Green synthesis and inhibitory effect of novel quinoline based thiazolidinones on the growth of MCF-7 human breast cancer cell line by G2/M cell cycle arrest

Research on Chemical Intermediates - Searching for new active molecules against human breast cancer cell line MCF-7, novel quinoline based thiazolidinones has been efficiently synthesized under...     

Theoretical analysis to investigate thermal performance of co-axial heat pipe solar collector

The thermal performance of co-axial heat pipe solar collector which consist of a collector 15 co-axial heat pipes surrounded by a transparent envelope and which heat a fluid flowing through the condenser tubes have been predicted using heat transfer analytical methods. The analysis considers conductive and convective losses and energy transferred to a fluid flowing through the collector condenser tubes. The thermal performances of co-axial heat pipe solar collector is developed and are used to determine the collector efficiency, which is defined as the ratio of heat taken from the water flowing in the condenser tube and the solar radiation striking the collector absorber. The theoretical water outlet temperature and efficiency are compared with experimental results and it shows good agreement between them. The main advantage of this collector is that inclination of collector does not have influence on performance of co-axial heat pipe solar collector therefore it can be positioned at any angle from horizontal to vertical. In high building where the roof area is not enough the co-axial heat pipe solar collectors can be installed on the roof as well as wall of the building. The other advantage is each heat pipe can be topologically disconnected from the manifold.     

Suction Induced Effects on the Fabric of a Structured Soil

This paper presents the mathematical modelling of the modification of the pore space geometry of a structured soil subjected to suction increase. Structured soil concepts are first introduced considering different fabric units, such as aggregates and fissures. The numerical modelling of the structural evolution is based on experimental test results in which the evolution of the structure of the samples subjected to different suctions is determined using the mercury intrusion porosimetry technique. From this information, the macro and micropore volume evolutions are determined. The results show that drying produces a reduction in the soil total porosity which mainly corresponds to a reduction of the macropore volume. Associated with this phenomenon, an increase in micropore volume is also observed. The proposed model divides pore size distribution into three pore classes (micropores, macropores and non-affected areas). Using the concept of a suction-influenced domain, the proposed model is able to reproduce the main observed fabric evolution between the saturated and dry states.     

Excellent photocatalytic reduction of nitroarenes to aminoarenes by BiVO4 nanoparticles grafted on reduced graphene oxide (rGO/BiVO4)

A novel heterogeneous composite material based on reduced graphene oxide (rGO) and bismuth vanadate (BiVO₄) was prepared and characterized by various techniques such as powder XRD, HRTEM, EADX, UV–Vis‐DRS, FT‐IR, Raman, BET and XPS analyses. The characterization results reveal that the rGO well decorated by BiVO₄. The electrochemical impedance spectroscopy (EIS) shows the increasing of charge transfer of rGO/BiVO₄ in presence of light irradiation. In this research, the pure BiVO₄ and rGO/BiVO₄ composite have been explored for photocatalytic reduction of nitroarenes. Among the prepared nanocomposites, rGO loaded with 10% BiVO₄ catalyst (noted as rGO/BiVO₄–10%) shows the best performance for the photo‐reduction of various nitroaromatic molecules to their corresponding amine compounds under visible‐light irradiation at room temperature. The catalyst exhibited in particular excellent photocatalytic activity for the conversion of 1,4‐dinitrobenzene to 4‐nitroanilline (100% conversion) in 20 min, 4‐chloronitrobenzene to 4‐chloroaniline and 2‐nitrophenol to 2‐aminophenol (100% conversion) in only 30 min. In addition, the conversion of 4‐bromonitrobenzene, 4‐iodonitrobenzene to their corresponding amine compounds (100% conversion) was achieved in 60 min. The catalyst was recovered for several times and reused without decreasing of its efficiency.     

Approximate solutions of fractional Zakharov–Kuznetsov equations by VIM

This paper presents the approximate analytical solution of a fractional Zakharov–Kuznetsov equation with the help of the powerful variational iteration method. The fractional derivatives are described in the Caputo sense. Several examples are given and the results are compared to exact solutions. The results show that the variational iteration method is very effective, convenient and simple to use.     

Explicit series solutions of some linear and nonlinear Schrodinger equations via the homotopy analysis method

In this paper, by means of the homotopy analysis method (HAM), the solutions of some Schrodinger equations are exactly obtained in the form of convergent Taylor series. The HAM contains the auxiliary parameter ?, that provides a convenient way of controlling the convergent region of series solutions. This analytical method is employed to solve linear and nonlinear examples to obtain the exact solutions. HAM is a powerful and easy-to-use analytic tool for nonlinear problems.     

Qualitative analysis of a fourth order difference equation

In this paper, we will investigate some qualitative behavior of solutions of the following fourth order difference equation $x_{n+1}=ax_{n-1}+\frac{bx_{n-1}}{cx_{n-1}-dx_{n-3}},$ \ $n=0,1,...,$ where the initial conditions $x_{-3,}x_{-2},\ x_{-1}$\ and\ $x_{0}\ $are arbitrary real numbers and the values $a,\ b,\ c\ $and$\;d$ are\ defined as positive real numbers.