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31.
Borges AR Hyacinth M Lum M Dingle CM Hamilton PL Chruszcz M Pu L Sabat M Caran KL 《Langmuir : the ACS journal of surfaces and colloids》2008,24(14):7421-7431
The synthesis and colloidal study of a new class of low molecular weight organogelators is reported. Racemic propargylic alcohols with perfluoroaryl and nonfluorinated aryl rings are capable of forming gels in alkane liquids and/or silicone oil. A full colloidal characterization of alkane gels prepared from (R/S)-1-pentafluorophenyl-3-phenylprop-2-yn-1-ol [(R/S)- 1] was conducted, including both structural [optical microscopy, scanning electron microscopy (SEM), powder X-ray diffraction (XRD), attenuated total reflectance infrared spectroscopy (ATR-IR)] and thermal stability [differential scanning calorimetry (DSC)] studies. A model of the organization of gelator molecules within gel fibers has been proposed primarily based on the correlation of diffraction data for the powder XRD pattern of a gel and a simulated powder pattern from a sublimed crystal of the gelator. Furthermore, structural requirements for propargylic alcohol gelators were investigated by subjecting derivatives with modified structures to gelation tests. An enantiomerically enriched sample [(R)- 1, 83% ee] fails to entrap the solvent under conditions where the racemate successfully forms a gel. The remaining racemic derivatives (with p-alkoxy or p-alkyl substituents on the nonfluorinated arene) form gels or partial gels in silicone oil and in some alkane preparations. 相似文献
32.
Heffernan JV Budzien J Wilson AT Baca RJ Aston VJ Avila F McCoy JD Adolf DB 《The Journal of chemical physics》2007,126(18):184904
Simulation results for the diffusive behavior of polymer chain/penetrant systems are analyzed. The attractive range and flexibility of simple chain molecules were varied in order to gauge the effect on dynamics. In all cases, the dimensionless diffusion coefficient, D*, is found to be a smooth, single-valued function of the packing fraction, eta. The functions D*(eta) are found to be power laws with exponents that are sensitive to both chain stiffness and particle type. For a specific system type, the D*'s for both penetrant and chain-center-of-mass extrapolate to zero at the same packing fraction, eta0. This limiting packing fraction is interpreted to be the location of the glass transition, and (eta0-eta), the distance to the glass transition. 相似文献
33.
Matyja A Rozanska M Adachi I Aihara H Aulchenko V Aushev T Bahinipati S Bakich AM Balagura V Barberio E Bedny I Bhardwaj V Bitenc U Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang MC Chang P Chen A Chen KF Cheon BG Chistov R Cho IS Choi Y Choi YK Dalseno J Dash M Eidelman S Fratina S Gabyshev N Golob B Ha H Haba J Hara T Hayasaka K Hazumi M Heffernan D Hokuue T Hoshi Y Hou WS Hyun HJ Iijima T Ikado K Inami K Ishikawa A Ishino H Itoh R Iwasaki Y Kaji H Kajiwara S Kang JH Katayama N 《Physical review letters》2007,99(19):191807
We report an observation of the decay B{0}-->D{*-}tau{+}nu{tau} in a data sample containing 535x10{6} BB pairs collected with the Belle detector at the KEKB asymmetric-energy e{+}e{-} collider. We find a signal with a significance of 5.2sigma and measure the branching fraction B(B{0}-->D{*-}tau{+}nu{tau})=(2.02{-0.37}{+0.40}(stat)+/-0.37(syst))%. This is the first observation of an exclusive B decay with a b-->ctaunu{tau} transition. 相似文献
34.
Mizuk R Abe K Adachi I Aihara H Anipko D Aulchenko V Aushev T Bakich AM Balagura V Barberio E Bay A Bedny I Belous K Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang MC Chen A Chen KF Chen WT Cheon BG Chistov R Choi Y Choi YK Cole S Dalseno J Danilov M Drutskoy A Eidelman S Epifanov D Fratina S Gabyshev N Garmash A Gershon T Gokhroo G Golob B Ha H Haba J Hayasaka K Hayashii H Hazumi M Heffernan D Hokuue T Hoshi Y Hou S Hou WS Iijima T Ikado K Imoto A Inami K 《Physical review letters》2007,98(26):262001
We report the results of several studies of the Lambda(c)(+)pi(+)pi(-)X final state in continuum e(+)e(-) annihilation data collected by the Belle detector. An analysis of angular distributions in Lambda(c)(2880)(+)-->Sigma(c)(2455)(0,++)pi(+,-) decays strongly favors a Lambda(c)(2880)(+) spin assignment of 5/2 over 3/2 or 1/2. We find evidence for Lambda(c)(2880)(+)-->Sigma(c)(2520)(0,++)pi(+,-) decay and measure the ratio of Lambda(c)(2880)(+) partial widths Gamma(Sigma(c)(2520)pi)/Gamma(Sigma(c)(2455)pi)=0.225+/-0.062+/-0.025. This value favors the Lambda(c)(2880)(+) spin-parity assignment of 5/2(+) over 5/2(-). We also report the first observation of Lambda(c)(2940)(+)-->Sigma(c)(2455)(0,++)pi(+,-) decay and measure Lambda(c)(2880)(+) and Lambda(c)(2940)(+) mass and width parameters. These studies are based on a 553 fb(-1) data sample collected at or near the Upsilon(4S) resonance at the KEKB collider. 相似文献
35.
Hydrogen-bonded assembly of methanol on Cu(111) 总被引:1,自引:0,他引:1
TJ Lawton J Carrasco AE Baber A Michaelides EC Sykes 《Physical chemistry chemical physics : PCCP》2012,14(33):11846-11852
Investigation of methanol's surface chemistry on metals is a crucial step towards understanding the reactivity of this important chemical feedstock. Cu is a relevant metal for methanol synthesis and reforming, but due to the weak interaction of methanol with Cu, an atomic scale view of methanol's coverage-dependent ordering and self-assembly on Cu(111), the most abundant facet of most nanoparticles, has not yet been possible. Low and variable temperature scanning tunneling microscopy coupled with density functional theory reveal a coverage-dependent range of highly ordered structures stabilized by two hydrogen bonds per molecule. While extended chains that resemble the hydrogen-bonded zigzag structures reported for solid methanol are an efficient way to pack methanol at higher coverages, lower surface coverages yield isolated hexamer units. These hexamers form the same number of hydrogen bonds as the chains but appear to repel one another on the surface. Annealing treatments lead to the desorption of methanol with almost no decomposition. This data serves as a useful guide to both the preferred adsorption geometries and energies of a variety of methanol structures on Cu(111) surfaces as a function of surface coverage. 相似文献
36.
A series of divalent first row triflate complexes supported by the ligand tris(2-pyridylmethyl)amine (TPA) have been investigated as oxygen reduction catalysts for fuel cell applications. [(TPA)M(2+)](n+) (M = Mn, Fe, Co, Ni, and Cu) derivatives were synthesized and characterized by X-ray crystallography, cyclic voltammetry, NMR spectroscopy, magnetic susceptibility, IR spectroscopy, and conductance measurements. The stoichiometric and electrochemical O(2) reactivities of the series were examined. Rotating-ring disk electrode (RRDE) voltammetry was used to examine the catalytic activity of the complexes on a carbon support in acidic media, emulating fuel cell performance. The iron complex displayed a selectivity of 89% for four-electron conversion and demonstrated the fastest reaction kinetics, as determined by a kinetic current of 7.6 mA. Additionally, the Mn, Co, and Cu complexes all showed selective four-electron oxygen reduction (<28% H(2)O(2)) at onset potentials (~0.44 V vs RHE) comparable to state of the art molecular catalysts, while being straightforward to access synthetically and derived from nonprecious metals. 相似文献
37.
Pakhlova G Adachi I Aihara H Arinstein K Aulchenko V Aushev T Bakich AM Balagura V Barberio E Bedny I Belous K Bitenc U Bondar A Bracko M Brodzicka J Browder TE Chen A Chen WT Cheon BG Chiang CC Chistov R Cho IS Choi Y Dalseno J Danilov M Dash M Drutskoy A Eidelman S Epifanov D Gabyshev N Golob B Ha H Haba J Hayasaka K Hazumi M Heffernan D Hoshi Y Hou WS Hsiung YB Hyun HJ Inami K Ishikawa A Ishino H Itoh R Iwasaki M Iwasaki Y Joshi NJ Kah DH Kang JH Kawasaki T Kibayashi A Kichimi H Kim HJ 《Physical review letters》2008,100(6):062001
We report measurements of the exclusive cross section for e(+)e(-)-->D(0)D(-)pi(+) over the center-of-mass energy range 4.0 GeV to 5.0 GeV with initial-state radiation and the first observation of the decay psi(4415)-->D(0)D(-)pi(+). From a study of the resonant substructure in psi(4415) decay we conclude that the psi(4415)-->D(0)D(-)pi(+) decay is dominated by psi(4415)-->DD(2)(*)(2460). We obtain B(psi(4415)-->D(0)D(-)pi(nonresonant)(+))/B(psi(4415)-->DD(2)(*)(2460)-->D(0)D(-)pi(+))<0.22 at 90% C.L. The analysis is based on a data sample collected with the Belle detector with an integrated luminosity of 673 fb(-1). 相似文献
38.
Chen KF Hou WS Shapkin M Sokolov A Adachi I Aihara H Arinstein K Aulchenko V Aushev T Bakich AM Balagura V Bay A Belous K Bhardwaj V Bitenc U Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang P Chao Y Chen A Chen WT Chistov R Choi Y Dalseno J Danilov M Dash M Drutskoy A Eidelman S Gabyshev N Golob B Ha H Haba J Hayasaka K Hayashii H Hazumi M Heffernan D Hoshi Y Hsiung YB Hyun HJ Iijima T Inami K Ishikawa A Ishino H Itoh R Iwasaki M Iwasaki Y Kah DH Kang JH Kapusta P Katayama N Kawai H 《Physical review letters》2008,100(11):112001
We report the first observation of e;{+}e;{-}-->Upsilon(1S)pi;{+}pi;{-}, Upsilon(2S)pi;{+}pi;{-}, and first evidence for e;{+}e;{-}-->Upsilon(3S)pi;{+}pi;{-}, Upsilon(1S)K+K-, near the peak of the Upsilon(5S) resonance at sqrt[s] approximately 10.87 GeV. The results are based on a data sample of 21.7 fb;{-1} collected with the Belle detector at the KEKB e;{+}e;{-} collider. Attributing the signals to the Upsilon(5S) resonance, the partial widths Gamma(Upsilon(5S)-->Upsilon(1S)pi;{+}pi;{-})=0.59+/-0.04(stat)+/-0.09(syst) MeV and Gamma(Upsilon(5S)-->Upsilon(2S)pi;{+}pi;{-})=0.85+/-0.07(stat)+/-0.16(syst) MeV are obtained from the observed cross sections. These values exceed by more than 2 orders of magnitude the previously measured partial widths for dipion transitions between lower Upsilon resonances. 相似文献
39.
Chen JH Wang MZ Adachi I Aihara H Arinstein K Aulchenko V Aushev T Bakich AM Balagura V Barberio E Bay A Bedny I Belous K Bitenc U Bondar A Bozek A Bracko M Browder TE Chang MC Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Cho IS Choi SK Choi Y Dalseno J Dash M Drutskoy A Eidelman S Golob B Ha H Haba J Hara T Hayasaka K Hayashii H Hazumi M Heffernan D Hoshi Y Hou WS Hsiung YB Hyun HJ Inami K Ishikawa A Ishino H Itoh R Iwasaki M Joshi NJ Kah DH Kaji H Kapusta P Katayama N Kawasaki T Kichimi H 《Physical review letters》2008,100(25):251801
Using a 492 fb{-1} data sample collected near the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e{+}e{-} collider, we observe the decay B{0}-->ppK*0 with a branching fraction of (1.18{-0.25}{+0.29}(stat)+/-0.11(syst))x10{-6}. We study the decay dynamics of B{0}-->ppK*0 and compare with B{+}-->ppK*+. The K*0 meson is found to be almost 100% polarized (with a fraction of (101+/-13+/-3)% in the helicity zero state), while the K*+ meson has a (32+/-17+/-9)% fraction in the helicity zero state. The direct CP asymmetries for B{0}-->ppK*0 and B{+}-->ppK*+ are measured to be -0.08+/-0.20+/-0.02 and -0.01+/-0.19+/-0.02, respectively. In addition, we report improved measurements of the branching fractions B(B{+}-->ppK*+)=(3.38{-0.60}{+0.73}+/-0.39)x10{-6} and B(B{0}-->ppK{0})=(2.51{-0.29}{+0.35}+/-0.21)x10{-6}, which supersede our previous measurements. 相似文献
40.
Xiao B Wheatley PS Zhao X Fletcher AJ Fox S Rossi AG Megson IL Bordiga S Regli L Thomas KM Morris RE 《Journal of the American Chemical Society》2007,129(5):1203-1209
Gas adsorption experiments have been carried out on a copper benzene tricarboxylate metal-organic framework material, HKUST-1. Hydrogen adsorption at 1 and 10 bar (both 77 K) gives an adsorption capacity of 11.16 mmol H2 per g of HKUST-1 (22.7 mg g(-)1, 2.27 wt %) at 1 bar and 18 mmol per g (36.28 mg g(-)1, 3.6 wt %) at 10 bar. Adsorption of D2 at 1 bar (77 K) is between 1.09 (at 1 bar) and 1.20(at <100 mbar) times the H2 values depending on the pressure, agreeing with the theoretical expectations. Gravimetric adsorption measurements of NO on HKUST-1 at 196 K (1 bar) gives a large adsorption capacity of approximately 9 mmol g(-1), which is significantly greater than any other adsorption capacity reported on a porous solid. At 298 K the adsorption capacity at 1 bar is just over 3 mmol g(-1). Infra red experiments show that the NO binds to the empty copper metal sites in HKUST-1. Chemiluminescence and platelet aggregometry experiments indicate that the amount of NO recovered on exposure of the resulting complex to water is enough to be biologically active, completely inhibiting platelet aggregation in platelet rich plasma. 相似文献