Dehydrogenation of propane on aluminoplatinum catalysts modified with Re,Zr, Sc,and Sn

The effect of addition of Re, Zr, Sc, and Sn on an aluminoplatinum catalyst in the reaction of dehydrogenation of propane was investigated. It was shown that addition of 0.2–0.5% Zr, Sc, or Re virtually does not alter the catalytic properties of the aluminoplatinum catalyst (APC); addition of 0.2% Sn increases the activity, selectivity, and stability of Pt/Al₂O₃. The amount of coke deposited on the APC after the first 5 min of work decreases by three times in the presence of Sn. The coke is more enriched with hydrogen than the other systems formed on the surface of Pt-Sn/Al₂O₃.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 765–771, April, 1991.     

Graphs whose every transitive orientation contains almost every relation

Given a graphG onn vertices and a total ordering ≺ ofV(G), the transitive orientation ofG associated with ≺, denotedP(G; ≺), is the partial order onV(G) defined by settingx<y inP(G; ≺) if there is a pathx=x ₁ x ₂…x _r=y inG such thatx ₁ ≺x _j for 1≦i<j≦r. We investigate graphsG such that every transitive orientation ofG contains ₂ ⁿ −o(n ²) relations. We prove that almost everyG _n,p satisfies this requirement if , but almost noG _n,p satisfies the condition if (pn log log logn)/(logn log logn) is bounded. We also show that every graphG withn vertices and at mostcn logn edges has some transitive orientation with fewer than ₂ ⁿ −δ(c)n ² relations. Partially supported by MCS Grant 8104854.     

Beryllium diffusion across GaAs/(Al,Ga)As heterojunctions and GaAs/AlAs superlattices during MBE growth

Beryllium diffusion during MBE growth of (Al, Ga)As layers, (Al, Ga)As/GaAs heterojunctions and GaAs/AlAs superlattices has been studied by electrochemical C-V and secondary ion mass spectrometry (SIMS) concentration profiling, in conjunction with transmission electron microscopy. Diffusion times were comparatively short since they were limited to part of the growth sequence, so non-equilibrium effects had a significant influence. The results are consistent with an interstitial-substitutional mechanism in which lattice site incorporation becomes more difficult with increasing band gap enthalpy. Incorporation involves a kick-out reaction which leads to the observed disordering of the superlattices.     

Stop times in fock space stochastic calculus

Summary A stop time S in the boson Fock space over L ₂()₊ is a spectral measure in [0,] such that {S([0,t])} is an adapted process. Following the ideas of Hudson [6], to each stop time S a canonical shift operator U ^Sis constructed in . When S({}) has the vacuum as a null vector U ^Sbecomes an isometry. When S({})=0 it is shown that admits a factorisation _S]{S where _{S is the range of U ^Sand _S] is a suitable subspace of called the Fock space upto time S. This, in particular, implies the strong Markov property of quantum Brownian motion in the boson as well as fermion sense and the Dynkin-Hunt property that the classical Brownian motion begins afresh at each stop time. The stopped Weyl and fermion processes are defined and their properties studied. A composition operation is introduced in the space of stop time to make it a semigroup. Stop time integrals are introduced and their properties constitute the basic tools for the subject.     

Approximation by Nörlund means of double fourier series to continuous functions in two variables

We study the rate of uniform approximation by Nörlund means of the rectangular partial sums of double Fourier series of continuous functionsf(x, y), 2π-periodic in each variable. The results are given in terms of the modulus of symmetric smoothness defined by $$\begin{gathered} \omega _2 \left( {f,\delta _1 ,\delta _2 } \right) = \mathop {\sup }\limits_{x,y} \mathop {\sup }\limits_{\left| u \right| \leqslant \delta _1 ,\left| v \right| \leqslant \delta _2 } \left| {f\left( {x + u,y + v} \right)} \right. + f\left( {x + u,y - v} \right) + f\left( {x - u,y + v} \right) \hfill \\ + \left. {f\left( {x - u,y - v} \right) + 4f\left( {x,y} \right)} \right| for \delta _1 ,\delta _2 \geqslant 0. \hfill \\ \end{gathered} $$ As a special case we obtain the rate of uniform approximation to functionsf(x,y) in Lip({α, β}), the Lipschitz class, and inZ({α, β}), the Zygmund class of ordersα andβ, 0<α,β ≤ l, as well as the rate of uniform approximation to the conjugate functions \(\tilde f^{(1,0)} (x,y), \tilde f^{(0,1)} (x,y)\) and \(\tilde f^{(1,1)} (x,y)\) .     

Some inequalities for partial orders

We establish some inequalities connecting natural parameters of a partial order P. For example, if every interval [a,b] contains at most maximal chains, if some antichain has cardinality v, and if there are ₁ chains whose union is cofinal and coinitial in P, then the chain decomposition number for P is ₁v (Theorem 2.2), and the inequality is sharp in a certain sense (Section 3).This paper was written while the authors were visitors at the Laboratoire d'algèbre ordinale, Département de Mathématiques, Université Claude Bernard, Lyon 1, France.Research supported by NSERC grant # A5198.     

A lower bound for the optimal crossing-free Hamiltonian cycle problem

Consider a drawing in the plane ofK _n , the complete graph onn vertices. If all edges are restricted to be straight line segments, the drawing is called rectilinear. Consider a Hamiltonian cycle in a drawing ofK _n . If no pair of the edges of the cycle cross, it is called a crossing-free Hamiltonian cycle (cfhc). Let (n) represent the maximum number of cfhc's of any drawing ofK _n , and (n) the maximum number of cfhc's of any rectilinear drawing ofK _n . The problem of determining (n) and (n), and determining which drawings have this many cfhc's, is known as the optimal cfhc problem. We present a brief survey of recent work on this problem, and then, employing a recursive counting argument based on computer enumeration, we establish a substantially improved lower bound for (n) and (n). In particular, it is shown that (n) is at leastk × 3.2684 ⁿ . We conjecture that both (n) and (n) are at mostc × 4.5 ⁿ .This research, part of which was conducted at Queen's University, was supported by an N.S.E.R.C. postgraduate scholarship.     

Lipschitz functions of self-adjoint operators in perturbation theory

Let A be a self-adjoint operator in a Hubert space. In order that for each differentiable function f and for each self-adjoint operator B one should have the estimate f(B)–f(A) c_f B–A it is necessary and sufficient that the spectrum. of the operator A be a finite set. If m is the number of points of the spectrum of the operator A, then for the constant cf one can take 8(log₂m+2)² [f], where [f] is the Lipschitz constant of the function f.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im. V. A. Steklova AN SSSR, Vol. 141, pp. 176–182, 1985.     

Estimation of density functions by order statistics

The properties of the empirical density function,f _n(x) = k/n( _j ⁺ – _j-1 ⁺ ) if _j-1 ⁺ < x ⁺ where _j-1 ⁺ and _j ⁺ are sample elements and there are exactlyk – 1 sample elements between them, are studied in that practical point of view how to choose a suitablek for a good estimation. A bound is given for the expected value of the absolute value of difference between the empirical and theoretical density functions.