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151.
In the present investigation, the optical property of the nematic sample p-methoxybenzylidene p-decylaniline, dispersed with SiO2 quantum dot (QD), has been reported. Enhanced luminescence has been observed from nematic-QD composites. Surface plasmonic effect along with QD exciton has been highlighted to discuss the observed intensification in photoluminescence. The intensified photoemission from the nematic composites can also be inferred from improved orientational behaviour of the liquid crystal molecules due to dispersion of QDs. Variation in the intensity of photoabsorption can be harnessed for development of luminescent display devices and optical parameter-driven scientific applications. 相似文献
152.
The design, synthesis and characterisation of some compounds whose constituent molecules have a completely new shape have been carried out. A total of eight different series/part of series of these zigzag-shaped compounds that are either symmetrical or unsymmetrical were synthesised. Only two mesophases were observed, and on the basis of polarising optical microscopy, differential scanning calorimetry, X-ray diffraction and electro-optical studies, these have been characterised as columnar phases with a rectangular or an oblique lattice. Perhaps, these represent the first examples of a rigid zigzag-shaped compound exhibiting a mesophase. 相似文献
153.
Dual switchable six-ring bent-core liquid crystals with azo linkages exhibiting B1 and B2 mesophases
A new series of asymmetric bent-core compounds were synthesised using azo linkages with equal as well as unequal terminal alkyl chains and their photo and electrical switching properties investigated. The mesomorphic properties were characterised using polarised optical microscopy, X-ray diffraction and differential scanning calorimetry. The lower homologues of the series of compounds show a B1 phase whereas higher homologues exhibit a B2 phase. The B2 phase shows an anticlinic-antiferroelectric switching behaviour during electro-optic measurements. The photo-switching properties of the azobenzene containing bent-core molecules were investigated using ultraviolet-visible spectroscopy. The trans to cis photo isomerisation was observed at 25 s whereas reverse processes took 14 h in chloroform. 相似文献
154.
Somnath Dasgupta‡ Vishal Kumar Rajput‡ Bimalendu Roy 《Journal of carbohydrate chemistry》2013,32(2):91-106
Lanthanum trifluoromethanesulfonate‐catalyzed solvent‐free per‐O‐acetylation with stoichiometric acetic anhydride proceeds in high yield (95%–99%) to afford exclusively pyranose products as anomeric mixtures. Subsequent anomeric substitution employing borontrifluoride etherate and thiols or alcohols furnished the corresponding 1,2‐trans‐linked thioglycosides and O‐glycosides, respectively, in good to excellent overall yield (75%–85%). Alternatively, reaction of free sugars in neat alcohol employing the same catalyst at elevated temperature gives the corresponding 1,2‐cis‐linked O‐glycosides (along with 1,2‐trans‐linked glycosides as minor product) in good yield (73%–80%). Anomeric mixtures of compounds thus produced were characterized as their per‐O‐acetylated derivatives. 相似文献
155.
ABSTRACT Synthesis of the terminal trisaccharide sequence of the ganglioside GD3, α-D-Neup5Ac-(2→8)-α-D-Neup5Ac-(2→3)-β-D-Galp-(1→4)-β-D-Glcp-(1→1)-Cer (2) was achieved by employing an α-(2→8) disialyl glycosyl donor (1). Condensation of 1 with the glycosyl acceptor 6, propyl 4,6-O-benzylidene-β-D-galactopyranoside, gave the desired protected trisaccharide 10 (14%) as well as the elimination and hydrolysis products of 6, compounds 8 and 9 respectively. O-Deacetylation and debenzylation of 10 gave the final trisaccharide 11, as its propyl glycoside. 相似文献
156.
Ambar Kumar Choudhury Asim Kumar Ray Nirmolendu Roy 《Journal of carbohydrate chemistry》2013,32(8):1153-1163
Abstract Starting from L-fucose, D-glucose and lactose, methyl O-[2,3-di-O-benzoyl-4, 6-O-(4-methoxybenzylidene)-β-D-glucopyranosyl]-(1→4)-2,3-di-O-benzoyl-α-L-fucopyranoside and methyl O-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-(1→4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl 2,3-di-O-benzoyl-β-D-glucopyranosyluronate)-(1→4)-2,3-di-O-benzoyl-α-L-fucopyranoside were synthesized. Removal of protecting groups gave the tetrasaccharide repeating unit of the antigen from Klebsiella type-16 in the form of its methyl ester methyl glycoside. 相似文献
157.
Abdelkrim Azzouz Vasilica-Alisa Aruş Nicoleta Platon Kamel Ghomari Ieana-Denisa Nistor Tze Chieh Shiao René Roy 《Adsorption》2013,19(5):909-918
Dendrimers bearing hydroxyl groups supported by layered double hydroxides (CO3–LDH) with Mg/Al ratio ranging from 1:1 to 5:1 showed improved properties for the reversible capture of carbon dioxide (CO2). The adsorption capacity of the starting LDH was due to the intrinsic base-like behavior, and was found to depend on the Mg/Al ratio. When contacted with polyol dendrimers in aqueous media, no intercalation took place. This was explained in terms of low exfoliation grade of LDH and hydrophobic character of the dendrimer molecules. The latter rather adsorb on the external surface of the LDH stacks for low dendrimer loadings, or aggregate into organic clusters for higher contents. Analyses through thermal programmed desorption of CO2 revealed that dendrimer incorporation advantageously attenuates the basicity strength of the starting LDH support, by lowering the desorption temperature. The OH groups of the organic moiety were found to display an amphoteric character, and act as the main adsorption sites. The weak interactions with CO2 facilitate easier release of the major part of adsorbed CO2 at temperature not exceeding 80–100 °C. On polyol organo-LDHs, the reversible CO2 retention was discussed herein in terms of acid–base interactions. This concept allows envisaging the capture of diverse pollutants and other greenhouse gases by modifying the chemical groups on the dendritic moiety. 相似文献
158.
Subhasish Roy Abhishek Baral Prof. Arindam Banerjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(44):14950-14957
An amino‐acid‐based (11‐(4‐(pyrene‐1‐yl)butanamido)undecanoic acid) self‐repairing hydrogel is reported. The native hydrogel, as well as hybrid hydrogels, have been thoroughly characterized by using various microscopic techniques, including transmission electron microscopy (TEM), atomic force microscopy (AFM), Raman spectroscopy, fluorescence spectroscopy, FTIR spectroscopy, X‐ray diffraction, and by using rheological experiments. The native hydrogel exhibited interesting fluorescence properties, as well as a self‐healing property. Interestingly, the self‐healing, thixotropy, and stiffness of the native hydrogel can be successfully modulated by incorporating carbon‐based nanomaterials, including graphene, pristine single‐walled carbon nanotubes (Pr‐SWCNTs), and both graphene and Pr‐SWCNTs, within the native gel system. The self‐recovery time of the gel was shortened by the inclusion of reduced graphene oxide (RGO), Pr‐SWCNTs, or both RGO and Pr‐SWCNTs. Moreover, hybrid gels that contained RGO and/or Pr‐SWCNTs exhibited interesting semiconducting behavior. 相似文献
159.
An Okinawan soft coral Cespitularia sp. has proven to be a good source of cytotoxic metabolites having a carbon skeleton of the seco-type variety of xenicin. This soft coral yielded alcyonolide, the major constituent, and other related compounds, all of which have proven to be cytotoxic. Reinvestigation of the cytotoxic ethyl acetate extracts of the coral yielded two new alcyonolide congeners, trisnorditerpenoid 1 and diterpenoid 2, possessing the same carbon skeleton. Their structures were elucidated by a detailed analysis of spectroscopic data (1D, 2D NMR, and MS). Metabolites 1 and 2 showed cytotoxicity against HCT116 cells (IC50 6.04 and 47.0 μM, respectively) and a dose dependent, anti-inflammatory effect in LPS/IFN-γ-stimulated inflammatory RAW 264.7 macrophage cells. 相似文献
160.
Mousumi Singha Sangita Pal K. N. Hareendran S. B. Roy 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(2):961-966
A novel hydrophilic, three dimensionally cross-linked, aliphatic backbones with pendant hydroxamic acid (HA) group as functional moiety has been synthesized and utilized targeting removal of gadolinium [Gd(III)] from laboratory waste aqueous effluent. To understand the nature of sorption, gadolinium solution of various concentrations viz., 20, 10, 5.0, 1.0, 0.5 and 0.1 ppm has been contacted with a dose rate of 1 g/100 mL for 2 h. In this study, ICP-AES has been used for determination of concentration (ppm) of gadolinium in feed, filtrate and elute. EDXRF study also ensures the presence of gadolinium in the respective medium. Loaded gadolinium matrix was eluted with 1 N HCl for determining the elution factor (0.98). 相似文献