全文获取类型
收费全文 | 391410篇 |
免费 | 4292篇 |
国内免费 | 1332篇 |
专业分类
化学 | 204951篇 |
晶体学 | 6220篇 |
力学 | 16965篇 |
综合类 | 5篇 |
数学 | 47192篇 |
物理学 | 121701篇 |
出版年
2020年 | 2945篇 |
2019年 | 3332篇 |
2018年 | 4944篇 |
2017年 | 5013篇 |
2016年 | 6846篇 |
2015年 | 4393篇 |
2014年 | 6611篇 |
2013年 | 17690篇 |
2012年 | 13393篇 |
2011年 | 15951篇 |
2010年 | 10898篇 |
2009年 | 10919篇 |
2008年 | 14289篇 |
2007年 | 14231篇 |
2006年 | 13341篇 |
2005年 | 14614篇 |
2004年 | 13428篇 |
2003年 | 11160篇 |
2002年 | 9768篇 |
2001年 | 11220篇 |
2000年 | 8426篇 |
1999年 | 6611篇 |
1998年 | 5540篇 |
1997年 | 5456篇 |
1996年 | 5141篇 |
1995年 | 4819篇 |
1994年 | 4626篇 |
1993年 | 4664篇 |
1992年 | 5165篇 |
1991年 | 5121篇 |
1990年 | 4878篇 |
1989年 | 4807篇 |
1988年 | 4861篇 |
1987年 | 4716篇 |
1986年 | 4519篇 |
1985年 | 6110篇 |
1984年 | 6292篇 |
1983年 | 5315篇 |
1982年 | 5725篇 |
1981年 | 5463篇 |
1980年 | 5345篇 |
1979年 | 5502篇 |
1978年 | 5767篇 |
1977年 | 5580篇 |
1976年 | 5785篇 |
1975年 | 5291篇 |
1974年 | 5422篇 |
1973年 | 5859篇 |
1972年 | 3705篇 |
1971年 | 2953篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
191.
A converging perturbation series that can be summed analytically has been obtained for intersubband transitions of electrons
coherently tunneling through the middle of a dimensionally quantized level in an asymmetric double-barrier structure in a
high-frequency terahertz electric field. The possibility of a substantial increase in tunneling current accompanied by either
absorption or emission of a photon has been demonstrated. The quantum efficiency of radiative transitions between dimensionally
quantized levels can be up to 66%.
Zh. éksp. Teor. Fiz. 112, 237–245 (July 1997) 相似文献
192.
The effect of iodine sorption on the free volume of polycarbonate is investigated by Positron Annihilation Lifetime method.
The observed results are interpreted in terms of the Charge Transfer Complex formation and precipitation of iodine at the
initial and final stages of sorption, respectively. At higher levels of sorption, changes in the second lifetime and its intensity
seem to suggest a conformational transformation, probably due to the net change in the amorphous-crystalline boundary regions
of the polymer matrix. The free volume cavities have been predominantly occupied by I-
3 species and the diffusion process obeys Fick’s law. An exponential type correlation has been observed between fractional
free volume and the diffusion coefficient.
Received: 13 June 1996/Accepted: 20 September 1996 相似文献
193.
We provide a characterization of the limit periodic sets for analytic families of vector fields under the hypothesis that the first jet is non-vanishing at any singular point. Also, applying the family desingularization method, we reduce the complexity of some of these sets. 相似文献
194.
Daniel L. Feldheim Del R. Lawson Charles R. Martin 《Journal of Polymer Science.Polymer Physics》1993,31(8):953-957
We report a strong dependence of the thermal stability of Nafion® perfluorosulfonate ionomer on the nature of the counterion associated with the fixed sulfonate site. These results were obtained using thermal gravimetric analysis on a series of alkali metal and alkyl ammonium cation-exchanged Nafion films. We have found that the temperature of decomposition of Nafion is inversely dependent on the size of the exchanged cation; i.e., Nafion films show improved thermal stability as the size of the counter cation decreases. We attribute this inverse relationship of thermal stability with counterion size to an initial decomposition reaction which is strongly influenced by the strength of the sulfonate-coun-terion interaction. © 1993 John Wiley & Sons, Inc. 相似文献
195.
A simple method is proposed for increasing the accuracy of computation of the eigenvalues of elliptic operators, which does not require high-order accurate schemes.Translated from Vychislitel'naya i Prikladnaya Matematika, No. 63, pp. 63–68, 1987. 相似文献
196.
V. M. Shopa B. N. Polevoi I. I. Popadyuk V. I. Tusevich 《Journal of Mathematical Sciences》1993,63(3):398-401
We propose a method of determining the contact pressures between the shells in a packet under the influence of nonlinear internal and constant external pressure. Using the equations of the general moment theory of shells we determine the stress-deformed state of a packet of finite cylindrical shells taking account of frictional forces on the contacting surfaces. One table. Bibliography: 10 titles.Translated fromMatematicheskie Metody i Fiziko-Mekhanicheskie Polya, Issue 30, 1989, pp. 94–98. 相似文献
197.
V. A. Samsonov L. B. Volodarskii V. L. Korolev G. Kh. Khisamutdinov 《Chemistry of Heterocyclic Compounds》1994,30(10):1243-1249
The reaction of 4-aminobenzofurazan with aryldiazonium salts leads to the formation of 4-amino-5-aryl-azobenzofurazans and 5-amino-2-aryl-4-nitroso-2H-benzotriazoles, products of the rearrangement of the initially formed 4-amino-7-(arylazo)benzofurazans. Oxidation of the benzofurazan as well as of the triazole derivatives gives 7-aryl-1,2,3-triazol[4,5-e]benzofurazans. The chemical properties of some of the compounds obtained have been investigated.Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1432–1438, October, 1994. Original article submitted July 25, 1994. 相似文献
198.
The reaction of 2-(2 pyridytcarbonyl)benzoic acid with thionyl chloride affords an unexpected product of the intramolecular acylation of the pyridine nitrogen atom, namely, 6,11-dioxo-6,11-dihydrobenzo[blquinotizinium chloride. At the same time, 2-(2-quinotylcarbonyl)benzoic acid forms the expected cyclic acid chloride, namely, 3-(2-gitinotyl)-3-chlorophthalide in this reaction. Both compounds acylate ammonia and primary amines, including those with bulky alkyl groups (tert-butyl, 1-adamantyl, and 1,1,3,3-tetramethylbutyl) with the formation of 2-R-3-hydroxy-3-(2pyridyl- or 2-quinolyl)isoindolines. The protonation of the pyridine nitrogen atom of N-(1,1,3,3-tetramethylbutyl)-2-(2pyridylcarbonyl)benzamide, obtained in the open amide form, is accompanied by the closing of the isoindotinone ring; the deprotonation is accompanied by ring opening.Riga Technical University, Riga LV-1048. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 499–504, April, 1994. Original article submitted March 17, 1994. 相似文献
199.
M. A. Mikhaleva B. M. Bolotin T. A. Kizner E. S. Serebrykova 《Chemistry of Heterocyclic Compounds》1994,30(1):79-81
We have synthesized 5-alkyl(alkoxy)-2-(o-lzydroxy-p-alkoxyphenyl)pyrimidines and considered the effect of the OH group on the inesomorphism. We have found that in binuclear o-hydroxyarylpyrimidines, an ortho OH group forming an intramolecular hydrogen bond increases Tmp, inhibits the appearance of nematic properties, and promotes the appearance of a smectic A.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 1, pp. 90–92, January, 1994. 相似文献
200.
G. N. Dalimova Kh. A. Abduazimov R. K. Rakhmanberdieva V. G. Gorokhova L. N. Petrushenko B. A. Babkin N. A. Koshilev 《Chemistry of Natural Compounds》1994,30(3):400-403
On the basis of the results of acid hydrolysis, chromatographic analysis of the hydrolysates, and a study of IR spectra, it has been established that the suspended particles liberated under the action of electrohydraulic shocks on heterodisperse water—plant systems consist of small fragments of the lignocarbohydrate complex of the plant tissue. 相似文献