首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   559344篇
  免费   6202篇
  国内免费   1702篇
化学   298454篇
晶体学   8571篇
力学   24345篇
综合类   16篇
数学   66836篇
物理学   169026篇
  2021年   4667篇
  2020年   5227篇
  2019年   5667篇
  2018年   7199篇
  2017年   7172篇
  2016年   11099篇
  2015年   7028篇
  2014年   10813篇
  2013年   25898篇
  2012年   19871篇
  2011年   24257篇
  2010年   17194篇
  2009年   16915篇
  2008年   22353篇
  2007年   22072篇
  2006年   20623篇
  2005年   18463篇
  2004年   17076篇
  2003年   15132篇
  2002年   14844篇
  2001年   16752篇
  2000年   12677篇
  1999年   9912篇
  1998年   8255篇
  1997年   7995篇
  1996年   7734篇
  1995年   6995篇
  1994年   6892篇
  1993年   6611篇
  1992年   7445篇
  1991年   7420篇
  1990年   7199篇
  1989年   6952篇
  1988年   6951篇
  1987年   6855篇
  1986年   6438篇
  1985年   8446篇
  1984年   8603篇
  1983年   7107篇
  1982年   7206篇
  1981年   7059篇
  1980年   6633篇
  1979年   7179篇
  1978年   7323篇
  1977年   7156篇
  1976年   7103篇
  1975年   6682篇
  1974年   6633篇
  1973年   6805篇
  1972年   4717篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
141.
Crystalline materials that are transparent in the vacuum UV spectral region and currently used have been reviewed. Transmission of crystals of solid solutions with the fluorite structure Ca1?x R xF2+x (R = Sc, Y, La, Yb, Lu) in the UV and vacuum UV spectral regions has been investigated. It is shown that application of different methods of purification of fluorides from some impurities can significantly improve the optical quality of fluoride multicomponent crystals in the short-wavelength spectral region.  相似文献   
142.
An adaptive hierarchical grid‐based method for predicting complex free surface flows is used to simulate collapse of a water column. Adapting quadtree grids are combined with a high‐resolution interface‐capturing approach and pressure‐based coupling of the Navier–Stokes equations. The Navier–Stokes flow solution scheme is verified for simulation of flow in a lid‐driven cavity at Re=1000. Two approaches to the coupling of the Navier–Stokes equations are investigated as are alternative face velocity and hanging node interpolations. Collapse of a water column as well as collapse of a water column and its subsequent interaction with an obstacle are simulated. The calculations are made on uniform and adapting quadtree grids, and the accuracy of the quadtree calculations is shown to be the same as those made on the equivalent uniform grids. Results are in excellent agreement with experimental and other numerical data. A sharp interface is maintained at the free surface. The new adapting quadtree‐based method achieves a considerable saving in the size of the computational grid and CPU time in comparison with calculations made on equivalent uniform grids. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
143.

A method for calculating the parameters of formation of vacancies in crystals formed by spherically symmetrical atoms was developed. Both quantum effects at low temperatures and the possibility of the delocalization of atoms at high temperatures were studied. The parameters of formation of vacancies in carbon subgroup element crystals C-diam, Si, Ge, α-Sn, and Pb were calculated. The inclusion of the delocalization of atoms was shown to increase the enthalpy, entropy, and volume of vacancy formation. At low temperatures, the parameters of vacancy formation were found to depend strongly on the temperature, and the entropy of vacancy formation became negative. At high temperatures, close agreement with experimental data and theoretical estimates reported by other authors was obtained. The temperature dependence of vacancy parameters was studied for diamond heated isobarically from 100 to 4500 K. The applicability scope of the Arrhenius equation with a temperature-independent activation energy is discussed. The validity of the “compensation rule” (correlation between the entropy and enthalpy of vacancy formation) was demonstrated. It was also shown that the volume and entropy of vacancy formation were correlated over the whole temperature range studied.

  相似文献   
144.
In this paper we obtain a number of Maharam-type slice integral representations, with respect to scalar measures, for positive projections in Dedekind complete vector lattices and f-algebras. AMS Classification: 47B65, 46A40, 06F25  相似文献   
145.
It is well known that F. G. Tricomi (1923) is the originator of the theoryof boundary value problems for mixed type equations by establishing the Thicomi equation: y·uxx+uyy=0 which is hyperbolic for y < 0, elliptic for y=0. and parabolic for y= 0 and then applied it in the theory of transonic flows.Then A.V.Bitsadze together with M. A . Lavrent′ev (1950) established the Bitsadze Lavre nt′ev equation: sgn( y ) ·uxx+uyy=0 where sgn(y) = 1 for y > 0, = -1 for y<0, 0 for y=0 with the discontinuous coefficient sgn( y ) of uxx, while in the case of Tricomi equation the corre sponding coefficient y is continuous. In this paper we establish the mixed Bitsadze Lavrent′ev Tricomi equation. Lu=K(y)·uxx+sgn(x) ·uyy+r(x,y)·u=f(x,y), where the coefficient K=K(y) of uxx is increasing continuous and coefficient M=sgn(x) of uyy discontinuous, r=r(x,y) is once continuously differentiable, f=f(x,y) continuous. Finally we prove the uniqueness of quasi regular solutions and observe that these new results can bbe applied in fluid dynamics.  相似文献   
146.
147.
Calculations are performed, using a basis of two-center functions described previously, for excited states of the following three-and four-electron compounds: H2 , He2 +, He2, Li2 +2. High efficiency is demonstrated for the frozen ionic core approximation and the nonorthogonal orbital method in such calculations. For four-electron systems the practical feasibility of the frozen hybrid core approximation is demonstrated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 53–56, August, 1987.  相似文献   
148.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
149.
The stress-strain state in the zone of load transfer in a uniaxially stretched specimen made of a unidirectional epoxy carbon-fiber-reinforced plastic (CFRP) is investigated. A parametric analysis of the influence of geometric and mechanical characteristics of the specimen on its stress-strain state is performed by means of finite-element modeling. The parameters allowing us to significantly reduce the dangerous concentration of transverse and tangential stresses are revealed. The mechanical tensile characteristics of a high-strength pultruded unidirectional CFRP are determined experimentally, and the size effect of its strength is estimated.  相似文献   
150.
In the present paper it is shown that if S1 and S2 are two Clifford topological semigroups satisfying certain conditions and T is an isometric isomorphism of LUC(S1*) onto LUC(S2*), then T maps S1 topologically isomorphically onto S2. Furthermore, T maps M l n(S1) (M(S1), respectively) isometrically isomorphically onto M l n(S2) (M(S2), respectively). Indeed, we have obtained a generalization of a well-known result of Ghahramani, Lau and Losert for locally compact groups to a more general setting of Clifford topological semigroups.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号