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81.
The ruthenium(III) complex bearing phenylpyridine as a cyclometalated ligand serves as an efficient catalyst for the aerobic oxidative dehydrogenation of benzylamines to the corresponding benzonitriles under mild conditions. 相似文献
82.
83.
Tetsutaro Kimachi Eri Torii Rina Ishimoto Ayako Sakue Motoharu Ju-ichi 《Tetrahedron: Asymmetry》2009,20(14):1683-1689
Starting from a reduced lapachol compound, the total synthesis of rhinacanthin A in both racemic and enantioenriched forms is achieved in eight steps without forming any undesired β-lapachone derivatives. For the synthesis of enantioenriched rhinacanthin A, the introduction of the asymmetric center was carried out by using the catalytic asymmetric epoxidation of an unfunctional trisubstituted olefin using Shi’s epoxidation diketal catalyst. The acidic treatment of a derived enantioenriched epoxynaphthol and the following CAN oxidation afforded the target molecule with high enantiomeric purity. 相似文献
84.
Yutaka Nagasawa Ayako Watanabe Yoshito Ando Tadashi Okada 《Journal of Molecular Liquids》2001,90(1-3):295-302
We have studied femtosecond ground state recovery dynamics of phenol blue (PB) by pump-probe spectroscopy with a time resolution of 33 fs. Multiexponential decay with time constants extending from 300 fs to 10 ps were observed. Some low frequency intramolecular quantum beats were also observed. Solvent dependence of these decays and beats are discussed. 相似文献
85.
In this paper, we will give a simple proof of Theorem of [8] and some applications.This research is partially supported by Grant-in-Aid for Scientific Research. 相似文献
86.
In this study, we propose a new Low-Reynolds-Number (LRN)one-equation model, which is derived from an LRN two-equation(k-ε) model. The derivation of the transport equation, in principle, is based on the assumption that the turbulent structure
parameter remains constant. However, the relation for the turbulent structure parameter a
1(=|−
|/k) is modified to account for near-wall turbulence. As a result, the present one-equation model contains a term which takes
the near-wall limiting behavior explicitly into account. Thus, the present model provides the correct wall-limiting behavior
of turbulence in the vicinity of the wall and can be applied to the analysis of heat transfer. The validity of the present
model is tested in channel flows, boundary layer flows with and without pressure gradient, plane wall jet, and flow with separation
and reattachment. The calculated results showed good agreement with the direct numerical simulation (DNS) and experimental
data.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
87.
Ayako Tokiwa Masayasu Nagoshi Yasuhiko Syono 《Physica C: Superconductivity and its Applications》1990,170(5-6):437-442
Superconductivity and composition analysis of PbBaSr(Y, Ca)Cu3Oy with fixed ratio of Sr/Ba = 1 were studied. Synthesis condition and superconductivity of Pb(Ba, Sr)2(Y, Ca)Cu3Oy with various ratio of Sr/Ba and Ca/Y were also studied. It was found that Tc increased with increasing Ca concentration, and that Sr-rich specimens allowed to contain more Ca. PbBa0.8Sr1.2Y0.6Ca0.4Cu3O7 showed superconductivity with zero-resistance temperature of 42 K, which was higher than PbBaSrY0.7Ca0.3Cu3O7 with maximum Ca content for Sr/Ba = 1. Decrease in averaged ionic radii of Ba and Sr in Sr-rich compositions would be favorable for the contraction of Cu-O bonds by hole-doping via Ca substitution for Y. 相似文献
88.
Michio Zenki Makiko Ideshima Miwa Taniguchi Ayako Katoh Takashi Yokoyama 《Analytical sciences》2005,21(5):517-520
A circulatory flow-injection method (cyclic FIA) for the repetitive determination of zinc has been proposed. The procedure involves the use of 2-(5-bromo-2-pyridylazo)-5-[N-n-propyl-N-(3-sulfopropyl)amino]phenol (5-Br-PAPS) together with EDTA as a reagent carrier solution, which is recycled in a single-line flow system via a reservoir. The formed 5-Br-PAPS-Zn(II) complex was measured spectrophotometrically at 552 nm, and the signal intensity corresponded to the zinc concentration. After passing through a flow-through cell, the carrier stream then returned to the reservoir, and the main reagent, 5-Br-PAPS, was successfully regenerated by a ligand-exchange reaction with EDTA, allowing the repetitive determination of zinc. The calibration curve for zinc was linear in the concentration range from 0.4 to 10.0 mg dm(-3) with a correlation coefficient of 0.9995 (n = 6). The detection limit of this method was 0.02 mg dm(-3) (S/N= 3). This method allowed as many as 300 repetitive determinations of 2.0 mg dm(-3) zinc solution with only 100 cm3 of the circulating carrier solution, providing a reduction in the consumption of reagents and an elimination of waste, an important approach towards clean chemistry. 相似文献
89.
90.