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排序方式: 共有185条查询结果,搜索用时 15 毫秒
41.
P. N. Bourosh E. B. Koropchanu A. A. Desyantnik O. A. Bologa Zh. P. Tyurina M. V. Stratan O. A. Chiobenike Ya. Lipkovsky I. I. Bulkhak Yu. A. Simonov 《Russian Journal of Coordination Chemistry》2009,35(10):751-757
The coordination compound [Co(DH)2(PP)2][BF4]2 · 2H2O (DH− is the dimethylglyoxime residue, PP is nicotinamide) was synthesized and studied by X-ray diffraction. The equatorial plane
of the octahedral Co(III) complex contains two DH− residues combined by intramolecular hydrogen bonds O-H…O, while the apical positions are occupied by two PP molecules. A
method for the optimal use of the complex for enhancement of the biosynthesis of standard and acid-stable amylases of the
micromycete Aspergillus niger 33–19 CNMN FD 02A and lipases of the micromycete Rhizopus arrhizus Fischer CNMN FD 03L was depeloped. The introduction of the complex in a concentration of 1–5 mg/l into the culture medium of Aspergillus niger 33-19 CNMN FD 02A reduces the process cycle by 24 h. The stimulating effect of the introduction of the complex (5 mg/l) into
the culture medium of the Rhizopus arrhizus Fischer CNMN FD 03L strain is 55.5%. 相似文献
42.
43.
S Rosenfeldt F Lüdel C Schulreich T Hellweg A Radulescu J Schmelz H Schmalz L Harnau 《Physical chemistry chemical physics : PCCP》2012,14(37):12750-12756
Triblock terpolymers exhibit a rich self-organization behavior including the formation of fascinating cylindrical core-shell structures with a phase separated corona. After crystallization-induced self-assembly of polystyrene-block-polyethylene-block-poly(methyl methacrylate) triblock terpolymers (abbreviated as SEMs = Styrene-Ethylene-Methacrylates) from solution, worm-like core-shell micelles with a patchy corona of polystyrene and poly(methyl methacrylate) were observed by transmission electron microscopy. However, the solution structure is still a matter of debate. Here, we present a method to distinguish in situ between a Janus-type (two faced) and a patchy (multiple compartments) configuration of the corona. To discriminate between both models the scattering intensity must be determined mainly by one corona compartment. Contrast variation in small-angle neutron scattering enables us to focus on one compartment of the worm-like micelles. The results validate the existence of the patchy structure also in solution. 相似文献
44.
Aurel Bejancu 《Journal of Nonlinear Science》2012,22(2):213-233
In the first part of the paper we present a new point of view on the geometry of nonholonomic mechanical systems with linear
and affine constraints. The main geometric object of the paper is the nonholonomic connection on the distribution of constraints.
By using this connection and adapted frame fields, we obtain the Newton forms of Lagrange–d’Alembert equations for nonholonomic
mechanical systems with linear and affine constraints. In the second part of the paper, we show that the Kaluza–Klein theory
is best presented and explained by using the framework of nonholonomic mechanical systems. We show that the geodesics of the
Kaluza–Klein space, which are tangent to the electromagnetic distribution, coincide with the solutions of Lagrange–d’Alembert
equations for a nonholonomic mechanical system with linear constraints, and their projections on the spacetime are the geodesics
from general relativity. Any other geodesic of the Kaluza–Klein space that is not tangent to the electromagnetic distribution
is also a solution of Lagrange–d’Alembert equations, but for affine constraints. In particular, some of these geodesics project
exactly on the solutions of the Lorentz force equations of the spacetime. 相似文献
45.
The synthesis of a novel series of N-based heterocyclic salts using a simple and efficient N-alkylation of 1,2-bis(4-pyridyl)ethane with reactive halides is reported. These compounds can be transformed into the corresponding pyridinium methylides by addition of a base. The former exhibit an unstable absorption bands at 395–410 nm. The structures of the salts were fully characterized by UV–vis, IR, NMR and MS spectroscopy and elemental analysis. The pK values of selected compounds were also determined and the acid–basic equilibrium was investigated by UV–vis spectrophotometry. The thermal stability of all species was determined by thermogravimetric analysis. 相似文献
46.
47.
Rainer Buckdahn Marc Quincampoix Aurel Răşcanu 《Probability Theory and Related Fields》2000,116(4):485-504
In the present paper, we study conditions under which the solutions of a backward stochastic differential equation remains
in a given set of constraints. This property is the so-called “viability property”. In a separate section, this condition
is translated to a class of partial differential equations.
Received: 23 April 1998 / Published online: 14 February 2000 相似文献
48.
Jeffrey M. Thompson Aurel Bulgac 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):462-465
We show that the electronic density of states of small sodium clusters is strongly affected by both thermal fluctuations about the ground state ionic configuration and transitions between different shape isomers as the temperature of the cluster is increased. Contrary to common expectations, the clusters undergo a sharp transition in the temperature range of 100K to 150 K, after which the single-particle level distributions become bimodal. At even higher temperatures the signature of the ground state configuration disappears, and the density of states is dominated by higher energy isomers. We also discuss the implications of these findings for the interpretation of the photoelectron spectra of these systems. 相似文献
49.
A converse of the well-known theorem on themean value property of harmonic functions is given. It is shown that a positive measurable function is harmonic if it possesses arestricted mean value property. Earlier proofs obtained using the probabilistic techniques were given by Veech, Heath and Baxter. Our approach is based on a Martin type compactification built up with the help of some quite elementarya priori inequalities foraveraging kernels. 相似文献
50.
The performance of a network subject to either state dependent or state independent flow control is investigated. In the state dependent case, the flow control policy is a function of the total number of packets for which the controller has not yet received an acknowledgment. In this case it is shown that the optimal flow control is a sliding window mechanism. The effect of the delayed feedback on the network performance as well as the size of the window are studied. The state independent optimal rate is also derived. The performance of the state dependent and state independent flow control policies are compared. Conditions for employing one of the two types of flow control policies for superior end-to-end network performance are discussed. All the results obtained are demonstrated using simple examples. 相似文献