全文获取类型
收费全文 | 497篇 |
免费 | 9篇 |
国内免费 | 2篇 |
专业分类
化学 | 207篇 |
晶体学 | 8篇 |
力学 | 11篇 |
数学 | 134篇 |
物理学 | 148篇 |
出版年
2022年 | 11篇 |
2021年 | 5篇 |
2020年 | 12篇 |
2019年 | 7篇 |
2018年 | 11篇 |
2017年 | 10篇 |
2016年 | 7篇 |
2015年 | 15篇 |
2014年 | 7篇 |
2013年 | 23篇 |
2012年 | 18篇 |
2011年 | 21篇 |
2010年 | 16篇 |
2009年 | 25篇 |
2008年 | 19篇 |
2007年 | 17篇 |
2006年 | 13篇 |
2005年 | 10篇 |
2004年 | 17篇 |
2003年 | 5篇 |
2001年 | 13篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 10篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 11篇 |
1992年 | 12篇 |
1991年 | 5篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 16篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 13篇 |
1978年 | 12篇 |
1977年 | 19篇 |
1976年 | 16篇 |
1975年 | 4篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1971年 | 2篇 |
1969年 | 2篇 |
排序方式: 共有508条查询结果,搜索用时 10 毫秒
221.
A complete vibrational assignment is made and ideal gas thermodynamic properties of vinyl acetate have been reported from 100–1500 K. Internal rotational contributions have been calculated using Pitzer and Gwinn's tables. 相似文献
222.
Chann B Huang RK Missaggia LJ Harris CT Liau ZL Goyal AK Donnelly JP Fan TY Sanchez-Rubio A Turner GW 《Optics letters》2005,30(16):2104-2106
We demonstrate 35 W output peak power with M2 approximately 1.35 in both dimensions from a 100 element, 100 microm pitch slab-coupled optical waveguide laser diode array using wavelength beam combining. 相似文献
223.
It has been proved that, ifR is a near-ring with no non-zero nilpotent two-sidedR-subsets and if the annihilator of any non-zero ideal is contained in some maximal annihilator, thenR is a subdirect sum of strictly prime near-rings. Moreover, ifR is a near-ring with no non-zero nilpotent two-sidedR-subsets and satisfying a.c.c. or d.c.c. on annihilating ideals of the form Ann (Q), whereQ is an ideal ofR, thenR is a finite subdirect sum of strictly prime near-rings. It is also proved that, ifR is a regular and right duo near-ring that satisfies a.c.c. (or d.c.c.) on annihilating ideals of the form Ann (Q), whereQ is an ideal ofR, thenR is a finite direct sum of near-ringsR
i (1 i n) where eachR
i is simple and strictly prime. 相似文献
224.
The macroscopic theory of elasticity is extended to determine the fourth order elastic constants. The expressions for the small amplitude sound wave velocity and for a natural velocity, in statically stressed media, are derived in terms of second, third and fourth order elastic constants. 相似文献
225.
A Simple and Sensitive Poly‐1,5‐Diaminonaphthalene Modified Sensor for the Determination of Sulfamethoxazole in Biological Samples 下载免费PDF全文
Sulfamethoxazole (SMZ), an antibacterial sulfonamide drug, has been selectively determined using poly‐1,5‐diaminonaphthalene (p‐DAN) modified glassy carbon electrode (GCE). The modified sensor was characterized by field emission scanning electron microscopy (FE‐SEM), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). SMZ showed linear response in the concentration range of 0.5–150 µM by using square wave voltammetry (SWV) and the detection limit was found to be 0.05 nM with sensitivity of 0.085 µA µM?1. The proposed sensor has been successfully employed to determine SMZ in the pharmaceutical tablets and human urine samples. 相似文献
226.
C60-modified glassy carbon electrode has been found to exhibit excellent electrocatalytic activity towards atenolol oxidation for its voltammetric determination at physiological pH. Lowering of overpotential associated with atenolol oxidation indicates electrocatalytic nature of electrode. Determination of atenolol was carried out at pH 7.2 at modified electrode and a well-defined oxidation peak has been observed ∼1040 mV versus Ag/AgCl electrode for atenolol oxidation. Calibration plot having good co-linearity with a correlation coefficient 0.997 was obtained in the concentration range of 0.25-1.5 mM atenolol and the sensitivity of the method has been found to be 8.58 μA mM−1. The detection limit is found to be 0.16 mM. The method developed is applicable for atenolol determination in pharmaceutical preparations and urine samples. The modified electrode showed a good surface coverage (∼85%) with C60. 相似文献
227.
Raman spectroscopy and control charts based on the net analyte signal (NAS) were applied to polymorphic characterization of carbamazepine. Carbamazepine presents four polymorphic forms: I-IV (dihydrate). X-ray powder diffraction was used as a reference technique. The control charts were built generating three charts: the NAS chart that corresponds to the analyte of interest (form III in this case), the interference chart that corresponds to the contribution of other compounds in the sample and the residual chart that corresponds to nonsystematic variations. For each chart, statistical limits were developed using samples within the quality specifications. It was possible to identify the different polymorphic forms of carbamazepine present in pharmaceutical formulations. Thus, an alternative method for the quality monitoring of the carbamazepine polymorphic forms after the crystallization process is presented. 相似文献
228.
Joshi R Poonam Saini R Guleria S Babu GD Kumari M Gulati A 《Natural product communications》2011,6(8):1155-1158
Volatile flavour components of tea flowers (Camellia sinensis) were isolated by two methods viz. simultaneous distillation extraction (SDE), supercritical fluid extraction (SFE), analyzed by GC and GC/MS and compared with headspace analysis (HS). The composition of the volatile components extracted by the three methods differed considerably. In SFE, phenylethanol (14.7%), linalool (7.9%), (E)-linalool oxide furanoid (3.5%), epoxy linalool (1.6%), geraniol (2.3%) and hotrienol (1.5%) were major components. m-Xylene (2.6%), (E)-linalool oxide pyranoid (5.4%), p-myrcene (5.2%), alpha-cadinol (4.3%) and methyl palmitate (2.9%) were major compounds isolated by SDE. 3-hexenol (2.1%) (E)-4,8-dimethyl-1,3,7-nonatriene (20.9%) and linalool (35.1%) are major components in headspace analysis. Acetophenone and pheromone germacrene D is detected in tea flowers by all the methods studied. Floral, fresh and fruity odour of tea flowers is retained by SFE as there is very little loss of heat sensitive volatiles in SFE. The flavour isolated from SFE has superior quality compared to SDE. 相似文献
229.
A novel and reliable direct electrochemical method has been established to monitor DNA damage in acid hydrolyzed calf thymus DNA, based on the determination of 2,8‐dihydroxyadenine (2,8‐DHA). A single‐wall carbon nanotubes (SWCNT) modified edge plane pyrolytic graphite electrode (EPPGE) has been used as a sensor to monitor the DNA damage. 2,8‐DHA the main in vivo adenine oxidation product undergoes oxidation at ~395 mV at SWCNT modified EPPGE using square wave voltammetry (SWV). The sensor exhibits potent and persistent electron‐mediating behavior. A well‐defined oxidation peak for the oxidation of 2,8‐DHA was observed at modified electrode with lowering of peak potential and increase in peak current as compared to bare EPPGE. At optimal experimental conditions, the catalytic oxidative peak current was responsive with the 2,8‐DHA concentrations ranging from 0.05 nM to 100 nM. The detection limit was 3.8×10?11 M and limit of quantification was 1.27×10?10 M. The modified electrode exhibited high stability and reproducibility. 相似文献
230.
Yogeeta O. Agrawal Umesh B. Mahajan Vinit V. Agnihotri Mayur S. Nilange Hitendra S. Mahajan Charu Sharma Shreesh Ojha Chandragouda R. Patil Sameer N. Goyal 《Molecules (Basel, Switzerland)》2021,26(5)
Ezetimibe (EZE) possesses low aqueous solubility and poor bioavailability and in addition, its extensive hepatic metabolism supports the notion of developing a novel carrier system for EZE. Ezetimibe was encapsulated into nanostructured lipid carriers (EZE-NLCs) via a high pressure homogenization technique (HPH). A three factor, two level (23) full factorial design was employed to study the effect of amount of poloxamer 188 (X1), pressure of HPH (X2) and number of HPH cycle (X3) on dependent variables. Particle size, polydispersity index (PDI), % entrapment efficiency (%EE), zeta potential, drug content and in-vitro drug release were evaluated. The optimized formulation displays pragmatic inferences associated with particle size of 134.5 nm; polydispersity index (PDI) of 0.244 ± 0.03; zeta potential of −28.1 ± 0.3 mV; % EE of 91.32 ± 1.8% and % CDR at 24-h of 97.11%. No interaction was observed after X-ray diffraction (XRD) and differential scanning calorimetry (DSC) studies. EZE-NLCs (6 mg/kg/day p.o.) were evaluated in the high fat diet fed rats induced hyperlipidemia in comparison with EZE (10 mg/kg/day p.o.). Triglyceride, HDL-c, LDL-c and cholesterol were significantly normalized and histopathological evaluation showed normal structure and architecture of the hepatocytes. The results demonstrated the superiority of EZE-NLCs in regard to bioavailability enhancement, dose reduction and dose-dependent side effects. 相似文献