S 《Physical review letters》1995,74(15):2895-2899
67.
Reaction of 2,2′-bipyridine-6-carboxaldehyde with the appropriate aliphatic diamine in MeOH and subsequent reduction with NaBH4 gives the new, potentially hexadentate, ligands N,N′-bis(2,2′-bipyridin-6-ylmethyl)ethane-1,2-diamine (bmet), N,N′-bis(2,2′-bipyridin-6-ylmethyl)propane-1,3-diamine (bmpp) and N,N′-bis(2,2′-bipyridin-6-ylmethyl)hexane-1,6-diamine (bmhx). The syntheses and characterisation of these ligands are reported; the ligands are isolated as the hydrochloride salts, with purification effected by either recrystallisation or cation exchange chromatography. [Co(bmet)](ClO4)3 · H2O is obtained on reaction of bmet · 4.25HCl · 2.5H2O with Na3[Co(O2CO)3] · 3H2O, and X-ray structural analysis shows this to have a pair of very short Co–N bonds. The synthesis and characterisation of the first coordination complex containing 6-(aminomethyl)-2,2′-bipyridine (amb) is also described. 相似文献
68.
The compounds (π-C6H6)Ru(R)Cl(PPh3) (RCH3, C6H5), (π-C6H6)RuCl(π-C3H5) and [(π-C6H6)Ru(π-C5H5)]Cl are described. The 31P NMR spectra of a series of tertiary phosphine complexes of the π-benzeneruthenium system are also reported. 相似文献
69.
The concept of ionic character in and bond systems is considered in the light of recent definitions of orbital electronegativity [6, 14].
We wish to acknowledge financial support from the National Research Council of Canada. One of us (N.C.B.) thanks the council for the award of a studentship. 相似文献
Zusammenfassung Das Konzept des ionischen Charakters in und Bindungen wird im Lichte neuerer Definitionen von Orbitalelektronegativitäten diskutiert.
Résumé Le caractère ionique des liaisons et est discuté en tenant compte des définitions récentes de l'électronégativité des orbitales.
We wish to acknowledge financial support from the National Research Council of Canada. One of us (N.C.B.) thanks the council for the award of a studentship. 相似文献
70.
Ryan D Madder Chu-Young Kim Pooja P Chandra Jeffrey B Doyon Teaster A Baird Carol A Fierke David W Christianson Judith G Voet Ahamindra Jain 《The Journal of organic chemistry》2002,67(2):582-584
QSAR has been used to elucidate the origin of the hydrophobicity and binding affinity of a small library of fluoroaromatic inhibitors of F131V carbonic anhydrase II. Our analysis predicted the presence of a twisted amide conformation for several bound inhibitors, which we confirmed crystallographically. We also determined that the hydrophobicity of the inhibitors as a whole results from the fragment hydrophobicities of their fluorobenzyl rings, corrected for field effects and the presence of an intramolecular F.H contact in solution. The loss of this interaction on binding to the enzyme makes the affinity sensitive to the same terms, but with the opposite dependence on the F.H contact. In the case of the four inhibitors bound as twisted amides, this F.H contact must be retained to some extent in the bound state in order for their affinities to be consistent with our QSAR analysis of the entire set of 17 molecules. 相似文献