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71.
Arthur E. Martell Ramunas J. Motekaitis Eric T. Clarke Rita Delgado Yizhen Sun Rong Ma 《Supramolecular chemistry》2013,25(3-4):353-363
Abstract In our studies of the stability constants of metal complexes, we have investigated a number of macrocyclic ligands with pendant donor groups. The ligands are characterized by the fact that they have nitrogen donors in the macrocyclic ring and oxygen or sulfur donors in the pendant arms. These ligands represent seven different macrocycles, and by varying the pendant donor groups, ten different ligands are indicated. The affinities of these ligands for fifteen metal ions will be described. The Fe(III) complex of triazanonane with o-hydroxypyridyl or o-hydroxybenzyl pendant donor groups are the most stable ferric complexes ever reported. The In(III) complex of triazacyclononane with pendant mercaptoethyl donor groups, is exceptionally stable. Also, the Ca(II) complex of DOTA probably has the highest stability of any calcium(II) complex. These, and other comparisons will be made on the basis of the thermodynamic stability constant data for the ligands described. 相似文献
72.
do Nascimento Ticiano Gomes Borges Arthur Luy Tavares Ferreira de Almeida Lara Mendes Ribeiro Êurica Adélia Nogueira Silva Fernanda Geny Calheiros da Costa Silva Valdemir do Nascimento Prata Ana Paula Basílio-Júnior Irinaldo Diniz Goulart Marília Oliveira Fonseca Morilla Demetrius Peireira de Freitas Johnnatan Duarte Aragão Cícero Flávio Soares 《Journal of Thermal Analysis and Calorimetry》2022,147(21):11949-11963
Journal of Thermal Analysis and Calorimetry - This work prepared and characterized microcapsule of Uncaria tomentosa (UT) in order to standardize a spray-dryer Uncaria tomentosa extract. The UT... 相似文献
73.
Ast CR Henk J Ernst A Moreschini L Falub MC Pacilé D Bruno P Kern K Grioni M 《Physical review letters》2007,98(18):186807
The long-range ordered surface alloy Bi/Ag(111) is found to exhibit a giant spin splitting of its surface electronic structure due to spin-orbit coupling, as is determined by angle-resolved photoelectron spectroscopy. First-principles electronic structure calculations fully confirm the experimental findings. The effect is brought about by a strong in-plane gradient of the crystal potential in the surface layer, in interplay with the structural asymmetry due to the surface-potential barrier. As a result, the spin polarization of the surface states is considerably rotated out of the surface plane. 相似文献
74.
I. Kachaev V. Dorofeev A. Ekimov V. Gotman A. Ivashin V. Kalendarev Yu. Khokhlov M. Kholodenko V. Konstantinov V. Matveev M. Mikhasenko V. Nikolaenko A. Plekhanov D. Ryabchikov Yu. Salomatin V. Sugonyaev E. Volkov A. Zaitsev 《Physics of Atomic Nuclei》2015,78(13):1474-1477
Partial wave analysis of the π–A π+π–π– system produced by 29 GeV/cπ– beam on a beryllium target is presented. About 30 × 106 |events in the wide t′|range 0–0.8 GeV2/c 2 are collected with upgraded VES setup. The size of the data sample is 2.5 times larger than one previously analyzed by VES. Data are analyzed using formalism of the density matrix with unlimited rank. We discuss status of the a 1(1420) a 2(1700) a 3(1875) states and a structure of exotic ρ(770)π P-wave with J PC = 1-+. Parameters of a 3(1875) are estimated as M = 1985 ± 20 MeV/c 2, Γ = 200 ± 50 MeV/c 2 (preliminary). 相似文献
75.
V. A. Burov O. V. Matveev D. I. Zotov O. D. Rumyantseva 《Physics of Wave Phenomena》2015,23(2):135-142
The possibility of simultaneous reconstruction of the blood flow velocity vector and spatial distributions of the speed of sound and absorption coefficient in a medical ultrasonic tomograph is discussed. The operating capacity of the proposed spatial-correlation method for determining the blood flow velocity vector is confirmed by experiments on a tomograph prototype. 相似文献
76.
77.
Chalykh A. E. Petrova T. F. Matveev V. V. Gerasimov V. K. Khasbiullin R. R. Shcherbina A. A. Abaturova N. A. 《Russian Chemical Bulletin》2020,69(4):675-682
Russian Chemical Bulletin - Phase equilibria in the mixtures of polyvinyl alcohol (PVA) and chitosan were revealed. Structures of the phases were identified. The temperature and concentration... 相似文献
78.
Matveev D. N. Vasilevskii V. P. Borisov I. L. Volkov V. V. Volkov A. V. 《Russian Journal of Applied Chemistry》2020,93(4):554-563
Russian Journal of Applied Chemistry - The influence of parameters of the dry-jet wet spinning process was studied on properties of porous polysulfone hollow fiber membranes. The air gap distance,... 相似文献
79.
80.
This work introduces channel-supermodular entropies, a subset of quasi-concave entropies. Channel-supermodularity is a property shared by some of the most commonly used entropies in the literature, including Arimoto–Rényi conditional entropies (which include Shannon and min-entropy as special cases), k-tries entropies, and guessing entropy. Based on channel-supermodularity, new preorders for channels that strictly include degradedness and inclusion (or Shannon ordering) are defined, and these preorders are shown to provide a sufficient condition for the more-capable and capacity ordering, not only for Shannon entropy but also regarding analogous concepts for other entropy measures. The theory developed is then applied in the context of query anonymization. We introduce a greedy algorithm based on channel-supermodularity for query anonymization and prove its optimality, in terms of information leakage, for all symmetric channel-supermodular entropies. 相似文献