Investigation of surface interactions between volatile chromium species and ceramics

Stainless steels are often used in high temperature (≥500°C) applications such as solid oxide fuel cells (SOFCs), combustion engine exhaust systems, and in power/chemical plant process equipment. At high temperature and in oxidizing conditions, chromium containing oxides, such as chromia, may form protective surface layers on the underlying alloy. Reactive evaporation of chromium, however, may occur from the protective surface layers given these conditions, resulting in the formation of volatile chromium species such as CrO₂(OH)₂. These volatile chromium species may then interact with surrounding materials, potentially resulting in hazardous compound formation, or having detrimental effects on system performance, as in the case of SOFCs. To better understand the interaction of volatile chromium condensation/deposition on material substrates, volatile chromium species were generated from chromia powder at 500°C to 900°C and flowed past coupons of alumina and mica and quartz wool at temperatures ranging from 150°C to 900°C for 24- and 100-hour exposures. The ceramic surfaces were characterized as a function of these exposures using X-ray photoelectron spectroscopy (XPS). Analysis of Cr 2p_3/2 peak positions revealed the influence of temperature, material, and exposure time on the oxidation states of surface chromium compounds and extent of chromium deposition. Potential mechanisms are proposed to help explain the observed trends.     

On Fitting p-groups with all proper subgroups satisfying an outer commutator law

In this note we consider certain Fitting p-groups in which every proper subgroup satisfies an outer commutator identity and obtained some conditions for such groups to be imperfect. We also give an application of the main theorem to obtain an idea of the abundance of the groups under consideration.     

On an inverse scattering problem for a class Dirac operator with discontinuous coefficient and nonlinear dependence on the spectral parameter in the boundary condition

On the positive semi‐infinite interval, we obtained a generalization of the Marchenko method for a Dirac equation system with a discontinuous coefficient and a quadratic polynomial on a spectral parameter in the boundary condition. In this connection, we use an new integral representation of the Jost solution of equation systems, which does not have a ‘triangular’ form. The scattering function of the problem is defined, and its properties are examined. The Marchenko‐type main equation is obtained, and it is shown that the potential is uniquely recovered in terms the scattering function. Copyright © 2012 John Wiley & Sons, Ltd.     

Stability of a thermoelastic laminated system subject to a neutral delay

In this work, we consider a system of two identical beams of uniform thickness modeled as a Timoshenko system. The slip between the beams is taken into account, and the system is coupled with a heat equation. Moreover, the slip equation is subject to a distributed delay of neutral type. Delays are known to be of a destructive nature in general. Therefore, here, the delay will compete with a frictional damping and the dissipation produced by the heat equation. We provide sufficient conditions ensuring exponential and polynomial stability of the structure.     

On Groups with Certain Proper FC-Subgroups

Algebras and Representation Theory - Let G be a group. If for every proper normal subgroup N and element x of G with N〈x〉≠G, N〈x〉 is an FC-group, but G is not an...     

The modular robotic systems

A very important design goal of these robotic systems is the adaptability to the inner diameters of the pipes. In this paper, we proposed two wheeled–type in–pipe modular robotic systems. Thus, the studied modular robotic systems are characterized by an adaptable structure, based on linkages mechanisms. The prototypes were designed in order to inspect pipes with variable diameters within 140 and 200 mm. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Determination of tianeptine in tablets by high-performance liquid chromatography with fluorescence detection

A sensitive and selective high-performance liquid chromatographic method has been developed for the determination of tianeptine (Tia) in tablets. The method is based on derivatization of Tia with 4-chloro-7-nitrobenzofurazan (NBD-CI). A mobile phase consisting of acetonitrile-10 mM orthophosphoric acid (pH 2.5; 77 + 23) was used at a flow rate of 1 mL/min on a C18 column. The Tia-NBD derivative was monitored using a fluorescence detector, with emission set at 520 nm and excitation at 458 nm. Gabapentin was selected as an internal standard. Linear calibration graphs were obtained in the concentration range of 45-300 ng/mL. The lower limit of detection (LOD) was 10 ng/mL at a signal-to-noise ratio of 4. The lower limit of quantitation (LOQ) was 45 ng/mL. The relative standard values for intra- and interday precision were <0.46 and <0.57%, respectively. The recovery of the drug samples ranged between 98.89 and 99.85%. No chromatographic interference from the tablet excipients was found. The proposed method was validated in terms of precision, robustness, recovery, LOD, and LOQ. All the validation parameters were within the acceptance range. The proposed method was applied for the determination of Tia in commercially available tablets. The results were compared with those obtained by an ultraviolet spectrophotometric method using t- and F-tests.     

Suzuki-Miyaura reactions of N-protected tribromopyrazoles. Efficient and site-selective synthesis of 3,4,5-triaryl-pyrazoles, 3,5-diaryl-4-bromopyrazoles and 5-aryl-3,4-dibromopyrazoles

Suzuki-Miyaura reactions of N-protected tribromopyrazoles were studied. The reactions proceed with excellent site-selectivity. The first attack occurs at position 5, while the second and third attack occur at positions 3 and 4, respectively. A variety of 3,4,5-triaryl-pyrazoles, 3,5-diaryl-4-bromopyrazoles, and 5-aryl-3,4-dibromopyrazoles were efficiently prepared. The products are not readily available by other methods.     

Transformations of 2-alkylidene-4-oxothiazolidine vinyl bromides initiated by bromophilic attack of neutral and anionic nucleophiles

Vinyl bromides derived from 2-alkylidene-4-oxothiazolidines represent a class of vinyl halides, which readily undergo a bromophilic attack by a range of nucleophiles. With Ph₃P, AcS⁻, CN⁻, I⁻, F⁻, Ac₂CH⁻ and N₃⁻ the attack ends up with reductive debromination, whereas the bromine substitution takes place with KSCN. When acetate anion and organic bases, such as pyridine, Et₃N or morpholine, are employed as nucleophiles the initial bromophilic attack is followed by bromine migration to the C(5) position of the ring, allowing the C(5) functionalization of this heterocyclic system.