9位芳香基取代超支化聚芴的合成与表征

以2,7-二溴芴酮为起始原料,在芴的9位引入芳香取代基代替传统的烷基取代基,增加9位的稳定性,并用AB+AB2的方法,用新单体合成了不同支化度的超支化聚合物,新合成的超支化聚合物具有良好的热稳定性和发光稳定性.聚合物的热分解温度都在400℃以上;聚合物的薄膜在空气中于200℃加热2 h后没有出现绿光发射带,发光稳定性和烷基聚芴相比得到明显的提高.DSC结果显示,线性聚合物在170℃时有玻璃化转变,超支化聚合物在300℃以内没有明显的相转变,保持一种稳定的无定形态,更有利于提高材料的发光效率.     

微视频在无机化学实验教学中的应用

To improve the students' autonomous learning ability and learning enthusiasm in practice course,we introduce micro video,which is short,fast,precise,easy,and fun,into inorganic chemistry laboratory teaching.As an important supplementary means of teaching,micro videos will solve the repeated problems,help students promote study efficiency,provide students with a good way for communication,and improve the students' study enthusiasm.     

On the m order difference sequence space of generalized weighted mean and compact operators

In this article, using generalized weighted mean and difference matrix of order m, we introduce the paranormed sequence space ?(u, v, p; Δ^(m)), which consist of the sequences whose generalized weighted Δ^(m)-difference means are in the linear space ?(p) defined by I.J. Maddox. Also, we determine the basis of this space and compute its α-, β- and γ-duals. Further, we give the characterization of the classes of matrix mappings from ?(u, v, p, Δ^(m)) to ?_∞, c and c₀. Finally, we apply the Hausdorff measure of noncompacness to characterize some classes of compact operators given by matrices on the space ?_p(u, v, Δ^(m))(1 ≤ p < ∞).     

The first and second Zagreb indices of some graph operations

In this paper some exact expressions for the first and second Zagreb indices of graph operations containing the Cartesian product, composition, join, disjunction and symmetric difference of graphs will be presented. We apply some of our results to compute the Zagreb indices of arbitrary C₄ tube, C₄ torus and q-multi-walled polyhex nanotorus.     

Structure and magnetism of the V/Ta(0 0 1) surface: A DFT calculation

Calculations using the density functional theory, norm-conserving pseudopotentials and the generalized gradient approximation are performed for vanadium (V) and tantalum (Ta) clean surfaces, and the V/Ta(0 0 1) system. Vanadium and Ta(0 0 1) clean surfaces are found to be nonmagnetic with large inward relaxations of 9.81% and 11.19%, respectively, in good agreement with experiment and other calculations. However, we obtained an appreciable magnetic moment of 2.24 μB for the V monolayer in the V/Ta(0 0 1) system. The inward relaxation is reduced to 6.01% for the V overlayer on Ta(0 0 1) as a result of its spin polarization. An induced magnetic moment of 0.41 μB is obtained on the Ta interfacial layer, which is found to be anti-ferromagnetically coupled with the V overlayer and the Ta layers below.     

不用固定规范的微扰论

本文建议从趋向平衡的Langevin方程出发,建立量子场论的微扰展开.文中证明了这种表述可用于规范理论,无需固定规范就能正确算出规范不变的量.文中还给出了简单例子的计算细节,并讨论了Langevin方程的微扰解趋向平衡的速率.     

Bound states of schrödinger equations with electromagnetic fields and vanishing potentials

We study the bound states to nonlinear Schrödinger equations with electro-magnetic fields $\text{i}h\frac{?\psi }{?t}={(\frac{h}{i}?-A(x))}^2\psi +V(x)\psi -K(x){|}^{p-1}\psi =0,\text{on}{?}_{+}\times {?}^N$. Let $G(x)={[V(x)]}^{\frac{p+1}{p-1}-\frac{N}{2}}{[K(x)]}^{-\frac{2}{p-1}}$ and suppose that G(x) has k local minimum points. For h > 0 small, we find multi-bump bound states ψh(x,t) = _e^?lEt/^h_Uh(χ) with Uh concentrating at the local minimum points of G(x) simultaneously as h → 0. The potentials V(x) and K(x) are allowed to be either compactly supported or unbounded at infinity.     

硅晶体中单个位错的运动

本文利用化学浸蚀方法,在400—900℃的温度范围内,在0.35—13kg·mm^{-2的应力条件下,测量了硅晶体中单个位错的运动速度。实验结果表明,位错运动速度V(τ,T)作为温度(T)和分解切应力(τ)的函数,满足如下方程:V(τ,T)=Aτme-Q/(KT)。式中m=1.02—1.49,Q=1.96—2.07eV。最后,把实验结果与扩展位错的弯结模型作了比较。 关键词：}     

质子交换膜燃料电池动态特性数值分析

本文基于CFD手段计算分析了质子交换膜燃料电池在启动过程、负载突变两种工况下的动态响应特性,与实验结果进行了对比,分析了其影响因素.分析了燃料电池动态工况下膜内含水量、极板电流和阴极扩散层水饱和度三个参数在负载变化时的响应速度,认为膜内含水量、极板电流在2s左右即可达到平衡,而阴极扩散层水饱和度需较长时间才能达到平衡.     

聚乙二醇-b-聚对苯二甲酸丁二醇酯嵌段共聚物降解行为的研究

研究了系列PEG-b-PBT嵌段共聚物在pH=7.4磷酸盐缓冲溶液中和37℃条件下的体外降解行为.同时观察了水解降解过程中系列共聚物溶胀率、失重、特性粘度、结晶度和表面形态等方面的变化.实验结果表明,嵌段共聚物的组成直接影响其水解降解性能,共聚物的溶胀率和失重率随聚醚组分含量而增大;通过调节共聚物的组分比可以达到调节降解速率的目的.此外研究还表明,共聚物最初的降解主要发生在软段和硬段相联的酯键上.