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63.
We successively pass two V-type three-level atoms through a single-mode cavity field. Considering the field to be initially in a classical state, we evaluate various statistical properties such as the quasiprobability Q function, Wigner distribution, Mandel?s Q parameter and normal squeezing of the resulted field. We notice that the sequential crossing of atoms induces nonclassicality into the character of a pure classical state (coherent field). The initial thermal field shows sub-Poissonian as well as squeezing property after interacting with the V atoms. 相似文献
64.
Single crystal X-ray diffraction studies show that the β-turn structure of tetrapeptide I, Boc-Gly-Phe-Aib-Leu-OMe (Aib: α-amino isobutyric acid) self-assembles to a supramolecular helix through intermolecular hydrogen bonding along the crystallographic a axis. By contrast the β-turn structure of an isomeric tetrapeptide II, Boc-Gly-Leu-Aib-Phe-OMe self-assembles to a supramolecular β-sheet-like structure via a two-dimensional (a, b axis) intermolecular hydrogen bonding network and π-π interactions. FT-IR studies of the peptides revealed that both of them form intermolecularly hydrogen bonded supramolecular structures in the solid state. Field emission scanning electron micrographs (FE-SEM) of the dried fibrous materials of the peptides show different morphologies, non-twisted filaments in case of peptide I and non-twisted filaments and ribbon-like structures in case of peptide II. 相似文献
65.
The synthesis and characterization of a family of Mn(2)(III)Mn(2)(II)Ln(III)(2) complexes (Ln = Gd (1), Tb (2), Dy (3), and Ho (4)) of formula [Mn(4)Ln(2)O(2)(O(2)CBu(t))(6)(edteH(2))(2)(NO(3))(2)] are reported, where edteH(4) is N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine. The analogous Mn(4)Y(2) (5) complex has also been prepared. They were obtained from reaction of Ln(NO(3))(3) or Y(NO(3))(3) with Mn(O(2)CBu(t))(2), edteH(4), and NEt(3) in a 2:3:1:2 molar ratio. The crystal structures of representative 1 and 2 were obtained, and their core consists of a face-fused double-cubane [Mn(4)Ln(2)(μ(4)-O(2-))(2)(μ(3)-OR)(4)] unit. Such double-cubane units are extremely rare in 3d metal chemistry and unprecedented in 3d-4f chemistry. Variable-temperature, solid-state dc and ac magnetic susceptibility studies on 1-5 were carried out. Fitting of dc χ(M)T vs T data for 5 gave J(bb) (Mn(III)···Mn(III)) = -32.6(9) cm(-1), J(wb) (Mn(II)···Mn(III)) = +0.5(2) cm(-1), and g = 1.96(1), indicating a |n, 0, n> (n = 0-5) 6-fold-degenerate ground state. The data for 1 indicate an S = 12 ground state, confirmed by fitting of magnetization data, which gave S = 12, D = 0.00(1) cm(-1), and g = 1.93(1) (D is the axial zero-field splitting parameter). This ground state identifies the Mn(II)···Gd(III) interactions to be ferromagnetic. The ac susceptibility data independently confirmed the conclusions about 1 and 5 and revealed that 2 displays slow relaxation of the magnetization vector for the Mn(4)Tb(2) analogue 2. The latter was confirmed as a single-molecule magnet by observation of hysteresis below 0.9 K in magnetization vs dc field scans on a single crystal of 2·MeCN on a micro-SQUID apparatus. The hysteresis loops also displayed well-resolved quantum tunneling of magnetization steps, only the second 3d-4f SMM to do so. 相似文献
66.
For the first time we propose the phenomenon of coupled tapering and uptapering in two mutually incoherent beams coaxially co-propagating in a nonlinear medium with small gain or loss. During tapering or uptapering, the widths and powers of the beams evolve in such a manner that they always satisfy the condition of soliton pairing. It is shown that under certain condition one beam can taper/uptaper, while, other uptaper/taper during coupled tapering/uptapering which is quite counterintuitive. 相似文献
67.
Pali Maiti Totan Ghosh Anjan Banerjee Arpita Banerjee Santanu Bhattacharya Eringathodi Suresh Debasis Das 《Transition Metal Chemistry》2011,36(2):195-199
A dinuclear MnII complex, namely [Mn2L2(μ1,5-dca)2(dca)2]·H2O [L = N,N′-ethylenebis(2-benzoylpyridineimine), dca = dicyanamide], has been synthesized and structurally characterized in
order to study its catecholase-like activity. Single-crystal X-ray analysis revealed that the molecule possesses a center
of inversion at the midpoint of the line bisecting the adjacent metal centers of the dimers. The coordination number of each
MnII center is seven, and the coordination geometry is approximately distorted pentagonal bipyramid. The complex is an efficient
catalyst for the oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylbenzoquinone under air in methanol solution but is inactive in acetonitrile solution. A kinetic study of the catalysis
was treated on the basis of the Michaelis–Menten model and reveals high turnover numbers (k
cat = 4.5 × 102 h−1) in methanol. 相似文献
68.
Molecular Diversity - Short synthetic peptide molecules which bind to a specific target protein with a high affinity to exert its function are known as peptide aptamers. The high specificity of... 相似文献
69.
70.
Semigroup Forum - The most powerful formulation of the Central Sets Theorem in an arbitrary semigroup was proved in the work of De, Hindman, and Strauss. The sets which satisfy the conclusion of... 相似文献