全文获取类型
收费全文 | 1240篇 |
免费 | 57篇 |
国内免费 | 1篇 |
专业分类
化学 | 917篇 |
晶体学 | 15篇 |
力学 | 36篇 |
数学 | 84篇 |
物理学 | 246篇 |
出版年
2023年 | 7篇 |
2022年 | 25篇 |
2021年 | 26篇 |
2020年 | 35篇 |
2019年 | 29篇 |
2018年 | 31篇 |
2017年 | 31篇 |
2016年 | 58篇 |
2015年 | 50篇 |
2014年 | 56篇 |
2013年 | 99篇 |
2012年 | 110篇 |
2011年 | 84篇 |
2010年 | 47篇 |
2009年 | 49篇 |
2008年 | 94篇 |
2007年 | 52篇 |
2006年 | 49篇 |
2005年 | 48篇 |
2004年 | 39篇 |
2003年 | 28篇 |
2002年 | 36篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 12篇 |
1995年 | 5篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 11篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 10篇 |
1977年 | 4篇 |
1969年 | 6篇 |
1968年 | 6篇 |
1964年 | 4篇 |
1963年 | 6篇 |
1962年 | 6篇 |
1961年 | 12篇 |
1958年 | 7篇 |
1957年 | 3篇 |
1955年 | 5篇 |
排序方式: 共有1298条查询结果,搜索用时 0 毫秒
101.
A Preconditioned Conjugate Gradient Approach to Linear Equality Constrained Minimization 总被引:2,自引:0,他引:2
We propose a new framework for the application of preconditioned conjugate gradients in the solution of large-scale linear equality constrained minimization problems. This framework allows for the exploitation of structure and sparsity in the context of solving the reduced Newton system (despite the fact that the reduced system may be dense). Numerical experiments performed on a variety of test problems from the Netlib LP collection indicate computational promise. 相似文献
102.
Density Functional Theory has been used to determine the energetically preferred structures of submonolayer, monolayer, and multilayer Pt films on both ideal terminations of SrTiO3(1 0 0), SrTiO3(1 1 1), and SrTiO3(1 1 0). The strength of the resulting metal/metal oxide interfaces was characterized by the adsorption energy of the film and the film’s work of separation. The two polar surfaces, SrTiO3(1 1 1) and SrTiO3(1 1 0), form significantly stronger interfaces than the non-polar SrTiO3(1 0 0) surface. Approximate criteria were applied to predict the growth mode of Pt on each surface. 相似文献
103.
DeSouza Arun H. G. Wilson David J. Tanner Robert D. 《Applied biochemistry and biotechnology》1990,24(1):565-578
Applied Biochemistry and Biotechnology - Extracellular proteins produced by yeast have been observed to stratify in the extracellular fluid of a batch bioreactor, thus creating a vertical... 相似文献
104.
V. Sankaranarayanan Arun D. Mahindrakar Ravi N. Banavar 《Communications in Nonlinear Science & Numerical Simulation》2008,13(10):2266-2278
We present a switched control law for stabilizing an underactuated underwater vehicle (UUV) moving in a horizontal plane in a neutrally buoyant condition. The control law consists of a sequential series of control actions, each of which achieves a certain objective, finally resulting in the system being moved to the origin. Finite-time controllers are employed at each stage to achieve the desired objective. Simulation results are presented to validate the control law. 相似文献
105.
This paper deals with a new solution technique for approximately solving certain variational problems in elasticity by using discrete optimization techniques that were originally used in information theory. This allows us to easily and approximately solve large deformation buckling problems for slender cantilever beams (including post-buckling behavior) as well as problems where the strain energy function is non-convex.The core idea is to quantize or discretize the variables describing the possible configurations of the body. This, when combined with the fact that the variational problem has an inherent Markov structure allows us to use computationally efficient search techniques based on dynamic programming (equivalent to finding the shortest path in a weighted directed graph) to find optimal solutions within the quantized state space. The results can be used in two ways: (1) directly as a fast approximate solution to the variational problem (2) As a means for finding very good (nearly minimum energy) initial configurations for application of conventional minimization techniques, which might otherwise fail because of a poor starting configurations which are far from the global minimum. We demonstrate both these uses in the paper. 相似文献
106.
107.
Palladium catalyzed intramolecular aminoacetoxylation of d-ribose derived alkenyl tosylsulfonamide to deliver l-deoxyallonojirimycin in an overall yield of 19%. The preliminary screening of l-deoxyallonojirimycin against carbohydrate processing enzymes showed moderate inhibitory activity against α-glucosidase (yeast) and α-mannosidases. 相似文献
108.
Lalit Giri Arun Kumar Jugran Amit Bahukhandi Praveen Dhyani Indra D. Bhatt Ranbeer Singh Rawal Shyamal Kumar Nandi Uppeandra Dhar 《Applied biochemistry and biotechnology》2017,181(1):267-282
Habenaria edgeworthii Hook. f. ex Collett is an important terrestrial orchid used in different Ayurvedic formulations. In the present study, variations among morphological, phytochemical and molecular markers were assessed. A significant difference was observed among populations using morphological traits. Inter-simple sequence repeat (ISSR) data revealed lower genetic diversity at population level (He = 0.207) as compared to species level (He = 0.334). Analysis of molecular variance (AMOVA) indicates 74 % variation among populations and 26 % within population. Tuber extracts showed significantly (p < 0.05) higher total phenolics and flavonoids among the populations. Antioxidant activity determined by 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radical scavenging, 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging and ferric reducing antioxidant power (FRAP) assays exhibited considerable antioxidant potential. Furthermore, the associations between molecular and morphological and phytochemical attributes were studied using multiple regression analysis (MRA). Several ISSR fragments were associated with some morphological and phytochemical traits. These ISSR fragments can be useful for breeding programme of the species when no other genetic information, such as linkage maps and quantitative trait loci, is available. 相似文献
109.
Basu M Sinha AK Pradhan M Sarkar S Pal A Pal T 《Chemical communications (Cambridge, England)》2010,46(46):8785-8787
Monoclinic CuO crystallite in grams has been obtained from resin bound Cu(II)-1,10-phenanthroline complex, R(-)[Cu(1,10-phen)(2)](2+) that becomes a recyclable catalyst for oxidative phenol coupling (OPC) reaction. Thus an exclusively intuitive blue fluorescing perylene derivative is derived from colorless 2,7-dihydroxynaphthalene (2,7-DHN) in high yield. 相似文献
110.
Arun Kumar Sinha Mrinmoyee Basu Mukul Pradhan Sougata Sarkar Tarasankar Pal Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(26):7865-7874
We report here the preparation of a crystalline, pure hexagonal phase of ZnO as hollow 500–800 nm spheroids in the presence of organic bases, such as pyridine, using zinc acetate as the precursor salt. The spheroids exhibit unique 3D hierarchical architectures, like cocoons, and demonstrate improved superhydrophobic (water contact angle, 150°) character due to the inherited air‐trapped capillarity within the cocoon structure. The simple synthetic strategy used in this process is modified hydrothermolysis (MHT), which represents a general approach and may contribute to the formation mechanism of the hollow nanostructures with highly improved porosity. Depending on the concentration of the precursor salt, it has been possible to cover glass plates or the inner wall of a reaction vessel with ZnO nanocrystals. A low salt concentration (<0.01 M ) allows the easy preparation of a superhydrophobic glass surface, whereas a high salt concentration (>0.01 M ) results in the precipitation of cocoons at the bottom of the reaction vessel as a solid mass together with a deposited thin film of ZnO nanocrystals covering the inner wall of the glass vessel. The thickness of the film successively grows through repetitive hydrothermolysis processes for which a low salt concentration (<0.01 M ) was employed. Because of the hollow cocoonlike morphology, the surface area of the film is greatly increased, which makes it accessible for functionalization by incoming substrates from both sides (internally and externally) and helps to drive a competent photocatalytic dye degradation pathway. The heterocyclic base pyridine exclusively develops cocoons. Thus, the mechanism of self‐aggregation of ZnO nanocrystals under MHT reaction conditions has been studied and the characterization of the compounds has been supported with physical measurements. 相似文献