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31.
Ana Ruas Angelica Graa Joana Marto Lídia Gonalves Ana Oliveira Alexandra Nogueira da Silva Madalena Pimentel Artur Mendes Moura Ana Teresa Serra Ana Cristina Figueiredo Helena M. Ribeiro 《Molecules (Basel, Switzerland)》2022,27(11)
Essential oils (EOs) and hydrolates (Hds) are natural sources of biologically active ingredients with broad applications in the cosmetic industry. In this study, nationally produced (mainland Portugal and Azores archipelago) EOs (11) and Hds (7) obtained from forest logging and thinning of Eucalyptus globulus, Pinus pinaster, Pinus pinea and Cryptomeria japonica, were chemically evaluated, and their bioactivity and sensorial properties were assessed. EOs and Hd volatiles (HdVs) were analyzed by GC-FID and GC-MS. 1,8-Cineole was dominant in E. globulus EOs and HdVs, and α- and β-pinene in P. pinaster EOs. Limonene and α-pinene led in P. pinea and C. japonica EOs, respectively. P. pinaster and C. japonica HVs were dominated by α-terpineol and terpinen-4-ol, respectively. The antioxidant activity was determined by DPPH, ORAC and ROS. C. japonica EO showed the highest antioxidant activity, whereas one of the E. globulus EOs showed the lowest. Antimicrobial activity results revealed different levels of efficacy for Eucalyptus and Pinus EOs while C. japonica EO showed no antimicrobial activity against the selected strains. The perception and applicability of emulsions with 0.5% of EOs were evaluated through an in vivo sensory study. C. japonica emulsion, which has a fresh and earthy odour, was chosen as the most pleasant fragrance (60%), followed by P. pinea emulsion (53%). In summary, some of the studied EOs and Hds showed antioxidant and antimicrobial activities and they are possible candidates to address the consumers demand for more sustainable and responsibly sourced ingredients. 相似文献
32.
Valverde J. S. Pimentel B. M. Fainberg V. Ya. 《Theoretical and Mathematical Physics》2004,140(1):931-938
Using the functional integral formalism for the statistical generating functional in the statistical (finite temperature) quantum field theory, we prove the equivalence of many-photon Green's functions in the Duffin–Kemmer–Petiau and Klein–Gordon–Fock statistical quantum field theories. As an illustration, we calculate the one-loop polarization operators in both theories and demonstrate their coincidence. 相似文献
33.
Luis O. Pimentel 《General Relativity and Gravitation》1992,24(9):985-989
The Klein-Gordon equation is studied in a family of exact solutions of the Einstein equations whose material content is a perfect fluid with stiff equation of state (p=). The field equations are solved exactly for some members of the family and for massive or massless fields. 相似文献
34.
L.A. Manzoni B.M. Pimentel J.L. Tomazelli 《The European Physical Journal C - Particles and Fields》1999,8(2):353-361
We consider the (2+1)-dimensional massive Thirring model as a gauge theory, with one-fermion flavor, in the framework of
the causal perturbation theory and address the problem of dynamical mass generation for the gauge boson. In this context we
obtain an unambiguous expression for the coefficient of the induced Chern–Simons term.
Received: 5 October 1998 / Published online: 19 February 1999 相似文献
35.
36.
F.T. Dias V.N. Vieira M.L. de Almeida A.L. Falck P. Pureur J.L. Pimentel X. Obradors 《Physica C: Superconductivity and its Applications》2010
We report on systematic field-cooled magnetization experiments in an Y0.98Ca0.02Ba2Cu3O7?δ single crystal and melt-textured YBa2Cu3O7?δ samples. Magnetic fields up to 50 kOe were applied and a paramagnetic response related to the superconducting state was observed. We discuss our results in terms of the flux compression scenario into the sample. 相似文献
37.
Peter D. Wentzell Siyuan Hou Carolina Santos Silva Chelsi C. Wicks Maria Fernanda Pimentel 《Analytica chimica acta》2015
Projection pursuit (PP) is an effective exploratory data analysis tool because it optimizes the projection of high dimensional data using distributional characteristics rather than variance or distance metrics. The recent development of fast and simple PP algorithms based on minimization of kurtosis for clustering data has made this powerful tool more accessible, but under conditions where the sample-to-variable ratio is small, PP fails due to opportunistic overfitting of random correlations to limiting distributional targets. Therefore, some kind of variable compression or data regularization is required in these cases. However, this introduces an additional parameter whose optimization is manually time consuming and subject to bias. The present work describes the use of Procrustes analysis as diagnostic tool that can be used to evaluate the results of PP analysis in an efficient manner. Through Procrustes rotation, the similarity of different PP projections can be examined in an automated fashion with “Procrustes maps” to establish regions of stable projections as a function of the parameter to be optimized. The application of this diagnostic is demonstrated using principal components analysis to compress FTIR spectra from ink samples of ten different brands of pen, and also in conjunction with regularized PP for soybean disease classification. 相似文献
38.
Ferreira VF Jorqueira A Leal KZ Pimentel HR Seidl PR da Silva MN da Souza MC Pinto AV Wardell JL Wardell SM 《Magnetic resonance in chemistry : MRC》2006,44(4):481-490
The assignment of the diazo site in products of the reaction of p-toluenesulfonylhydrazine with beta-lapachone, 3,4-dihydro-2,2-dimethyl-2H-naphtho[1,2-b]pyran-5,6-dione, and other 1,2-naphthoquinones in methanol solution at room temperature has been accomplished using 1H,13C HMBC and 1H,15N HMBC NMR experiments. Only one diazo-naphthalenone product was isolated in yields ranging from 50-100% from each reaction. The site of diazo substitution of beta-lapachone and derivatives is the 1-position, in contrast to substitution at the 2-position in 4-MeO-1,2-naphthoquinone. Steric factors, rather than electronic factors, control the reaction site. Along with 2-diazo-1(2H)-naphthalenone, an additional product isolated from the reaction of p-toluenesulfonylhydrazide with 1,2-naphthoquinone was 2-diazo-4-hydroxy-1(2H)-naphthalenone. Confirmation of the formation of 6-diazo-2,2-dimethyl-2,3,4,6-tetrahydro-2H-benzo[h]cromen-5-one, obtained from beta-lapachone, was achieved using single crystal X-ray diffraction. 相似文献
39.
Liliana Fátima Bezerra de Lira Jose Geraldo Andrade Pacheco Eduardo Homem de Siqueira Cavalcanti Maria Fernanda Pimentel 《Microchemical Journal》2010,96(1):126-34
This paper evaluates analytical methods based on near infrared (NIR) and middle infrared (MIR) spectroscopy and multivariate calibration to monitor the stability of biodiesel. There was a focus on three parameters: oxidative stability index, acid number and water content. Ethylic and methylic biodiesel from different feedstocks were used in experiments of accelerated aging, in order to take into account the wide variety of oilseeds and feedstocks available in Brazil. Partial least squares (PLS) and multiple linear regression (MLR) models were developed. Different pre-processing techniques and spectral variable/regions selection algorithms were evaluated. For MLR models, the successive projection algorithm (SPA) was employed. Interval PLS (iPLS) and selection of variables taking into account the significant regression coefficients were used for PLS models. Results showed that both near and middle infrared regions, and all variable selection methods tested were efficient for predicting these three important quality parameters of B100, the root mean squares error of prediction (RMSEP) values being comparable to the reproducibility of the corresponding standard method for each property investigated. 相似文献
40.
Hidalgo AA Pimentel AS Tabak M Oliveira ON 《The journal of physical chemistry. B》2006,110(39):19637-19646
An investigation has been made of the interaction between chlorpromazine (CPZ) and monolayers of 1,2-dipalmitoyl-sn-3-glycerophosphatidylcholine (DPPC) and 1,2-dipalmitoyl-sn-3-glycero[phospho-rac-(1-glycerol)] (DPPG), both at the air/water interface and in transferred Langmuir-Blodgett films. The Gibbs free energy, DeltaG, and the compressibility modulus (C(S)(-1)), obtained from the surface pressure isotherms, indicated changes in the in-plane interactions of CPZ/DPPG mixed monolayers, with positive values of DeltaG. The arrangement of CPZ in the zwitterionic DPPC monolayers causes a weaker interaction in CPZ/DPPC mixed monolayers, with the DeltaG fluctuating around zero. IR measurements in transferred monolayers showed that CPZ did not affect the conformational order of the acyl chains, its effects being limited to the bands corresponding to the headgroups. Furthermore, since no shift was observed for the acyl chain bands, the phase transition induced by CPZ is not a liquid expanded (LE) to liquid condensed (LC) transition, as the latter is associated with chain ordering. Taken together, the IR and compressibility results demonstrate that the effect from CPZ cannot be correlated with temperature changes in the subphase for pure monolayers, in contrast to models proposed by other authors. 相似文献