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171.
A di-triazole based peptide has been synthesised by copper catalyzed Huisgen cycloaddition. Fluorescence intensity is enhanced selectively in the presence of Zn(2+), which is ascribed to reversal of photoelectron transfer. Compound 7 was found to self-assemble in the presence of Zn(ClO(4))(2) in an exclusive 2:1 ratio, which is supported by (1)H NMR titration and mass spectral data. The fluorescence intensity of 7 shows a subsequent ON-OFF phenomenon upon repetitive and alternate addition of Zn(ClO(4))(2) and HClO(4). 相似文献
172.
The symmetry reduction method based on the Fr′echet derivative of differential operators is applied to investigate symmetries of the Einstein-Maxwell field equations for magnetostatic fields, which is a coupled system of nonlinear partial differential equations of the second order. The technique yields invariant transformations that reduce the given system of partial differential equations to a system of nonlinear ordinary differential equations. Some of the reduced systems are further studied to obtain the exact solutions. 相似文献
173.
In this paper, an analog microwave over fiber link for long haul distance based upon Rate Equation Laser is demonstrated. This system uses the advantage of high potential bandwidth of fiber in transmission of microwave signal. The interface of the two systems needs an up-conversion of microwave band into baseband (at which fiber operates). An Intensity Modulation Direct Detection (IMDD) technique is used to achieve this purpose. The Rate Equation laser is operated in a dynamic state, where its intensity oscillates at a microwave frequency that varies with the input signal fed by wave generator. This system can also use for two modulating tones. The frequency of the first tone is varied from 1 to 20 GHz and second is set at 5 GHz. A data signal of 10 Gbps is transmitted over long haul single mode fiber by single tone system. A very good bit error rate (BER) 10?40 performances for 100 km and 25 km fiber link is achieved for both single tone and two tones respectively in proposed microwave over fiber communication system. 相似文献
174.
In the present paper we make an attempt to model the lattice energy with the lattice constants through the first-principles calculations. This formalism is designed particularly for application with the self-consistent pseudopotential (PP) method within the density functional (DF) framework and includes exchange and correlation effects. Applying the above formalism we have calculated the lattice energy and correlation energy for a number of solids belonging to groups I–VII and II–VI of the periodic table. The convergence of our results is in the favour of used PP. These results will be helpful in determining various structural and elastic properties of these solids and in the generation of equation of state. 相似文献
175.
Anubha Goyal Ashavani Kumar Prabir K. Patra Shaily Mahendra Salomeh Tabatabaei Pedro J. J. Alvarez George John Pulickel M. Ajayan 《Macromolecular rapid communications》2009,30(13):1116-1122
We demonstrate a simple one‐step method for synthesizing noble metal nanoparticle embedded free standing polydimethylsiloxane (PDMS) composite films. The process involves preparing a homogenous mixture of metal salt (silver, gold and platinum), silicone elastomer and the curing agent (hardener) followed by curing. During the curing process, the hardener crosslinks the elastomer and simultaneously reduces the metal salt to form nanoparticles. This in situ method avoids the use of any external reducing agent/stabilizing agent and leads to a uniform distribution of nanoparticles in the PDMS matrix. The films were characterized using UV‐Vis spectroscopy, transmission electron microscopy and X‐ray photoemission spectroscopy. The nanoparticle‐PDMS films have a higher Young's modulus than pure PDMS films and also show enhanced antibacterial properties. The metal nanoparticle‐PDMS films could be used for a number of applications such as for catalysis, optical and biomedical devices and gas separation membranes.
176.
Arivozhi Mohan S. Shanmugavel Ajay Goyal B. R. Venkataraman D. Saravanan 《Chromatographia》2009,12(3)
Five impurities were observed when candesartan cilexetil tablets were subjected to stability and forced degradation studies.
These impurities were successfully isolated and characterized as desethyl candesartan cilexetil, 1N-ethyl candesartan cilexetil, 2N-ethyl candesartan cilexetil, 1N-ethyl oxo candesartan cilexetil, and 2N-ethyl oxo candesartan cilexetil. A gradient reverse phase liquid chromatography (LC) and an isocratic preparative LC method
were used to detect and isolate all five degradation products impurities simultaneously. Mass spectrometry, 1H/13C, DEPT and 2D NMR experiments were extensively utilized to characterize these impurities. Even though desethyl candesartan
cilexetil, 1N-ethyl candesartan cilexetil were 2N-ethyl candesartan cilexetil were documented in the literature as known impurities, the regioisomers 1N-ethyl oxo candesartan cilexetil and 2N-ethyl oxo candesartan cilexetil were never noticed. Single-crystal diffraction data has been used to confirm their structure
unambiguously and synthetic preparations of all known and unknown impurities were also presented. 相似文献
177.
The purpose of this research is to solve the mixed integer constrained optimization problem with interval coefficient by a real-coded genetic algorithm (RCGA) with ranking selection, whole arithmetical crossover and non-uniform mutation for non-integer decision variables. In the ranking selection, as well as in finding the best solution in each generation of RCGA, recently developed modified definitions of order relations between interval numbers with respect to decision-making are used. Also, for integer decision variables, new types of crossover and mutation are introduced. This methodology is applied to solve a finite time horizon inventory model with constant lead-time, uniform demand rate and a discount by paying an amount of money in advance. Moreover, different inventory costs are considered to be interval valued. According to the consumption of items during lead-time and reorder level, two cases may arise. For each case, the mathematical model becomes a constrained nonlinear mixed integer problem with interval objective. Our objective is to determine the optimal number of cycles in the finite time horizon, lot-size in each cycle and optimal profit. The model is illustrated with some numerical examples and sensitivity analysis has been done graphically with the variation of different inventory parameters. 相似文献
178.
An extensive theoretical set of atomic data for Rb XXIX in a wide range with L-shell electron excitations to the M-shell has been reported. We have computed energy levels for the lowest 113 fine structure levels of Rb XXIX. The fully relativistic multiconfigurational Dirac-Fock method (MCDF) within the framework of Dirac-Coulomb Hamiltonian taking quantum electrodynamics (QED) and Breit corrections into account has been adopted for calculations. Radiative data are reported for electric dipole (E1), magnetic dipole (M1), electric quadrupole (E2), and magnetic quadrupole (M2) transitions from the ground level, although calculations have been performed for a much larger number of levels. To assess the accuracy of results, we performed analogous calculations using flexible atomic code (FAC). Comparisons are made with existing available results and a good agreement has been achieved. Most of the wavelengths calculated lie in the soft x-ray (SXR) region. Lifetimes for all 113 levels have also been provided for the first time. Additionally, we have provided the spectra for allowed transitions from n=2 to n= 3 within the x-ray region and also compared our SXR photon wavelengths with experimentally recognized wavelengths. We hope that our results will be beneficial in fusion plasma research and astrophysical applications. 相似文献
179.
Surface plasmon band tailoring of plasmonic nanostructure under the effect of water radiolysis by synchrotron radiation 下载免费PDF全文
Amardeep Bharti Ashish K. Agrawal Balwant Singh Sanjeev Gautam Navdeep Goyal 《Journal of synchrotron radiation》2017,24(6):1209-1217
Plasmonic metal nanostructures have a significant impact on a diverse domain of fields, including photocatalysis, antibacterial, drug vector, biosensors, photovoltaic cell, optical and electronic devices. Metal nanoparticles (MNps) are the simplest nanostructure promising ultrahigh stability, ease of manufacturing and tunable optical response. Silver nanoparticles (AgNp) dominate in the class of MNps because of their relatively high abundance, chemical activity and unique physical properties. Although MNps offer the desired physical properties, most of the synthesis and fabrication methods lag at the electronic grade due to an unbidden secondary product as a result of the direct chemical reduction process. In this paper, a facile protocol is presented for fabricating high‐yield in situ plasmonic AgNps under monochromatic X‐rays irradiation, without the use of any chemical reducing agent which prevents the formation of secondary products. The ascendancy of this protocol is to produce high quantitative yield with control over the reaction rate, particle size and localized surface plasmon resonance response, and also to provide the feasibility for in situ characterization. The role of X‐ray energy, beam flux and integrated dose towards the fabrication of plasmonic nanostructures has been studied. This experiment extends plasmonic research and provides avenues for upgrading production technologies of MNps. 相似文献
180.
Armin Darvish Jung Soo Lee Bin Peng Jugal Saharia Ramalingam VenkatKalyana Sundaram Gaurav Goyal Nuwan Bandara Chi Won Ahn Jungsuk Kim Prashanta Dutta Irwin Chaiken Min Jun Kim 《Electrophoresis》2019,40(5):776-783
Enveloped viruses fuse with cells to transfer their genetic materials and infect the host cell. Fusion requires deformation of both viral and cellular membranes. Since the rigidity of viral membrane is a key factor in their infectivity, studying the rigidity of viral particles is of great significance in understating viral infection. In this paper, a nanopore is used as a single molecule sensor to characterize the deformation of pseudo‐type human immunodeficiency virus type 1 at sub‐micron scale. Non‐infective immature viruses were found to be more rigid than infective mature viruses. In addition, the effects of cholesterol and membrane proteins on the mechanical properties of mature viruses were investigated by chemically modifying the membranes. Furthermore, the deformability of single virus particles was analyzed through a recapturing technique, where the same virus was analyzed twice. The findings demonstrate the ability of nanopore resistive pulse sensing to characterize the deformation of a single virus as opposed to average ensemble measurements. 相似文献