全文获取类型
收费全文 | 259篇 |
免费 | 6篇 |
专业分类
化学 | 152篇 |
力学 | 1篇 |
数学 | 5篇 |
物理学 | 107篇 |
出版年
2022年 | 2篇 |
2021年 | 3篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2014年 | 8篇 |
2013年 | 12篇 |
2012年 | 19篇 |
2011年 | 8篇 |
2010年 | 4篇 |
2009年 | 8篇 |
2008年 | 8篇 |
2007年 | 10篇 |
2006年 | 14篇 |
2005年 | 13篇 |
2004年 | 11篇 |
2003年 | 11篇 |
2002年 | 7篇 |
2001年 | 8篇 |
2000年 | 5篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1930年 | 2篇 |
1927年 | 3篇 |
1926年 | 1篇 |
1925年 | 1篇 |
1923年 | 1篇 |
排序方式: 共有265条查询结果,搜索用时 15 毫秒
41.
Crouse CA Maruyama B Colorado R Back T Barron AR 《Journal of the American Chemical Society》2008,130(25):7946-7954
Carbon nanotubes (CNTs) have been grown using Fe, Co, Ni, and Co/Fe spin-on-catalyst (SOC) systems, involving the metal salt dispersed with a spin-on-glass precursor. During initial growth runs (CH4/H2/900 degrees C), the CNT yield followed the order Co-SOC > Fe-SOC > Ni-SOC. The Fe catalysts produced the longest nanotubes at the expense of a larger average CNT diameter and broader diameter distribution than the Co-SOC system. A series of Co/Fe-SOCs were prepared where as the atomic percentage of Co is increased nucleation of CNT increases but the CNT length decreases. The linear relationship between the diameter and length of CNTs grown from the Co/Fe-SOC suggests that slow growth is beneficial with respect to control over CNT diameter. After initial CNT growth, the original samples were subjected to additional growth runs. Four individual reactions were observed in the Fe-SOC and binary Co/Fe-SOC: regrowth (amplification), double growth (a second CNT growing from a previously active catalyst), CNT etching, and nucleation from initially inactive catalysts (new growth). CNT etching was observed for the mixed catalyst systems (Co/Fe-SOC) but not for either Fe-SOC or Co-SOC. During the regrowth experiments, CNTs were observed that were not present after the initial growth run (and were not as a result of amplification or double growth). Thus, catalysts, which were initially inactive toward nucleation of CNTs in the original growth run, are capable of becoming activated when placed back into the furnace and submitted to regrowth under identical conditions. 相似文献
42.
Back DF de Oliveira GN Burrow RA Castellano EE Abram U Lang ES 《Inorganic chemistry》2007,46(7):2356-2358
The reaction of Hg(TePh)2 with AgX (X = Cl, NO3) in the presence of PPh3 and PMePh2 in dimethylformamide (DMF) affords the cluster [Hg6Ag4(TePh)16] (1) at room temperature or [Hg6Ag4Te(TePh)14]2 (2) with heating. When Hg(TePh)2 is reacted with [Co(PPh3)2Cl2] or [Ni(PPh3)2Cl2], the clusters [Hg8Te(PhTe)12Cl4]Q [3; Q = [Co(DMF)6]2+ (3a), [Ni(DMF)6]2+ (3b)] are formed. The syntheses of 1 and 2 occur with the incorporation of AgI into the cluster, and the single-crystal analyses show that the two ternary clusters consist of Hg, Ag, and Te centers occupying well-defined positions. Compounds 3a and 3b do not show the incorporation of the metal into the cluster, but the CoII and NiII salts provide the Cl atom to generate the anionic cluster 3 stabilized by the [Co(DMF)6]2+ or [Ni(DMF)6]2+ ion. 相似文献
43.
The cyclization of gamma-chloroamine 11, derived from l-alanine, and acetylenic sulfone 12 afforded the dehydropiperidine 19 via conjugate addition followed by intramolecular alkylation of the corresponding sulfone-stabilized anion. An unexpected acid-catalyzed desulfonylation of 19 occurred in one step via desilylation and tautomerization of the enamine moiety to the corresponding aldehyde, followed by elimination of p-toluenesulfinic acid. The highly stereoselective reduction of the resulting unsaturated aldehyde 25 with sodium cyanoborohydride produced piperidine 23 with a diastereomeric ratio of >98:2. (-)-(ent)-Julifloridine (8) was obtained by Swern oxidation of 23, followed by Wittig olefination and hydrogenation/debenzylation. 相似文献
44.
E. Heindl C. Kefes M. Soda J. Vancea C.H. Back 《Journal of magnetism and magnetic materials》2009,321(22):3693-3697
We investigate spin-dependent hot electron transport through metallic epitaxial spin valves by ballistic electron magnetic microscopy (BEMM). By variation of the thickness of one of the ferromagnetic layers we determine the spin dependent attenuation lengths which reflect hot electron transport along the vicinity of the [1 0 0]-axis of the bcc Fe34Co66 lattice. The majority spin attenuation length is more than 6 times larger than that of the minority spins within the measured energy interval of 1.3 up to 2 eV above the Fermi level. Consequently a Magnetocurrent effect exceeding 1200% accompanied by a monotonic bias voltage behavior is observed at room temperature. 相似文献
45.
46.
AL Stein FN Bilheri JT da Rocha DF Back G Zeni 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(34):10602-10608
A copper-catalyzed cyclization of (ortho-alkynyl)benzaldimines with diorganoyl dichalcogenides allowed the synthesis of 4-organochalcogen isoquinolines, whereas the presence of base in the reaction medium inhibited the product formation producing the undesirable isoquinoline without the organochalcogen atom at the 4-position. The cyclization reaction was carried out by using CuI (20?%) as a catalyst with diorganoyl dichalcogenides (1.5?equiv) in the presence of DMF at 100?°C. Furthermore, the reaction did not require an argon atmosphere and was carried out in an open flask. The cyclization reaction tolerated a variety of functional groups both in ortho-alkynylbenzaldimines and diorganoyl dichalcogenides, such as trifluoromethyl, chloro, fluorine, and methoxyl, to give the six-membered heterocyclic ring exclusively through a 6-endo-dig cyclization process. The organochalcogen group present at the 4-position of the isoquinoline ring was further subjected to a selective chalcogen-lithium exchange reaction followed by the addition of aldehydes to afford the desired secondary alcohols in good yields. The obtained isoquinolines also proved to be suitable substrates for the Suzuki and Sonogashira coupling conditions affording the corresponding products through C?C bond formation. 相似文献
47.
J. Pedersen B. B. Back S. Bjørnholm J. Borggreen G. Sletten F. Azgui H. Emling H. Grein G. Seiler-Clark W. Spreng H. J. Wollersheim P. Walker 《Zeitschrift für Physik A Hadrons and Nuclei》1985,321(4):567-575
Results of a search for high-spin isomers in W and Os nuclei withN=104–107 are presented. Targets of48Ca and48, 50Ti are bombarded with a pulsed136Xe beam, and delayed gamma-radiation is detected by an array of NaI- and Ge-detectors. Several new isomers, with spin values up to ~22h, are found in178,180W and180, 182, 183Os. Markedly different decay patterns and hindrance factors are found in the Os isotopes as compared to the expectations based on theK-selection rule valid for axially symmetric nuclei. The findings are ascribed to the onset of triaxial distortions. 相似文献
48.
49.
50.