全文获取类型
收费全文 | 111篇 |
免费 | 0篇 |
专业分类
化学 | 46篇 |
晶体学 | 1篇 |
数学 | 15篇 |
物理学 | 49篇 |
出版年
2017年 | 1篇 |
2016年 | 3篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 5篇 |
2007年 | 2篇 |
2006年 | 3篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 2篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 4篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1972年 | 3篇 |
1971年 | 1篇 |
排序方式: 共有111条查询结果,搜索用时 21 毫秒
21.
L.M.M. Veugen J. van der Wal J. Wessels 《European Journal of Operational Research》1985,20(2):248-254
In this paper the possibility is investigated of using aggregation in the action space for some Markov decision processes of inventory control type. For the standard (s, S) inventory control model the policy improvement procedure can be executed in a very efficient way, therefore, aggregation in the action space is not of much use. However, in situations where the decisions have some aftereffect and, hence, the old decision has to be incorporated in the state, it might be rewarding to aggregate actions. Some variants for aggregation and disaggregation are formulated and analyzed. Numerical evidence is presented. 相似文献
22.
An Ft n.m.r. experiment is described which may lead to a substantial increase in the peak height of n.m.r. signals. 相似文献
23.
Ford WE Yasuda A Wessels JM 《Langmuir : the ACS journal of surfaces and colloids》2008,24(7):3479-3485
Coprecipitation of urea-melt modified carbon nanotubes and calcium carbonate from an aqueous solution by two methods yielded microcrystalline composite particles. Powders obtained by colloidal crystallization from a supersaturated solution that were isolated and dried soon after precipitation were a mixture of raspberry-shaped and rhombohedral particles. These were shown by infrared and X-ray diffraction analyses to be mainly calcite. Particles that were kept wet for 1 day or longer before being isolated were typically entirely rhombohedral with edge lengths in the range of 5-30 microm. Scanning electron microscopy investigations revealed that the nanotubes were adsorbed on the particle surface and also incorporated into the interior matrix. Removal of the calcium carbonate component by treating the particles with acid yielded nanotube shells whose size and shape reflected those of the original particles. 相似文献
24.
von Wrochem F Scholz F Schreiber A Nothofer HG Ford WE Morf P Jung T Yasuda A Wessels JM 《Langmuir : the ACS journal of surfaces and colloids》2008,24(13):6910-6917
The structure and electrical properties of self-assembled monolayers of cyclic aromatic and aliphatic dithioacetamides (1,4-bis(mercaptoacetamido)benzene and 1,4-bis(mercaptoacetamido)cyclohexane) and of mixed dithioacetamide/alkanethiol monolayers are characterized by X-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM) and contact angle goniometry. Both dithioacetamides are found to pack densely on Au(111), however the monolayers are poorly ordered as a result of hydrogen bond formation between the amide groups. The coassembly and the insertion method are compared for the formation of mixed dithioacetamide/alkanethiol monolayers. By coassembly, islands of dithioacetamides in a dodecanethiol matrix can only be obtained at a low dithioacetamide/dodecanethiol concentration ratio in solution (1/10) and by thermal annealing of the resulting monolayers. Small and well defined dithioacetamide domains are realized by insertion of dithioacetamides into defect sites of closely packed octanethiol monolayers. These domains are used to determine the molecular conductance by means of STM height profiles and molecular lengths resulting from density functional theory (DFT) calculations. The difference in the tunneling decay constant beta measured for aromatic dithioacetamides (beta = 0.74-0.76/A) and for aliphatic dithioacetamides (beta = 0.84-0.91/A) highlights the influence of the conjugation within the cyclic core on molecular conductance. 相似文献
25.
The transverse polarization of forward Λ hyperons produced in high-energy p–A collisions is expected to display an extremum at a transverse momentum around the saturation scale. This was first observed within the context of the McLerran–Venugopalan model which has an x -independent saturation scale. The extremum arises due to the kt-odd nature of the polarization-dependent fragmentation function, which probes approximately the derivative of the dipole scattering amplitude. The amplitude changes most strongly around the saturation scale, resulting in a peak in the polarization. We find that the observation also extends to the more realistic case in which the saturation scale Qs is x-dependent. Since a range of x and therefore Qs values is probed at a given transverse momentum and rapidity, this result is a priori not expected. Moreover, the measurement of Λ polarization over a range of xF values actually provides a direct probe of the x-dependence of the saturation scale. This novel feature is demonstrated for typical LHC kinematics and for several phenomenological models of the dipole scattering amplitude. We show that although the measurement will be challenging, it may be feasible at LHC. The situation at RHIC is not favorable, because the peak will likely be at too low transverse momentum of the Λ to be a trustworthy measure of the saturation scale. 相似文献
26.
27.
van de Waal BW 《Physical review letters》1991,67(23):3263-3266
28.
29.
Dieter Seebach Jennifer L. Matthews Anton Meden Thomas Wessels Christian Baerlocher Lynne B. McCusker 《Helvetica chimica acta》1997,80(1):173-182
The solid-state structures of three stereoisomer, 1–3 , of the cyclic tetramer of 3-aminobutanoic acid are presented. These cyclo-β-peptides were found to be highly insoluble materials, and it proved to be impossible to grow crystals of sufficient quality for X-ray single-crystal analysis. The samples of 1–3 were, however, suitable candidates for structure determination from powder diffraction data (Fig. 1), and the application of this method is described. All three isomers have been found to adopt tubular structures (Figs. 2–4) in a fashion similar to those already observed for certain cyclo-α-peptides. The stacks of 16-membered rings are held together by four nonlinear C?O…?H? N H-bonds between pairs of molecules (Fig.5). 相似文献
30.
Nicole Stieger Wilna Liebenberg Johanna C. Wessels Halima Samsodien Mino R. Caira 《Structural chemistry》2010,21(4):771-777
X-ray structural and thermoanalytical data for a series of solvates 2–7 of the anti-HIV drug nevirapine containing primary alcohols CH3(CH2) n OH with n = 2–7 are reported. The structures of 2–7 are based on a common isostructural framework comprising centrosymmetric hydrogen-bonded nevirapine dimers and contain a common channel parallel to the crystal b-axis whose repeat length spans a narrow range (~8.43–8.52 Å) in the series and accommodates the various solvent molecules in 2–7. Thermogravimetry yielded a guest–host ratio close to 0.5 for the 1-butanol solvate 3 and a steady decrease in this ratio from 0.43 to 0.32 for the solvates 4–7. This anomalous stoichiometric variation was resolved following successful X-ray analysis of solvate 3 which revealed that the length spanned by the disordered 1-butanol molecule is commensurate with the channel periodicity b, resulting in a stoichiometric compound. Instead, solvates 5–7, for which single crystal X-ray data were available, showed significant disorder for the solvent molecules, attributed to their increasing chain lengths being incommensurate with the parameter b. 相似文献