Structure and orientation of an intermetallic phase in a W-Ni-Co alloy

The aim of this investigation is crystal structure determination of an intermetallic phase formed in a W-Ni-Co alloy during a heat-treatment carried out at a temperature of 800°C. This intermetallic phase is expected to play a critical role on the final microstructure (fine tungsten particles in an FCC matrix that is present in between large tungsten grains) and thereby, on the properties of the alloy. 92W-5.3Ni-2.7Co alloy was prepared through powder metallurgy route (liquid phase sintering) followed by heat-treatment at 800°C for 5?h. The intermetallic phase formed at this temperature was characterised using transmission and scanning electron microscopes. The intermetallic phase was found to have orthorhombic crystal structure with Pnam (62) space group as determined using automated diffraction tomography along with precession electron diffraction. Chemical analysis in TEM suggested that the intermetallic phase is based on stoichiometry (Co,Ni)₂W. Orientation imaging of the phase was also carried out in TEM and EBSD to understand its evolution. Equiaxed or lath morphology of the intermetallic phase was found to depend on the crystallographic orientation relationship of the phase with the tungsten grains and the matrix phase.     

Carbon-13 NMR spectra of Piper alkamides and related compounds

¹³C NMR spectra of Piper alkamides and related compounds have been completely assigned on the basis of splitting patterns in the coupled spectra, application of additivity relationships and internal comparison of chemical shifts.     

On the Anistropy of the Speed of Light on a Rotating Platform

The paper discusses a recently posed paradox in relativity concerning the speed of light as measured by an observer on board a rotating turn-table. The counter-intuitive problem put forward by F. Selleri concerns the theoretical prediction of an anisotropy in the speed of light in a reference frame comoving with the edge of a rotatiing disc even in the limit of zero acceleration. The paradox not only challenges the internal consistency of the special relativity theory but also undermines the basic tenet of the conventionality of simultaneity thesis of relativity. The present paper resolves the issue in a novel way by recasting the original paradox in the Galilean world and thereby revealing, in a subtle way, the weak points of the reasonings leading to the fallacy. As a background the standard and the non-standard synchronies in the relativistic as well as in the Galilean world are discussed. In passing, this novel approach also clarifies (contrary to often made assertions in the literature) that the so-called desynchronization of clocks cannot be regarded as the root cause of the Sagnac effect. Finally in spite of the flaw in the reasonings leading to the paradox Selleri's observation regarding the superiority of the absolute synchrony over the standard one for a rotation observer has been upheld.     

Effect of salt concentration on the electrophoretic speed of a polyelectrolyte through a nanopore

In a previous paper [S. Ghosal, Phys. Rev. E 74, 041901 (2006)] a hydrodynamic model for determining the electrophoretic speed of a polyelectrolyte through an axially symmetric slowly varying nanopore was presented in the limit of a vanishingly small Debye length. Here the case of a finite Debye layer thickness is considered while restricting the pore geometry to that of a cylinder of length much larger than the diameter. Further, the possibility of a uniform surface charge on the walls of the nanopore is taken into account. It is thereby shown that the calculated transit times are consistent with recent measurements in silicon nanopores.     

Nonadiabatic dissociation dynamics of ClHD van der Waals complex initiated by electron detachment of Cl–HD

Nuclear dynamics following the electron detachment of the Cl⁻–HD anion is investigated by a time-dependent wave packet propagation approach. Photodetachment of Cl⁻–HD promotes it to the van der Waals well region of the reactive ClHD potential energy surface. The latter is a manifold of three electronic states coupled by the electronic and (relativistic) spin-orbit coupling. Among the three surfaces, the electronic ground one is of ²Σ_1/2 type and yields products in their electronic ground state. The remaining two, ²Π_3/2 and ²Π_1/2, on the other hand, yield products in their excited electronic states. However, these two can yield products in their electronic ground state via nonadiabatic transitions to the ²Σ_1/2 state. The channel specific, HCl + D or DCl + H or Cl + HD, dissociation probabilities on this latter state are calculated both in the uncoupled and coupled surface situations. Separate initial transitions (via, photodetachment) to the ²Σ_1/2, ²Π_3/2 and ²Π_1/2 adiabatic electronic states of ClHD are considered in order to elucidate the nonadiabatic coupling effects on this important class of chemical reactions initiated by an electron detachment.     

Anomalous diffusion in an electrolyte saturated paper matrix

Diffusion of colored dye on water saturated paper substrates has been traditionally exploited with great skill by renowned water color artists. The same physics finds more recent practical applications in paper-based diagnostic devices deploying chemicals that react with a bodily fluid yielding colorimetric signals for disease detection. During spontaneous imbibition through the tortuous pathways of a porous electrolyte saturated paper matrix, a dye molecule undergoes diffusion in a complex network of pores. The advancing front forms a strongly correlated interface that propagates diffusively but with an enhanced effective diffusivity. We measure this effective diffusivity and show that it is several orders of magnitude greater than the free solution diffusivity and has a significant dependence on the solution pH and salt concentration in the background electrolyte. We attribute this to electrically mediated interfacial interactions between the ionic species in the liquid dye and spontaneous surface charges developed at porous interfaces, and introduce a simple theory to explain this phenomenon.     

Structure–property correlation of a boron and carbon modified as cast β titanium alloy

Beta titanium alloys, Ti-15V-3Cr-3Al-3Sn, with minor additions of boron and carbon were prepared by consumable vacuum arc melting. Detailed microstructural characterizations were carried out using optical, scanning electron microscopes and transmission electron microscopes. Addition of boron resulted in refinement of the as cast beta grain while carbon addition resulted in the precipitation of extremely fine α phase during ageing. Formation of boride and carbide particles due to addition of boron and carbon, respectively, and refinement of the aged microstructure increased the hardness and strength as compared to the base alloy but reduced elongation to failure considerably, especially in the carbon-containing alloy where no measurable plasticity was observed. Fracture toughness values, however, were comparable for the boron- and carbon-containing alloys but these were lower than that of the base alloy.     

Statistical convergence of a sequence of random variables and limit theorems

In this paper the ideas of three types of statistical convergence of a sequence of random variables, namely, statistical convergence in probability, statistical convergence in mean of order r and statistical convergence in distribution are introduced and the interrelation among them is investigated. Also their certain basic properties are studied.     

A chiron approach to aminocytitols by petasis-borono-mannich reaction: formal synthesis of (+)-conduramine e and (-)-conduramine e

A chiron approach to a stereoselective route for the synthesis of aminocytitols from carbohydrates is described. The formal synthesis of (+)-conduramine E and (-)-conduramine E was achieved by utilizing this strategy. The key features of the synthetic strategy include one-pot three-component Petasis-Borono-Mannich reaction to introduce the syn-β-amino alcohol functionality of conduramine E and ring-closing metathesis to construct its carbocyclic core. The present synthetic approach paves the way for stereoselective synthesis of several conduramines starting from carbohydrates.