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Azadeh Kiani Ali Ghaffarinejad Seyed Abolfazl Seyedsadjadi Atiyeh Mansouri 《Electroanalysis》2020,32(2):281-290
In this study, an available and inexpensive graphite substrate, was easily modified with Ni/Cr nanoparticles via electrodeposition technique in a very short time (3 min) and used as an electrocatalyst for glucose oxidation in alkaline solution. Graphite electrode modified with Ni/Cr nanoparticles demonstrated an outstanding electrocatalytic performance to glucose oxidation in comparison to examined Ni‐based electrodes or even different materials in other reports. It is noteworthy to mention that adding a little Cr led to a synergistic effect with Ni; accordingly, the presence of Cr not only resulted in a greater adsorption of glucose molecules by chromium oxide but also boosted conductivity of the nickel oxide because of the enhancement of Ni(III) amount. The electrochemical studies were performed by cyclic voltammetry and electrochemical impedance spectroscopy (EIS). The morphology and structure of catalyst layer was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD) and energy dispersive x‐ray spectroscopy (EDS). The linear range of the electrode by cyclic voltammetry was between 2–31 mM with a high sensitivity of 2094 μA cm?2 mM?1. The repeatability and reproducibility of the proposed electrode was examined in glucose solution which were 0.3 % and 4.7 %, respectively. According to the low cost, ease and fast preparation, good repeatability and high sensitivity, this electrode can be a good candidate for nonenzymatic glucose oxidation. 相似文献
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Activation of a Photodissociative Ruthenium Complex by Triplet–Triplet Annihilation Upconversion in Liposomes
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Sven H. C. Askes Azadeh Bahreman Dr. Sylvestre Bonnet 《Angewandte Chemie (International ed. in English)》2014,53(4):1029-1033
Liposomes capable of generating photons of blue light in situ by triplet–triplet annihilation upconversion of either green or red light, were prepared. The red‐to‐blue upconverting liposomes were capable of triggering the photodissociation of ruthenium polypyridyl complexes from PEGylated liposomes using a clinical grade photodynamic therapy laser source (630 nm). 相似文献
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This study presents the vortex structure and numerical instability increase occurring when the level of elasticity is enhanced in inertial flows in planar contraction configuration for finitely extensible nonlinear elastic model by Peterlin (FENE‐P) fluid 1 . The re‐entrant corner effect on corner vortices is also considered. The calculations are performed using extended matrix logarithm formulation described in a previous paper: A. Jafari et al. A new extended matrix logarithm formulation for the simulation of viscoelastic fluids by spectral elements. Computer & Fluids 2010; 39 (9):1425–1438. In that reference, the proposed algorithm has been tested for simple geometry such as Poiseuille flow. In this study, we are interested in the capability of this algorithm for more complex geometry. This formulation helps to reach higher values of the Weissenberg number when compared with the classical one. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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This paper presents an adaptive network based fuzzy inference system (ANFIS)–auto regression (AR)–analysis of variance (ANOVA) algorithm to improve oil consumption estimation and policy making. ANFIS algorithm is developed by different data preprocessing methods and the efficiency of ANFIS is examined against auto regression (AR) in Canada, United Kingdom and South Korea. For this purpose, mean absolute percentage error (MAPE) is used to show the efficiency of ANFIS. The algorithm for calculating ANFIS performance is based on its closed and open simulation abilities. Moreover, it is concluded that ANFIS provides better results than AR in Canada, United Kingdom and South Korea. This is unlike previous expectations that auto regression always provides better estimation for oil consumption estimation. In addition, ANOVA is used to identify policy making strategies with respect to oil consumption. This is the first study that introduces an integrated ANFIS–AR–ANOVA algorithm with preprocessing and post processing modules for improvement of oil consumption estimation in industrialized countries. 相似文献
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A. Azadeh M. MoghaddamS.M. Asadzadeh A. Negahban 《European Journal of Operational Research》2011,214(3):768-779
This paper puts forward an integrated fuzzy simulation-fuzzy data envelopment analysis (FSFDEA) algorithm to cope with a special case of single-row facility layout problem (SRFLP). Discrete-event-simulation, a powerful tool for analyzing complex and stochastic systems, is employed for modeling different layout formations. Afterwards, a range-adjusted measure (RAM) is used as a data envelopment analysis (DEA) model for ranking the simulation results and finding the optimal layout design. Due to ambiguousness associated with the processing times, fuzzy sets theory is incorporated into the simulation model. Since the results of simulation are in the form of possibility distributions, the DEA model is treated on a fuzzy basis; therefore, a recent possibilistic programming approach is used to convert the fuzzy DEA model to an equivalent crisp one. The proposed FSFDEA algorithm is capable of modeling and optimizing small-sized SRFLP’s in stochastic, uncertain, and non-linear environments. The solution quality is inspected through a real case study in a refrigerator manufacturing company. 相似文献
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The one‐pot multicomponent reaction of alkyl isocyanide, alkylidene‐substituted Meldrum's acid, and arylcarboxylic acids affords new derivatives of iminofuranone in fair yields. The structure of the products was deduced from their spectroscopic data. Two equivalents of the respective isocyanides participate in this reaction. 相似文献
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The purpose of this paper is to develop a fast and sensitive spectrophotometric method for the simultaneous determination of zinc(II), manganese(II) and iron(II) in pharmaceutical preparations. The method presented in this work is based on the well-known reaction of these ions with 4-(pyridylazo)resorcinol (PAR)1. The application of quantitative chemometric methods, particularly PLS to multivariate chemical data is becoming more widespread owing to the availability of digitized spectroscop… 相似文献
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Summary. An efficient procedure was developed for the preparation of selenoformates by means of an one-pot zinc-mediated reaction of
diaryl diselenides and chloroformates in aqueous media. 相似文献