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21.
There is a concentration-polarization (CP) force acting on a particle submerged in an electrolyte solution with a concentration (conductivity) gradient under an externally applied DC electric field. This force originates from the two mechanisms: (i) gradient of electrohydrodynamic pressure around the particle developed by the Coulombic force acting on induced free charges by the concentration polarization, and (ii) dielectric force due to nonuniform electric field induced by the conductivity gradient. A perturbation analysis is performed for the electric field, the concentration field, and the hydrodynamic field, under the assumptions of creeping flow and small concentration gradient. The leading order component of this force acting on a dielectric spherical particle is obtained by integrating the Maxwell and the hydrodynamic stress tensors. The analytical results are validated by comparing the surface pressure and the skin friction to those of a numerical analysis. The CP force is proportional to square of the applied electric field, effective for electrically neutral particles, and always directs towards the region of higher ionic concentration. The magnitude of the CP force is compared to that of the electrophoretic and the conventional dielectrophoretic forces. 相似文献
22.
We present parallelization of a quantum-chemical tree-code for linear scaling computation of the Coulomb matrix. Equal time partition is used to load balance computation of the Coulomb matrix. Equal time partition is a measurement based algorithm for domain decomposition that exploits small variation of the density between self-consistent-field cycles to achieve load balance. Efficiency of the equal time partition is illustrated by several tests involving both finite and periodic systems. It is found that equal time partition is able to deliver 91%-98% efficiency with 128 processors in the most time consuming part of the Coulomb matrix calculation. The current parallel quantum chemical tree code is able to deliver 63%-81% overall efficiency on 128 processors with fine grained parallelism (less than two heavy atoms per processor). 相似文献
23.
Patterned, amine-terminated monolayers can be fabricated from 4-nitrobenzenethiol (4-NBT) monolayers simply by irradiating under ambient conditions with visible laser after spreading Ag nanoparticles onto selected regions of the 4-NBT monolayers on Au. Au nanoparticles were adsorbed selectively onto the amine groups produced by photoreaction, and polyaniline was found to grow exclusively at the amine groups when electrochemical polymerization was conducted using the patterned substrate as the working electrode. These observations clearly support our previous contention that Ag nanoparticles can act as moderate photoelectron emitters. 相似文献
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Soo Yeon Kim Arup Podder Hyunseung Lee Youn-Joo Cho Eun Hee Han Sabina Khatun Jonathan L. Sessler Kwan Soo Hong Sankarprasad Bhuniya 《Chemical science》2020,11(36):9875
Abnormal anaerobic metabolism leads to a lowering of the pH of many tumours, both within specific intracellular organelles and in the surrounding extracellular regions. Information relating to pH-fluctuations in cells and tissues could aid in the identification of neoplastic lesions and in understanding the determinants of carcinogenesis. Here we report an amphiphilic fluorescent pH probe (CS-1) that, as a result of its temporal motion, provides pH-related information in cancer cell membranes and selected intracellular organelles without the need for specific tumour targeting. Time-dependent cell imaging studies reveal that CS-1 localizes within the cancer cell-membrane about 20 min post-incubation. This is followed by migration to the lysosomes at 30 min before being taken up in the mitochondria after about 60 min. Probe CS-1 can selectively label cancer cells and 3D cancer spheroids and be readily observed using the green fluorescence channel (λem = 532 nm). In contrast, CS-1 only labels normal cells marginally, with relatively low Pearson''s correlation coefficients being found when co-incubated with standard intracellular organelle probes. Both in vivo and ex vivo experiments provide support for the suggestion that CS-1 acts as a fluorescent label for the periphery of tumours, an effect ascribed to proton-induced aggregation. A much lower response is seen for muscle and liver. Based on the present results, we propose that sensors such as CS-1 may have a role to play in the clinical and pathological detection of tumour tissues or serve as guiding aids for surgery.A self-assembled amphiphilic fluorescent probe allows pH-fluctuations within cancer cells and tumour tissues to be readily detected. 相似文献
26.
Ionic liquid-coated enzyme for biocatalysis in organic solvent 总被引:8,自引:0,他引:8
Ionic liquid-coated enzyme (ILCE) is described as a useful catalyst for biocatalysis in organic solvent. An ionic liquid, [PPMIM]-[PF(6)] (1, [PPMIM] = 1-(3'-phenylpropyl)-3-methylimidazolium), which is solid at room temperature and becomes liquid above 53 degrees C, was synthesized in two steps from N-methylimidazole. The coating of enzyme was done by simply mixing commercially available enzyme with 1 in the liquid phase above 53 degrees C and then allowing the mixture to cool. A representative ILCE, prepared with a lipase from Pseudomonas cepacia, showed markedly enhanced enantioselectivity without losing any significant activity. 相似文献
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S. Barlag H. Becker A. Bożek T. Böhringer M. Bosman V. Castillo V. Chabaud C. Damerell C. Daum H. Dietl A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon D. P. Kelsey R. Klanner S. Kwan B. Lücking G. Lütjens G. Lutz J. Malos W. Männer E. Neugebauer H. Pałka M. Pepé J. Richardson K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers M. Witek T. Zeludziewicz 《Zeitschrift fur Physik C Particles and Fields》1992,55(3):383-390
We combine highly complementary information on branching fractions of charmed mesonsD 0,D + andD s + coming from two experiments both yielding doublecharm samples. The NA 32 experiment provided exclusive branching fractions for channels with at least two charged decay products while a recent Mark III paper provides results on inclusive charm decay properties. The knowledge of channels withK 0's in the former is used to recalculate the charged multiplicity distribution in the latter. We obtain 〈n ch〉=2.25±0.08 forD 0, 〈n ch〉=1.96±0.08 forD + and 〈n ch〉=2.41±0.38 forD s + . In turn the knowledge of the charged multiplicity improves the overall normalization of exclusive branching fractions. This reanalysis yields model-independent results for charmed mesons. In particular we obtain branching fractions for 16D s + decay channels including $$BF(D_s^ + \to \phi \pi ^ + ) = \left( {4.4\begin{array}{*{20}c} { + 2.3} \\ { - 1.8} \\ \end{array} } \right)\% .$$ . 相似文献
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S. Barlag H. Becker T. Böhringer M. Bosman V. Castillo V. Chabaud C. Damerell C. Daum H. Dietl A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon D. P. Kelsey R. Klanner S. Kwan B. Lücking G. Lütjens G. Lütz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers M. Witek T. Zeludziewicz 《Zeitschrift fur Physik C Particles and Fields》1991,49(4):555-562
We have studied the hadronic production of charmed mesons in the NA 32 experiment at CERN. A special trigger together with a high resolution vertex detector consisting of charge coupled devices and silicon microstrip detectors allowed the selection of very clean samples of charmed mesons. We have collected 852 fully reconstructed decays: 60D s + →K + K ?π+, 543D°→K ?π+ andK ?π+π?π+ as well as 249D +→K ?π+π+ (or charge conjugate). 147 mesons out of our \({{D^0 } \mathord{\left/ {\vphantom {{D^0 } {\bar D^0 }}} \right. \kern-0em} {\bar D^0 }}\) sample were produced via chargedD * state. For all charmed mesons we determine the total production cross-section and study thex F andp t 2 distributions. 相似文献
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