全文获取类型
收费全文 | 4945篇 |
免费 | 787篇 |
国内免费 | 546篇 |
专业分类
化学 | 3402篇 |
晶体学 | 46篇 |
力学 | 348篇 |
综合类 | 24篇 |
数学 | 609篇 |
物理学 | 1849篇 |
出版年
2024年 | 25篇 |
2023年 | 103篇 |
2022年 | 164篇 |
2021年 | 199篇 |
2020年 | 200篇 |
2019年 | 193篇 |
2018年 | 184篇 |
2017年 | 137篇 |
2016年 | 277篇 |
2015年 | 230篇 |
2014年 | 259篇 |
2013年 | 381篇 |
2012年 | 478篇 |
2011年 | 456篇 |
2010年 | 308篇 |
2009年 | 286篇 |
2008年 | 306篇 |
2007年 | 249篇 |
2006年 | 244篇 |
2005年 | 210篇 |
2004年 | 185篇 |
2003年 | 158篇 |
2002年 | 132篇 |
2001年 | 111篇 |
2000年 | 94篇 |
1999年 | 100篇 |
1998年 | 73篇 |
1997年 | 73篇 |
1996年 | 74篇 |
1995年 | 61篇 |
1994年 | 45篇 |
1993年 | 45篇 |
1992年 | 28篇 |
1991年 | 39篇 |
1990年 | 36篇 |
1989年 | 26篇 |
1988年 | 12篇 |
1987年 | 12篇 |
1986年 | 15篇 |
1985年 | 18篇 |
1984年 | 10篇 |
1983年 | 10篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1974年 | 2篇 |
1944年 | 4篇 |
1943年 | 1篇 |
1942年 | 3篇 |
1941年 | 1篇 |
1940年 | 1篇 |
排序方式: 共有6278条查询结果,搜索用时 21 毫秒
81.
As the hardware of FLIM technique becomes mature, the most important criterion for FLIM application is the correct interpretation of its data. In this research, first of all, a more orthogonal phasor approach, called as Modified Phasor Approach (MPA), is put forward. It is a way to calculate the lifetime of the complex fluorescent process, and a rule to measure how much the fluorescence process deviates from single exponential decay. Secondly, MPA is used to analysis the time-resolved fluorescence processes of the transfected CHO-K1 Cell lines expressing adenosine receptor A1R tagged by CYP and YFP, measured in the channel of the acceptor. The image of the fluorescence lifetime and the multiplication of the fluorescence lifetime and deviation from single exponential decay reveal the details of the Homo-FRET. In one word, MPA provides the physical meaning in its whole modified phasor space, and broadens the way for the application of the fluorescence lifetime imaging. 相似文献
82.
83.
Sen‐Wang Zhang Ling‐Pan Lu Bai‐Xiang Li Yue‐Sheng Li 《Journal of polymer science. Part A, Polymer chemistry》2012,50(22):4721-4731
Vanadium(III) complexes bearing phenoxy‐phosphine ligands ( 2a–g ) (2‐R1‐4‐R2‐6‐PPh2‐C6H2O)VCl2(THF)2 ( 2a : R1 = R2 = H; 2b : R1 = F, R2 = H; 2c : R1 = Ph, R2 = H; 2d : R1 = tBu, R2 = H; 2e : R1 = R2 = Me; 2f : R1 = R2 = tBu; 2g : R1 = R2 = CMe2Ph) were prepared from VCl3(THF)3 by treating with 1.0 equiv of the ligand in tetrahydrofuran (THF) in the presence of excess triethylamine (TEA). The reaction of VCl3(THF)3 with 2.0 equiv of the ligand in THF in the presence of excess TEA afforded vanadium(III) complexes bearing two phenoxy‐phosphine ligands ( 3c–f ). These complexes were characterized by FTIR and mass spectrum as well as elemental analyses. Structures of 2f and 3c were further confirmed by X‐ray crystallographic analyses. Complexes 2a–g and 3c–f were employed as the catalysts for ethylene polymerization under various reaction conditions. On activation with Et2AlCl, these complexes exhibited high catalytic activities (up to 41.3 kg PE/mmolV·h·bar) even at high temperature (70°C), and produced high molecular weight polymer with unimodal molecular weight distributions, indicating the polymerization took place in a single‐site nature. Complexes 3c–f displayed better thermal stability than the corresponding complexes 2a–g under similar conditions. In addition, copolymerizations of ethylene and 1‐hexene with precatalysts 2a–g were also explored in the presence of Et2AlCl. Catalytic activity, comonomer incorporation, and properties of the resultant polymers can be controlled over a wide range by tuning catalyst structures and reaction parameters.© 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
84.
85.
86.
87.
In this paper, transmission properties through an array of compound unit with multiple concentric or eccentric annular apertures are numerically studied. It is demonstrated that the transmission of the compound structure is not a simple superposition of that of each annular aperture array but exhibit substantial changes in both the position and intensity of resonant peaks. It is also found that the gap plasmon resonance exhibit split peaks when the symmetry is broken, which can be well explained from the view of charge oscillation. These properties provide a method to achieve enhanced transmission in multi-frequencies simultaneously and are of significant applicable value to the design of tunable optical devices. 相似文献
88.
89.
Li Chenglang Dou Qiang Bai Zhifei Lu Quliang 《Journal of Thermal Analysis and Calorimetry》2015,122(1):407-417
Journal of Thermal Analysis and Calorimetry - The effect of cadmium phenylmalonate (PMA-Cd) as a novel nucleating agent on the crystallization behaviors and spherulitic morphology of poly(lactic... 相似文献
90.
PG 1407+265 is a radio quiet quasar that has a relativistic jet.In this report,we show some peculiar properties of its optical and X-ray emissions,which indicate possible non-thermal origins produced from the jet.We use a simple synchrotron + synchrotron self Compton (SSC) model to fit the emissions with different ratios of energy densities between the magnetic field and electrons (η≡U B/U e),which predicts a different γ-ray luminosity.The First LAT AGN Catalog (1LAC) did not include PG 1407+265,which indic... 相似文献